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Citation: ZHAO Yan, DENG Jianhui, LIU Meiling, LI Haitao, ZHANG Youyu. Synthesis and Electrochemical Properties of FerroceneTerminated Phenylethynythiol Compounds[J]. Chinese Journal of Applied Chemistry, ;2011, 28(10): 1161-1166. doi: 10.3724/SP.J.1095.2011.00609 shu

Synthesis and Electrochemical Properties of FerroceneTerminated Phenylethynythiol Compounds

ZHAO Yan ^a ,
DENG Jianhui ^a ,
LIU Meiling ^a,, ,
LI Haitao ^a,b,, ,
ZHANG Youyu ^a

1.
a College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 41008;
2.
b Hunan Vocational Institute of Safety Technology, Changsha 410151

Corresponding author: LIU Meiling, LI Haitao,
Received Date: 13 October 2010
Available Online: 19 January 2011
Fund Project: 国家自然科学基金(20975037,21075037) (20975037,21075037)湖南省自然科学基金(09JJ3019,07JJ3024) (09JJ3019,07JJ3024)湖南省教育厅一般目(10C0926)资助项目 (10C0926)

Ferrocene-terminated phenylethynythiol derivatives 1 and 2 were prepared from S-acetyl-4-iodothiophenol(6) or 4-iodophenyl methyl sulfide(7) and ethynylferrocene via cross-coupling reactions.Compounds 6 and 7 were prepared in a good yield with Zn/Me₂SiCl₂/DMA(N,N-dimethylacet amide) reduction system at room temperature instead of traditional low temperature metal lithium system(-78℃).The spectral characteristics,electrochemical properties and self-assembly behaviors of the target compounds on Au modified glassy carbon electrodes(Au/GCE) were investigated.Compound 1 film coated Au/GCE has high electrocatalytic activity toward the oxidation of rutin and has potential applications as biosensor and electrochemical sensor.
- ferrocene-terminated phenylethynythiol,
- self-assembly,
- electrochemical properties,
- chemically modified electrode,
- cross-coupling
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