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Citation: DENG Quanzhi, HU Bingcheng, SUN Chengguo, XU Shichao, LIU Zuliang. A New Approach to Prepare Deuteroporphyrin and Its Metallo-Complexes[J]. Chinese Journal of Applied Chemistry, ;2011, 28(11): 1263-1268. doi: 10.3724/SP.J.1095.2011.00715 shu

A New Approach to Prepare Deuteroporphyrin and Its Metallo-Complexes

1.
College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094

Corresponding author: HU Bingcheng,
Received Date: 1 December 2010
Available Online: 15 March 2011
Fund Project: 江苏省自然科学基金(BK2009386) (BK2009386)南京理工大学科技发展基金(2010GJPY043)资助项目 (2010GJPY043)

A facile demetalation of deuterohemin(DP) has been developed in a mixed solvent of acetic anhydride and hydrobromic acid. The influences of reaction time, bath temperature and the molar ratio on the yields were also investigated. Under the optimal reaction conditions for the demetalation of DP, the yield of 96.3% is obtained at the temperature of 100℃ for 2 h with the molar ratio of DP, hydrobromic acid and acetic anhydride about 1:6.3:61.2. A series of metallo-deuteroporphyrins was prepared and characterized by electrospray ionization tandem mass spectrometry(ESI-MS-MS), UV-Vis and IR. In addition, we also studied the effects of different solvents on the synthesis of metalloporphyrins, and the properties of metal cations on the shift of S and Q bands of porphyrin.
- deuteroporphyrin,
- deuterohemin,
- synthesis,
- metallo-deuteroporphyrin
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