Citation: YAO Meiren, WANG Kangjun, ZHANG Yajing, WANG Dongping. Application of Sterically Hindered Chiral (Pyrrolidine Salen) Mn(Ⅲ) Complex in Asymmetric Epoxidation of Alkenes[J]. Chinese Journal of Applied Chemistry, ;2020, 37(8): 889-895. doi: 10.11944/j.issn.1000-0518.2020.08.200140 shu

Application of Sterically Hindered Chiral (Pyrrolidine Salen) Mn(Ⅲ) Complex in Asymmetric Epoxidation of Alkenes

a.
College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
b.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: WANG Dongping, dpwang2015@163.com
Received Date: 13 May 2020
Revised Date: 29 May 2020
Accepted Date: 2 June 2020

Fund Project: the Shenyang University of Chemical Technology XXLQ2019001the Department of Education of Liaoning Province L2016003the State Key Laboratory of Fine Chemicals KF1610Supported by the Department of Education of Liaoning Province (No. L2016003), the State Key Laboratory of Fine Chemicals (No. KF1610) and the Shenyang University of Chemical Technology (No. XXLQ2019001)

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A new sterically hindered chiral (pyrrolidine salen)Mn(Ⅲ) complex Mn3 was synthesized and employed in the asymmetric epoxidation of alkenes in NaClO aqueous/organic biphasic system. Complex Mn3 bearing tertiary amine unit displays higher activity, comparable yield and slightly higher enantioselectivity as compared with Jacobsen's catalyst. Especially, adding excess CH₃I into the catalytic system can greatly shorten the reaction time while maintaining high yield and high enantioselectivity.
- chiral(salen)Mn(Ⅲ) complex,
- alkene,
- asymmetric epoxidation,
- catalytic activity,
- enantioselectivity
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