Citation: WANG Yichen, LUO Jing, LIU Ren, DAI Shenghua. Progress in Preparation of Graphene Hollow Microspheres[J]. Chinese Journal of Applied Chemistry, ;2020, 37(12): 1374-1383. doi: 10.11944/j.issn.1000-0518.2020.12.200163 shu

Progress in Preparation of Graphene Hollow Microspheres

WANG Yichen ^a ,
LUO Jing ^a,, ,
LIU Ren ^a ,
DAI Shenghua ^b

a.
School of Chemical and Material Engineering Jiangnan University, Wuxi, Jiangsu 214000, China
b.
Wuxi Aibang Special Electric Wire Co., Ltd, Wuxi, Jiangsu 214000, China

Corresponding author: LUO Jing, jingluo19801007@126.com
Received Date: 1 June 2020
Revised Date: 22 June 2020
Accepted Date: 23 July 2020

Fund Project: the National Natural Science Foundation of China 51873080Supported by the National Natural Science Foundation of China(No.51873080)

Figures(6)

With excellent electrical conductivity, mechanical properties and large specific surface areas, graphene is a new material with great potentials. However, graphene is prone to stacking because of the intermolecular forces and π-π interaction between sheets. Constructing a three-dimensional hollow microsphere structure not only effectively prevents the agglomeration of graphene sheets, ensures a large specific surface area and excellent properties, but also has unique advantages of regular structures and adjustable sizes. This article describes the preparation methods of graphene hollow microspheres reported in recent years. It is mainly arranged and analyzed according to two major categories:template method and templateless method, and the template method is divided into two categories:hard template method and soft template method. Introductions and examples of various technologies applied in the preparation of graphene hollow microspheres are presented. The review concludes with the analyses and summaries of the hard template method, soft template method and templateless method respectively, as well as a discussion of future perspectives.
- graphene,
- hollow microspheres,
- preparation method
1. [1]
  Lee T, Min S H, Gu M. Layer-by-layer Assembly for Graphene-based Multilayer Nanocomposites:Synthesis and Applications[J]. Chem Mater, 2015,27:3785-3796. doi: 10.1021/acs.chemmater.5b00491
2. [2]
  Jiang L, Fan Z. Design of Advanced Porous Graphene Materials:From Graphene Nano Mesh to 3D Architectures[J]. Nanoscale, 2014,6:1922-1945. doi: 10.1039/C3NR04555B
3. [3]
  Li S, Pasc A, Fierro V, Celzard A. Hollow Carbon Spheres, Synthesis and Applications-A Review[J]. J Mater Chem A, 2016,4:12686-12713. doi: 10.1039/C6TA03802F
4. [4]
  Liu T, Zhang L Y, Cheng B. Hollow Carbon Spheres and Their Hybrid Nanomaterials in Electrochemical Energy Storage[J]. Adv Energy Mater, 2019,9:1614-6832.
5. [5]
  Yan W, Wang L, Chen C. Polystyrene Microspheres-Templated Nitrogen-Doped Graphene Hollow Spheres as Metal-Free Catalyst for Oxygen Reduction Reaction[J]. Electrochim Acta, 2016,188:230-239. doi: 10.1016/j.electacta.2015.11.146
6. [6]
  Jiang Z, Zhao X, Tian X. Hydrothermal Synthesis of Boron and Nitrogen Codoped Hollow Graphene Microspheres with Enhanced Electrocatalytic Activity for Oxygen Reduction Reaction[J]. ACS Appl Mater Interfaces, 2015,7:19398-19407. doi: 10.1021/acsami.5b05585
7. [7]
  Trung N B, Van Tam T, Kim H R. Three-Dimensional Hollow Balls of Graphene-Polyaniline Hybrids for Supercapacitor Applications[J]. Chem Eng J, 2014,255:89-96. doi: 10.1016/j.cej.2014.06.028
8. [8]
  Fan W, Zhang C, Tjiu W W. Graphene-wrapped Polyaniline Hollow Spheres as Novel Hybrid Electrode Materials for Supercapacitor Applications[J]. ACS Appl Mater Interfaces, 2013,5:3382-3391. doi: 10.1021/am4003827
9. [9]
  Hong J, Char K, Kim B S. Hollow Capsules of Reduced Graphene Oxide Nanosheets Assembled on a Sacrificial Colloidal Particle[J]. J Phys Chem Lett, 2010,1(24):3442-3445. doi: 10.1021/jz101441a
10. [10]
  Fan W, Xia Y, Tjiu W. Nitrogen-doped Graphene Hollow Nanospheres as Novel Electrode Materials for Supercapacitor Applications[J]. J Power Sources, 2013,243:973-981. doi: 10.1016/j.jpowsour.2013.05.184
11. [11]
  Luo J, Ma Q, Gu H. Three-dimensional Graphene-Polyaniline Hybrid Hollow Spheres by Layer-by-Layer Assembly for Application in Supercapacitor[J]. Electrochim Acta, 2015,173:184-192. doi: 10.1016/j.electacta.2015.05.053
