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Citation: JIA Baozhu, WANG Honghua, ZHOU Guangyuan, CUI Shanzi. Preparation of Linear Chloromethylated Phenophthalein Polyether Sulfone with 1,4-Bis(chloromethoxyl) butane as Chloromethylation Reagent[J]. Chinese Journal of Applied Chemistry, ;2011, 28(12): 1360-1363. doi: 10.3724/SP.J.1095.2011.00035 shu

Preparation of Linear Chloromethylated Phenophthalein Polyether Sulfone with 1,4-Bis(chloromethoxyl) butane as Chloromethylation Reagent

1.
a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b School of Chemical Engineering, Changchun University of Technology, Changchun 130012

Corresponding author: ZHOU Guangyuan, CUI Shanzi,
Received Date: 19 January 2011
Available Online: 8 March 2011
Fund Project: 吉林省科技发展重大项目(20106017) (20106017)

Chloromethylation of phenophthalein polyether sulfone(PES-C) was performed in a homogeneous system using 1,4-bis(chloromethoxyl) butane(BCMB) as the chloromethylation reagent.Chloromethylation of PES-C(CMPES-C) with an appropriate chloromethylation degree and complete linearity was obtained under the optimum reaction conditions.The chemical structures and compositions of the products were characterized by IR and ¹H NMR.The chloromethylation degree and properties of CMPES-C,such as solubility in common organic solvents and thermal stability compared with phenophthalein polyether ketone(PEK-C) were also discussed.The chloromethylation degree was determined by ¹H NMR integration.
- bis(chloromethoxyl) butane,
- chloromethylation modification,
- phenophthalein polyether sulfone
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