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Citation: HUA Yingjie, WANG Chongtai, LI Tianlue, HE Mengxiong, XU Kunqin. The Adsorptive Properties of the D301R Resin Towards Nitrobenzene in Aqueous Solution[J]. Chinese Journal of Applied Chemistry, ;2011, 28(9): 1067-1072. doi: 10.3724/SP.J.1095.2011.00631 shu

The Adsorptive Properties of the D301R Resin Towards Nitrobenzene in Aqueous Solution

1.
School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158

Corresponding author: WANG Chongtai,
Received Date: 22 October 2010
Available Online: 25 February 2011
Fund Project: 国家自然科学基金(20963003) (20963003)海南省自然科学基金(509009)资助项目 (509009)

The adsorptive properties of the D301R resin towards nitrobenzene in aqueous solution were investigated in details. The adsorption kinetic curves and adsorption isotherm curves were determined at different temperatures. An adsorption kinetic model was proposed. The equilibrium adsorption capacity, the adsorptive activation energy and the adsorption enthalpy were estimated. The experimental results showed that the adsorption kinetics follows a pseudo-second-order equation controlled by a surface process. The rate constant k₂ is 3.74×10^-2 g/(mg·min) at 300 K, which increases with the increase of temperature. The equilibrium adsorption capacity is 5.02 mg/g at 300 K, which decreases with the increase of temperature. The adsorptive activation energy is 39.02 kJ/mol. The adsorption isotherm is consistent with the Langmuir isotherm and the calculated adsorption enthalpy is about -22.47 kJ/mol. The hydrogen bonding was suggested to be responsible for nitrobenzene adsorption onto D301R resin.
- D301R resin,
- nitrobenzene,
- adsorption kinetics,
- adsorption isotherm
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