12. [12]
  Yang D, Chen S, Huang P. Bacteria-Template Synthesized Silver Microspheres with Hollow and Porous Structures as Excellent SERS Substrate[J]. Green Chem, 2010,12:2038-2042. doi: 10.1039/c0gc00431f
13. [13]
  Wang S, Gu F, L M K. Sonochemical Synthesis of Hollow PbS Nanospheres[J]. Langmuir, 2006,22:398-401. doi: 10.1021/la0518647
14. [14]
  Chen G, Xia D, Nie Z. Facile Synthesis of Co-Pt Hollow Sphere Electrocatalyst[J]. Chem Mater, 2007,19:1840-1844. doi: 10.1021/cm062336z
15. [15]
  Sohn K, Joo Na Y, Chang H. Oil Absorbing Graphene Capsules by Capillary Molding[J]. Chem Commun, 2012,48:5968-5970. doi: 10.1039/c2cc32049e
16. [16]
  Byun A, Shim J, Han S W. One-pot Microfluidic Fabrication of Graphene Oxide-patched Hollow Hydrogel Microcapsules with Remarkable Shell Impermeability[J]. Chem Commun, 2015,51:12756-12759. doi: 10.1039/C5CC04547A
17. [17]
  Guo P, Song H, Chen X. Hollow Graphene Oxide Spheres Self-assembled by W/O Emulsion[J]. J Mater Chem, 2010,20:4867-4874. doi: 10.1039/b927302f
18. [18]
  Luo Q, Wei P, Pentzer E. Hollow Microcapsules by Stitching Together of Graphene Oxide Nanosheets with a Di-functional Small Molecule[J]. Carbon, 2016,106:125-131. doi: 10.1016/j.carbon.2016.05.024
19. [19]
  Thickett S C, Wood N, Ng Y H. Hollow Hybrid Polymer-Graphene Oxide Nanoparticles via Pickering Miniemulsion Polymerization[J]. Nanoscale, 2014,6:8590-8594. doi: 10.1039/C4NR01175A
20. [20]
  Teo G H, Ng Y H, Zetterlund P B. Factors Influencing the Preparation of Hollow Polymer-Graphene Oxide Microcapsules via Pickering Miniemulsion Polymerization[J]. Polymer, 2015,63:1-9. doi: 10.1016/j.polymer.2015.02.035
21. [21]
  Ali M, Meaney S P, Abedin M J. Graphene Oxide-silica Hybrid Capsules for Sustained Fragrance Release[J]. J Colloid Interface Sci, 2019,552:528-539. doi: 10.1016/j.jcis.2019.05.061
22. [22]
  Luo J, Chen Y, Zheng Y. Hollow Graphene-Polyaniline Hybrid Spheres Using Sulfonated Graphene as Pickering Stabilizer for High Performance Supercapacitors[J]. Electrochim Acta, 2018,272:221-232. doi: 10.1016/j.electacta.2018.04.011
23. [23]
  Hu J, Chen M, Fang X. Fabrication and Application of Inorganic Hollow Spheres[J]. Chem Soc Rev, 2011,40:5472-5491. doi: 10.1039/c1cs15103g
24. [24]
  Liu B, Zeng H. Symmetric and Asymmetric Ostwald Ripening in the Fabrication of Homogeneous Core-Shell Semiconductors[J]. Small, 2005,1:566-571. doi: 10.1002/smll.200500020
25. [25]
  Ostwald W. Vber die Vermeintliche Isomerie des Roten und Gelben Quecksilberoxyds und die Oberflächenspannung Fester Körper[J]. Z Phys Chem, 1900,34(1):495-503.
26. [26]
  Kim K, Voorhees P W. Ostwald Ripening of Spheroidal Particles in Multicomponent Alloys[J]. Acta Mater, 2018,152:327-337. doi: 10.1016/j.actamat.2018.04.041
27. [27]
  Bera S, Pal M, Naskar A. Hierarchically Structured ZnO-Graphene Hollow Microspheres Towards Effective Reusable Adsorbent for Organic Pollutant via Photodegradation Process[J]. J Alloy Compd, 2016,669:177-186. doi: 10.1016/j.jallcom.2016.02.007
28. [28]
  CHEN Chen. Preparation of Crimpled Graphene Micro-spheres and Its Applications in Composites[D]. Zhejiang: Zhejiang University, 2018.
29. [29]
  Mei R, Song X, Hu Y. Hollow Reduced Graphene Oxide Microspheres as a High-Performance Anode Material for Li-Ion Batteries[J]. Electrochim Acta, 2015,153:540-545. doi: 10.1016/j.electacta.2014.05.154
30. [30]
  Wang Y, Cao J, Rao J. Electron Beam "Ballooned" Carbon Sphere Derived from Graphene Oxide by a Hydrazine Assisted Hydrothermal Method[J]. RSC Adv, 2014,4:5826-5829. doi: 10.1039/c3ra46027d
31. [31]
  MU Ya'nan. Study on the Preparation of GR/CNTs/MnO₂ Hollow Composite Microspheres and Its Application in Supercapacitors[D]. Shanxi: Northwest University, 2017。
32. [32]
  ZENG Qiang. Design and Preparation of Magnetic Particles-Cotaining Graphene Hollow Micropheres and Their Microwave Absorption Performance[D]. Dalian: Dalian University of Technology, 2017
33. [33]
  XU Zehai. Design of Novel Functionalized Hollow Microspheres and Composites for Versatile Purposes[D]. Zhejiang: Zhejiang University of Technology, 2017.
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