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Citation: ZHANG Lijun, LU Tianhong, LI Shiyin, DU Jiangyan. Fabrication and Application of CAP-MIP-OAP Film Electrode for Chloramphenicol Detection[J]. Chinese Journal of Applied Chemistry, ;2011, 28(3): 338-342. doi: 10.3724/SP.J.1095.2011.00295 shu

Fabrication and Application of CAP-MIP-OAP Film Electrode for Chloramphenicol Detection

1.
Jiangsu Key Laboratory of Bio-functional Materials, College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210046

Corresponding author: DU Jiangyan,
Received Date: 18 May 2010
Available Online: 25 July 2010

The chloramphenicol(CAP) molecule-imprinted polymer(MIP) of o-aminophenol(OAP) on Pt (CAP-MIP-OAP/Pt) electrode was prepared via an electrochemical polymerization method using OAP as the functional monomer and CAP as the template molecule. This preparation method is simple. The as-prepared membrane is uniform and stable. The performances and configurations of the CAP-MIP-OAP/Pt and MIPOAP/Pt electrodes were investigated using scanning electron microscope (SEM) and electrochemical techniques. The results illustrated that the MIP-OAP/Pt electrode exhibited improved selectivity and sensitivity for the CAP detection. A linear region of the CAP detection is in the range of 4.33×10^-8~3.09×10^-6 mol/L. The detection limit is 2.5×10^-8 mol/L. Therefore, the MIP-OAP/Pt electrode shows potential application for the enrichment and detection of CAP in the environmental water sample.
- electrochemical polymerization,
- chloramphenicol,
- o-aminophenol,
- molecular imprinted polymer film,
- electrochemical detection
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