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Citation: WANG Li, ZHANG Yanhui, WANG Yingbo. Synthesis, Crystal Structure and Magnetic Characterization of Azido-bridged Binuclear Cobalt(Ⅱ) Coordination Polymer[J]. Chinese Journal of Applied Chemistry, ;2012, 29(8): 938-941. doi: 10.3724/SP.J.1095.2012.00211 shu

Synthesis, Crystal Structure and Magnetic Characterization of Azido-bridged Binuclear Cobalt(Ⅱ) Coordination Polymer

1.
College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumuqi 830054, China

Corresponding author: ,
Received Date: 16 May 2011
Available Online: 15 November 2011
Fund Project: 国家自然科学基金(21065012) (21065012)新疆师范大学博士科研启动基金(XJnubs1102) (XJnubs1102)新疆维吾尔自治区高校科研计划(XJEDU2011S32)资助项目 (XJEDU2011S32)

Using phenanthroline(phen) as an auxiliary azide-bridging ligand,a Co²⁺ coordination polymer [Co₂(μ_1,1-N₃)₂(phen)₂(N₃)₂],was prepared hydrothermally.The complex was characterized by IR,elemental analysis,X-ray single crystal diffraction.The bridging manner of azide in this complex was discussed and the magnetic properties were measured.The complex belongs to the triclinic system(space group of P1) with a=0.69272(14) nm,b=1.0318(2) nm,c=1.0381(2) nm,α=64.47(3)°,β=71.02(3)°,γ=85.79(3)°,Z=1,V=0.6312(2) nm³,D=1.701 mg/m³,F(000)=326.
- coordination polymer,
- azide,
- crystal structures,
- molecular magnetism
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