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Citation: BIAN Chang-Hua, XU Xing-You, YAO Cheng, YIN De-Shuai, FAN Ying-Ying. Synthesis,Crystal Structure and Antimicrobial Activity of a Co(Ⅱ) Polyamine Complex[J]. Chinese Journal of Applied Chemistry, ;2010, 27(3): 295-299. doi: 10.3724/SP.J.1095.2010.90218 shu

Synthesis,Crystal Structure and Antimicrobial Activity of a Co(Ⅱ) Polyamine Complex

a. College of Life Science and Chemical Engineering, Huaiyin institute of Technology, Huaiyin 223000;
b. College of Science, Nanjing University of Technology, Nanjing 210009;
c. Department of Chemistry, Jiangsu Polytechnic University, Changzhou

Received Date: 31 March 2009
Revised Date: 6 July 2009

A new organic polyamine(1-(N,N-2-aminopropyl) aminoethyl-4-aminopropyl piperazine) was synthesized from 1-(2-aminoethyl)piperazine and acrylonitrile.Using this polyamine ligand purple needle single crystals of[Co(L)HCl](ClO₄)₂ was synthesized.The compound was characterized by elemental analysis,molar conductivity and X-ray single crystal analysis.X-ray data reveals that the title complex crystallized in the orthorhombic system,with space group I4/m,a=2.5006(3),b=2.5006(3),c=0.85615(11) nm,M_r=594.79,V=5.3534(10) nm³,Z=8,F(000)=2488,D_c=1.476 g/cm³,μ(MoKα)=0.989 mm^-1,R₁=0.0666,wR₂=0.1852(I>2σ(I)).The complex showed a certain anti-bacteriostatic property to staphylococcus aureus,escherichia coli,bacillus subtilis and marine vibrio using an agar diffusion antimicrobial test.
- polyamines,
- complex,
- crystal structure,
- antimicrobial
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