Citation: GUO Wei, WANG Yaming, JIANG Lihong, ZHENG Yan'e, LIU Biying. Preparation of Sulfonated Chiral Nematic Mesoporous Silicate Solid Acid and Its Catalytic Synthesis of Borneol[J]. Chinese Journal of Applied Chemistry, ;2020, 37(12): 1447-1456. doi: 10.11944/j.issn.1000-0518.2020.12.200097 shu

Preparation of Sulfonated Chiral Nematic Mesoporous Silicate Solid Acid and Its Catalytic Synthesis of Borneol

Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

Corresponding author: WANG Yaming, wym@kmust.edu.cn
Received Date: 3 April 2020
Revised Date: 13 July 2020
Accepted Date: 19 August 2020

Fund Project: Yunnan Rosin High Efficiency Development and Utilization Research 649220130010Supported by Yunnan Rosin High Efficiency Development and Utilization Research(No.649220130010)

Figures(10)

Chiral nematic mesoporous silicate (CNMS) was prepared by a sol-gel method and sulfonated CNMS-SO₃H solid acid catalyst was prepared by an impregnation method. The structure and properties of the catalysts were characterized by BET, powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy analysis (FT-IR), NH₃-TPD and Py-FTIR. When the molar ratio of amount of substance of α-pinene to oxalic acid is 1:0.4, the mass ratio of CNMS-SO₃H catalyst to turpentine oil is 7:100, the temperature is 100℃ and the time is 8 h, the conversion of α-pinene is 100% and the yield of borneol is 49.89% and the amount of borneol is 4 times of that of isoborneol. The solid acid catalyst has good catalytic activity and stability. After 8 times of reuse, the conversion of α-pinene is over 99%.
- sulfonated chiral nematic mesoporous silicate,
- solid acid,
- esterification,
- borneol
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