Citation:
FAN Jiangli, LU Jing, LI Honglin, LIU Xiaojian, ZHU Hao, PENG Xiaojun. An Improved Fluorescence-enhanced Pd2+ Probe Derived from Rhodamine Fluorophore[J]. Chinese Journal of Applied Chemistry,
;2011, 28(11): 1292-1297.
doi:
10.3724/SP.J.1095.2011.00718
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A new fluorescence-enhanced Pd2+ probe RPd5 was synthesized which shows both fluorescent and colorimetric responses to Pd2+ within 16 minutes. The fluorescent intensity was enhanced 40 times. With a pKa value of 3.96 ±0.01, it can detect Pd2+ in a wide pH range, especially in the neutral pH environment. RPd5 has the detection limit of 2.31×10-6 mol/L suggesting its high sensitivity for Pd2+ detection. Proof-ofconcept experiments demonstrate its potential application for Pd2+ detection in real soil and water samples. Additionally, RPd5 can be loaded as test paper for Pd2+ evaluation in the clean water solution.
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Keywords:
- fluorescence probe,
- rhodamine,
- fluorescence-enhanced,
- Pd2+,
- propargyl group
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