Citation: LIU Lixin, DONG Jianhong, ZHANG Guanghui, ZHU Luyi, WANG Xinqiang, XU Dong, CHOW Yuktak. Preparation and Properties of Polyvinylidene Fluoride@Diatomite Fiber Membranes by Eletrospinning as Separator of Lithium-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2020, 37(12): 1441-1446. doi: 10.11944/j.issn.1000-0518.2020.12.200149 shu

Preparation and Properties of Polyvinylidene Fluoride@Diatomite Fiber Membranes by Eletrospinning as Separator of Lithium-Ion Batteries

a.
State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Ji'nan 250100, China
b.
Department of Electrical Engineering, City University of Hong Kong, Hong Kong, China

Corresponding author: ZHANG Guanghui, ghzhang@sdu.edu.cn
Received Date: 18 May 2020
Revised Date: 29 June 2020
Accepted Date: 5 August 2020

Fund Project: the National Natural Science Foundation of China 51472144the Fundamental Research Funds for the Central Universities 2082019014Supported by the National Natural Science Foundation of China(No. 51472144), Shandong University Young Scholars Program(No.2016WLJH27) and the Fundamental Research Funds for the Central Universities(No.2082019014)Shandong University Young Scholars Program 2016WLJH27

Figures(8)

Using polyvinylidene fluoride (PVDF) and diatomite as raw materials, PVDF@diatomite composite fiber membranes were prepared by electrospinning for lithium-ion battery. The electrolyte absorption rate, thermal stability and electrochemical properties of the separators were investigated. The addition of diatomite can effectively improve the electrolyte absorption rate and electrochemical performance of the composite separators. The electrolyte uptake is up to 623.6%. Compared with PVDF and polypropylene (PP) separators, it has excellent cycle and rate performance.
- lithium-ion battery,
- separator,
- polyvinylidene fluoride,
- diatomite
1. [1]
  MO Mingyue, CHEN Hongyu. Research Progress on Separator Materials for Lithium-Ion Batteries[J]. Chinese J Power Sources, 2011,35(11):1438-1440, 1466.
2. [2]
  CHEN Meng. Battery Separators Consisting of Polyphenylene Sulfide Nonwovens Modified by Silicone or Silica Ceramic Slurry[D]. Wuhan: Wuhan Textile University, 2017(in Chinese).
3. [3]
  HU Jiwen, XU Kai, SHEN Jiarui. Research and Development of Separators for Lithium-Ion Batteries[J]. Polym Mater Sci Eng, 2003(1):215-219.
4. [4]
  ZHANG Chuanwen, YAN Yurong, QU Weifeng. Review on Membrane in Lithium-Ion Battery Prepared by Electrospinning[J]. Technol Text, 2009,27(1):1-6.
5. [5]
  YU Jianxiang, LIU Taiqi. Research Development of Electrospinning Preparation of Lithium Ion Battery Septum[J]. New Technol New Process, 2012(5):61-64.
6. [6]
  GONG Wenzheng, GU Junfeng, RUAN Shilun. Preparation of High-Strength Polyvinylidene Fluoride Lithium-Ion Battery Separator by Electrospinning[J]. Polym Mater Sci Eng, 2019,35(3):148-155.
7. [7]
  LI Xiaoyun. Electrochemical Performance and Preparation of Electrospun PVDF/PMMA Membranes for Lithium Ion Battery[D]. Xiangtan: Xiangtan University, 2011(in Chinese).
8. [8]
  Costa C M, Kundu M, Cardoso V F. Silica/Poly(vinylidene fluoride) Porous Composite Membranes for Lithium-Ion Battery Separators[J]. J Membr Sci, 2018,564:842-851.
9. [9]
  Bhute M V, Mitra S, Kondawar S B. Improved Performance of Silver Doped Titania/Poly(vinylidine fluoride) Nanofibers Polymer Electrolyte for Lithium Ion Battery[J]. Mater Lett, 2019,236:225-228.
10. [10]
  Fang C J, Yang S L, Zhao X F. Electrospun Montmorillonite Modified Poly(vinylidene fluoride) Nanocomposite Separators for Lithium-Ion Batteries[J]. Mater Res Bull, 2016,79:1-7.
11. [11]
  XUE Bing, LI Dongni, MIAO Shiding, et al. Diatomite Membrane for Lithium Ion Battery and Preparation Method: CN108232089B[P]. 2019-09-20(in Chinese).
12. [12]
  SUN Meiling, TANG Haolin, PAN Mu. A Review on the Separators of Power Li-Ion Batteries[J]. Mater Rev, 2011,25(9):44-50.
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
10. [10]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
11. [11]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
12. [12]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
13. [13]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
14. [14]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
15. [15]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
16. [16]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
19. [19]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
20. [20]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(708)
HTML views(188)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142