Citation: ZHANG Lu, WANG Haichang, LI Hua, WANG Huijun, HUI Linhai, PENG Meiling, ZHU Yutian. Progress of Recycling of Carbon Fiber/Resin Composites via Supercritical Fluid[J]. Chinese Journal of Applied Chemistry, ;2020, 37(12): 1357-1363. doi: 10.11944/j.issn.1000-0518.2020.12.200173 shu

Progress of Recycling of Carbon Fiber/Resin Composites via Supercritical Fluid

ZHANG Lu ^a ,
WANG Haichang ^b ,
LI Hua ^a ,
WANG Huijun ^a ,
HUI Linhai ^a,, ,
PENG Meiling ^c ,
ZHU Yutian ^c,,

a.
Shandong Non-Metallic Materials Institute, Ji'nan 250031, China
b.
Engineering & Design Institution of Air Force Academy, Beijing 100068, China
c.
College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China

Corresponding author: HUI Linhai, huilinhai@163.com ZHU Yutian, ytzhu@hznu.edu.cn
Received Date: 8 June 2020
Revised Date: 13 July 2020
Accepted Date: 20 August 2020

Fund Project: the Shandong Province Major Science and Technology Innovation Project 2018CXGC0406Supported by the Shandong Province Major Science and Technology Innovation Project(No.2018CXGC0406)

Figures(5)

