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Citation: YIN Sheng, WANG Kun, LUO Zhi-Jun, XIA Jie-Xiang, LI Hua-Ming. Preparation of Ni Microspheres Doped with Carbon and Their Electrocatalytic Activity for the Oxidation of Glucose[J]. Chinese Journal of Applied Chemistry, ;2010, 27(12): 1430-1433. doi: 10.3724/SP.J.1095.2010.00096 shu

Preparation of Ni Microspheres Doped with Carbon and Their Electrocatalytic Activity for the Oxidation of Glucose

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013

Received Date: 5 February 2010
Revised Date: 8 May 2010

Ni(OH)₂ doped with carbon(C-Ni(OH)₂) microsphere was prepared by the hydrothermal method via starting with sodium gluconate and nitrate nickel. The precipitant OH^- comes from the hydrolysis of sodium gluconate's carboxylic acid. The as-prepared C-Ni(OH)₂ microsphere was adopted as the precursor for fabricating Ni doped with carbon(C-Ni) microsphere by calcined 8 h at 600℃ in N₂,and the resulting C-Ni microsphere was further characterized by FE-SEM,XRD,EDS,and BET,verifying the C-Ni microsphere possess considerable large surface area and pore volume of about 276 m²/g and 0.248cm³/g,respectively. Finally,the electrochemical experiment showed that C-Ni microsphere exhibited good electrocatalytic activity toward the oxidation of glucose.
- carbon doped,
- Ni microsphere,
- hydrothermal method,
- glucose,
- electrocatalytic oxidation
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