Citation:
CAI Tiejun, SHEN Xiaoming, LV Shuzi, PENG Zhenshan, LIU Jin, DENG Qian. Hydrothermal Synthesis,Crystal Structure and Catalytic Performance of (C5H7N2)3(AsMo12O40)·3C5H6N2·2H2O[J]. Chinese Journal of Applied Chemistry,
;2011, 28(3): 284-289.
doi:
10.3724/SP.J.1095.2011.00345
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A novel compound, (C5H7N2) 3 (AsMo12O40) ·3C5H6N2·2H2O, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR, UV/Vis and TG-DTA. Using catalytic elimination reaction of acetone as a model reaction, the catalytic performance of the title compound has been tested. The results indicate that the structure of the title compound consists of[AsMo12O40]3- heteropolyoxoanion,[C5H7N2]+ cations,[C5H6N2] molecules and water molecules. The compound crystallizes in the monoclinic, space group P21/n, a=1.33820(12) nm, b=2.2542(2) nm, c=1.9848(2) nm, β=100.27(3) °, V=5.8912(10) nm3, Z=4, Rgt(F)=0.0590, wRref(F2)=0.1882. The compound has a good catalytic activity for the elimination of acetone. When the initial concentration of acetone is 1.3 g/m3 in the air with a flow velocity of 4.5 mL/min, the acetone is completely eliminated at 160℃ over 0.20 g of the title compound.
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