The recycling of carbon fiber/resin composites (CFRC) is critical for the sustainable development of carbon fiber industry and has received intensive attention from both the academy and industry. Recycling CFRC via supercritical fluid (SCF) is an effective and clean technique to recycle carbon fibers without damaging the properties of the carbon fibers. This article reviews the recent progress of the recycling of CFRC via SCF. The influence of the SCF system, reaction condition, and catalyst on recycling of carbon fibers are systematically discussed. Finally, the future development of the recycling of CFRC via SCF is also discussed in this article.
- supercritical fluid,
- carbon fiber/epoxy resin composites,
- recycle
1. [1]
  Huang J R, Mao C, Zhu Y T. Control of Carbon Nanotubes at the Interface of a Co-continuous Immiscible Polymer Blend to Fabricate Conductive Composites with Ultralow Percolation Thresholds[J]. Carbon, 2014,73(1):267-274.
2. [2]
  Chen J W, Li H, Yu Q Z. Strain Sensing Behaviors of Stretchable Conductive Polymer Composites Loaded with Different Dimensional Conductive Fillers[J]. Compos Sci Technol, 2018,168:388-396.
3. [3]
  Mao C, Huang J R, Zhu Y T. Tailored Parallel Graphene Stripes in Plastic Film with Conductive Anisotropy by Shear-Induced Self-assembly[J]. J Phys Chem Lett, 2013,4(1):43-47.
4. [4]
  Huang J R, Zhu Y T, Jiang W. Parallel Carbon Nanotube Stripes in Polymer Thin Film with Tunable Microstructures and Anisotropic Conductive Properties[J]. Compos Part A-Appl S, 2015,69:240-246.
5. [5]
  Chen J W, Cui X H, Zhu Y T. Design of Superior Conductive Polymer Composite with Precisely Controlling Carbon Nanotubes at the Interface of a Co-Continuous Polymer Blend via a Balance of π-π Interactions and Dipole-Dipole Interactions[J]. Carbon, 2017,114:441-448.
6. [6]
  Cui X H, Chen J W, Zhu Y T. Lightweight and Conductive Carbon Black/Chlorinated Poly(propylene carbonate) Foams with a Remarkable Negative Temperature Coefficient Effect of Resistance for Temperature Sensor Applications[J]. J Mater Chem C, 2018,6:9354-9362.
7. [7]
  Huang J R, Li N, Xiao L. Fabrication of a Highly Tough, Strong, and Stiff Carbon Nanotube/Epoxy Conductive Composite with an Ultralow Percolation Threshold via Self-assembly[J]. J Mater Chem A, 2019,7:15731-15740.
8. [8]
  Chen J W, Yu Q L, Cui X H. An Overview of Stretchable Strain Sensors from Conductive Polymer Nanocomposites[J]. J Mater Chem C, 2019,7:11710-11730.
9. [9]
  Cui X H, Chen J W, Zhu Y T. Natural Sunlight-Actuated Shape Memory Materials with Reversible Shape Change and Self-healing Abilities Based on Carbon Nanotubes Filled Conductive Polymer Composites[J]. Chem Eng J, 2020,382122823.
10. [10]
  Chen J W, Zhu Y T, Huang J R. Advances in Responsively Conductive Polymer Composites and Sensing Applications[J]. Polym Rev, 2020. doi: 10.1080/15583724.2020.1734818
11. [11]
  Chen J W, Zhu Y T, Jiang W. A Stretchable and Transparent Strain Sensor Based on Sandwich-Like PDMS/CNTs/PDMS Composite Containing an Ultrathin Conductive CNT Layer[J]. Compos Sci Technol, 2020,186107938.
12. [12]
  Chen J W, Cui X H, Sui K Y. Balance the Electrical Properties and Mechanical Properties of Carbon Black Filled Immiscible Polymer Blends with a Double Percolation Structure[J]. Compos Sci Technol, 2017,140:99-105.
13. [13]
  ZHOU Chuanlei, AI Hui, YAN Yongjun. Industrial Status of Carbon Fiber[J]. Chem Eng, 2010(8):42-43.
14. [14]
  REN Yan. Recycling and Utilization of Carbon Fiber Composites[J]. New Mater Ind, 2014(8):19-22.
15. [15]
  Sugeta T, Nagaoka S, Otake K. Decomposition of Fiber Reinforced Plastics Using Fluid at High Temperature and Pressure[J]. Kobunshi Ronbunshu, 2001,58:557-563(in Japanese).
16. [16]
  Piñ ero-Hernanz R, Dodds C, Hyde J. Chemical Recycling of Carbon Fibre Reinforced Composites in Nearcritical and Supercritical Water[J]. Compos Part A-Appl S, 2008,39:454-461.
17. [17]
  Okajima I, Sako T. Recycling of Carbon Fiber-Reinforced Plastic Using Supercritical and Subcritical Fluids[J]. J Mater Cycles Waste Manage, 2017,19:15-20.
18. [18]
  Okajima I, Hiramatsu M, Sako T. Recycling of Carbon Fiber Reinforced Plastics Using Subcritical Water[J]. Adv Mater Res, 2011,222:243-246.
19. [19]
  CHENG Huanbo. Supercritical Fluid Recovery Mechanism and Process Research of Carbon Fiber/Epoxy Composites[D]. Hefei: Hefei University Technology, 2016
20. [20]
  Piñero-Hernanz R, García-Serna J, Dodds C. Chemical Recycling of Carbon Fibre Composites Using Alcohols Under Subcritical and Supercritical Conditions[J]. J Supercrit Fluids, 2008,46:83-92.
21. [21]
  Hyde J R, Lester E, Kingman S. Supercritical Propanol, A Possible Route to Composite Carbon Fibre Recovery:Aviability Study[J]. Compos Part A-Appl S, 2006,37:2171-2175.
22. [22]
  Jiang G, Pickering S J, Lester E H. Characterisation of Carbon Fibres Recycled from Carbon Fibre/Epoxy Resin Composites Using Supercritical n-Propanol[J]. Comps Sci Technol, 2009,69:192-198.
23. [23]
  HUANG Haihong, ZHAO Zhipei, CHENG Huanbo. Degradation Effects of Supercritical Fluids on Carbon Fiber/Epoxy Composites[J]. Acta Mater Compos Sin, 2016,33(8):1621-1629.
24. [24]
  Oliveux G, Dandy L O, Leeke G A. Degradation of a Model Epoxy Resin by Solvolysis Routes[J]. Polym Degrad Stab, 2015,188:96-103.
25. [25]
  HUANG Haihong, ZHANG Baoyu, CHENG Huanbo. Degradation Effects of Supercritical Water/n-Butanol Mixture on CF/EP Composites[J]. J Mater Sci Eng, 2019,37(2):189-194.
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