Citation: Si-Jia LU, Zhuo XING, Rui-Qin YANG. Detection of Metal Imprints on Non-porous Surfaces[J]. Chinese Journal of Applied Chemistry, ;2021, 38(1): 116-122. doi: 10.19894/j.issn.1000-0518.200155 shu

Detection of Metal Imprints on Non-porous Surfaces

  • Corresponding author: Rui-Qin YANG, yangruiqin@ppsuc.edu.cn
  • Received Date: 22 May 2020
    Accepted Date: 21 July 2020

    Fund Project: the Innovation Personnel Training Project of People′s Public Security University of China in 2020 2020ssky006the Fund of Liu Yao Academician of Chinese Academy of Engineering 2019-YZ-01

Figures(9)

  • A new method of visualizing metal imprints on non-porous surfaces was studied using 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol as the chromogenic reagent. The affecting factors such as contact time, time elapse from the contact to the reaction, type of substrates and transfer times were studied. The results show that imprints with good quality are obtained when the contact time is more than 1 s, the time interval is between 1~30 days and the metal imprints within 5 deposition times after the contact between hands and metal tools for 90 s. This method has the advantages of high sensitivity and easy operation and is used to establish the connection between suspects and metal tools, which has potential applications in forensic science.
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    1. [1]

      XING Z, YANG R Q. Chromogenic detection of imprints left by zinc coatings on human skins by 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol[J]. Chinese J Appl Chem, 2015,32(9):1093-1098.  

    2. [2]

      United States of America. Trace Metal Detection Techniques in Law Enforcement[M]. Bureau of Justice Statistics, 1970.

    3. [3]

      STEVENS J M, MESSLER H. The trace metal detection technique(TMDT): a report outlining a procedure for photographing results in color, and some factors influencing the results in controlled laboratory tests[J]. J Forensic Sci, 1974,19(3):496-503.  

    4. [4]

      GOLDMAN G L, THORNTON J I. A new trace ferrous metal detection reagent[J]. J Forensic Sci, 1976,21(3):625-628.  

    5. [5]

      LEE C W, PHIL M. The detection of iron traces on hands by ferrozine sprays: a report on the sensitivity and interference of the method and recommended procedure in forensic science investigation[J]. J Forensic Sci, 1986,31(3):920-930.  

    6. [6]

      ALMOG J, HIRSHFELD A, GLATTSTEIN B. Chromogenic reagents for iron(Ⅱ): studies in the 1, 2, 4-triazine series[J]. Anal Chim Acta, 1996,322(3):203-208. doi: 10.1016/0003-2670(95)00605-2

    7. [7]

      AVISSAR Y Y, SAGIV A E, DANIEL M. Identification of firearms handling by the[Fe(PDT)3]2+ complex: chemical and time-dependent factors[J]. Talanta, 2005,67(2):328-333. doi: 10.1016/j.talanta.2005.01.032

    8. [8]

      ALMOG J, BAR-OR K L, LEIFER A. Detection of recent holding of firearms: improving the sensitivity of the PDT test[J]. Forensic Sci Int, 2014(241):55-59.  

    9. [9]

      OLEJNICZAK A, CYGANIUK A W, LUKASZEWICZ J P. 1, 2, 4-Triazine-based chromogenic reagents for the detection of microtraces of various metals left on human skin[J]. J Forensic Sci, 2010,55(3):747-752. doi: 10.1111/j.1556-4029.2010.01350.x

    10. [10]

      XING Z, YANG R Q. Improvement techniques of the imprint left by metal tools on human skins with 5-Br-PADAP reagents[J]. Chem Reag, 2015,37(11):1009-1014.  

    11. [11]

      YANG R Q, XING Z, ZHOU H. Spectrophotometric determination of the amount of zinc on the imprint left on hands by zinc coatings with 5-Br-PADAP as the chromogenic reagent[J]. Spectrosc Spectr Anal, 2016,36(12):4017-4020.  

    12. [12]

      BLEAY S M, GROVE L E, KELLY P F. Non-invasive detection and chemical mapping of trace metal residues on the skin[J]. RSC Adv, 2014,4(37)19525. doi: 10.1039/c4ra02463j

    13. [13]

      XING Z, YANG R Q, LIU W. A modified trace metal detection test for secondary imprints on porous substrates: a preliminary study[J]. Forensic Sci Int, 2019(260):28-38.  

    14. [14]

      XING Z, YANG D S, ZHOU H. Intergrated detection of latent fingerprints and imprints left by metallic tools on porous substrates[J]. Chem Reag, 2019,41(3):288-293.  

    15. [15]

      XING Z, LU S J, WANG A H, et al. A subsequent procedure for further deciphering weapons after application of the trace metal detection test (TMDT): proof of concept[J/OL]. Forensic Sci Int, 2020(310): 110253. http://dx.doi.org/10.1016/j.forsciint.2020.110253/pdf. [published online ahead of print].

    16. [16]

      WEI F S, ZHU Y R, SHEN N K. High sensitive chromogenie reagent 5-Br-PADAP[J]. Chem Reag, 1980(1):54-57.  

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