Citation: DONG Yilin, ZHANG Hao, CHEN Jinlong. Preparation of Cosmetic-Grade Sodium Polyaspartate[J]. Chinese Journal of Applied Chemistry, ;2020, 37(8): 883-888. doi: 10.11944/j.issn.1000-0518.2020.08.200062 shu

Preparation of Cosmetic-Grade Sodium Polyaspartate

DONG Yilin ^a,b ,
ZHANG Hao ^a ,
CHEN Jinlong ^b,,

a.
College of Food Science and Engineering, Jilin Agricultural University, Changchun 130118, China
b.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: CHEN Jinlong, chenjl2015@ciac.ac.cn
Received Date: 10 March 2020
Revised Date: 15 April 2020
Accepted Date: 9 May 2020

Fund Project: Supported by the National Natural Science Foundation of China(No.21805272, No.31801477)the National Natural Science Foundation of China 21805272the National Natural Science Foundation of China 31801477

Figures(7)

Cosmetic-grade sodium polyaspartate was synthesized through the polycondensation of L-aspartic acid. The effects of polymerization temperature, time and catalyst amount on the polymerization were systematically investigated to obtain the optimal polymerization conditions. The structure and molecular weight of sodium polyaspartate were characterized by nuclear magnetic resonance spectroscopy (NMR) and gel permeation chromatography (GPC). The properties of acid and alkali resistance, temperature resistance and compatibility were also evaluated. The resultant sodium polyaspartate has light color (white), low odor, few impurities and high quality, exhibits excellent acid, alkali, temperature resistance and compatibility, reaches the standard as a moisturizing additive.
- L-aspartic acid,
- sodium polyaspartate,
- condensation polymerization
1. [1]
  TAO Youhua. A New Method for Amino Acid Polymerization Based on Ring-Opening Polymerization of Lactam[J]. Acta Polym Sin, 2016,9(9):1151-2259.
2. [2]
  Tao Y H, Chen X Y, Jia F. New Chemosynthetic Route to Linear ε-Poly-lysine[J]. Chem Sci, 2015,7(6):6385-6391.
3. [3]
  Chen J L, Li M S, He W J. Facile Organocatalyzed Synthesis of Poly(ε-lysine) under Mild Conditions[J]. Macromolecules, 2017,11(50):9128-9134.
4. [4]
  WANG Jiaming. Production, Application and Development Prospect of Polyaspartic Acid[J]. Chem Ind, 2009,27(12):39-43. doi: 10.3969/j.issn.1673-9647.2009.12.008
5. [5]
  Maninder K, Zhang H J, Martin L. Conjugates of Magnetic Nanoparticle-actinide Specific Chelatofor Radioactive Waste Separation[J]. Environ Sci Technol, 2013,47(6):1142-1159.
6. [6]
  Kharecha P A, Hansen J E. Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power[J]. Environ Sci Technol, 2013,47(15):4889-4895.
7. [7]
  He C J, Tian Z P, Zhang B R. Inhibition Effect of Environment-friendly Inhibitors on the Corrosion of Carbon Steel in Recirculating Cooling Water[J]. Ind Eng Chem Res, 2015,54(21):1971-1981.
8. [8]
  Comotti I M, Trueba M, Trasatti S P. The Pit Transition Potential in the Repassivation of Aluminium Alloys[J]. Surf Interface Anal, 2013,45(21):1575-1583.
9. [9]
  Arutunow A, Darowicki K, Tobiszewski M T. Electrical Mapping of Aisi-304 Stainless Steel Subjected to Intergranular Corrosion Performed by Means of AFM-LIS in the Contact Mode[J]. Corros Sci, 2013,71(6):37-44.
10. [10]
  Ma X. The Inhibition Effect of Polyaspartic Acid and Its Mixed Inhibitor on Mildsteel Corrosion in Seawater Wet/Dry Cyclic Conditions[J]. Int J Electrochem Sci, 2016,10(2/4):3024-3038.
11. [11]
  Malcolm A. Effect of Various Cations on the Formation of Calciumcarbonate and Barium Sulfate Scale with and Without Scale Inhibitors[J]. Int J Electrochem Sci, 2011,50(36):5852-5861.
12. [12]
  Hanson A D, Gregory J F. Folate Biosynthesis, Turnover and Transport in Plants[J]. Annu Rev Plant Biol, 2010,62(24):105-125.
13. [13]
  Choudhury M R, Hsieh M K. Development of an Instantaneous Corrosion Rate Monitoring System for Metal and Metal Alloys in Recirculating Cooling Systems[J]. Ind Eng Chem Res, 2012,51(2):4230-4236.
14. [14]
  Xu Y, Zhang B, Zhao L L. Synthesis of Polyaspartic Acid/5-Aminoorotic Acid Graft Copolymer and Evaluation of Its Scale Inhibition and Corrosion Inhibition Performance[J]. Desalination, 2013,311(6):156-161.
15. [15]
  DONG Ping, LI Xiaolin, QI Panlun. Progress in the Synthesis and Application of Polyaspartic Acid[J]. China Pet Chem Ind, 2007,12(4):92-95.
16. [16]
  Vegotsky A, Harada K, Fox S W. The Characterization of Polyaspartic Acid and Some Related Compounds 1, 2[J]. J Am Chem Soc, 1958,80(13):3361-3366. doi: 10.1021/ja01546a042
17. [17]
  CAO Hui, SHANG Fei, TAN Tianwei. Synthesis of Polyaspartic Acid from Maleic Anhydride as Raw Material and Determination of Its Scale Inhibition Performance[J]. J Beijing Univ Chem Technol(Nat Sci Ed), 2004,31(6):9-12. doi: 10.3969/j.issn.1671-4628.2004.06.003
18. [18]
  Jacquet B, Papantoniou C, Land G. Polyaspartic Acid Derivatives, Their Preparation and Their Use in Cosmetic Composition: US, US4363797A[P]. 1982-12-14.
19. [19]
  Zuang V, Rona C, Distante F. The Use of a Capacitance Device to Evaluate the Hydration of Human Skin[J]. J Appl Cosmetol, 1997,9(15):95-102.
20. [20]
  LIU Haiyan, LV Aimin, LIU Shuping. Production Technology and Research Development of Polyaspartic Acid[J]. Hebei Chem Ind, 2006,29(1):39-40.
21. [21]
  Tomida M, Nakato T. Convenient Synthesis of High Molecular Weight Poly(succinimide) by Acid-catalyzed Polycondensation of L-Aspartic Acid[J]. Polymer, 2010,38(18):4733-4736.
22. [22]
  Tomida M, Nakato T, Kuramochi M. Novel Method of Synthesizing Poly(succinimide) and Its Copolymeric Derivative by Acid-catalyzed Polycondensation of L-Aspartic Acid[J]. Polymer, 2011,37(19):4435-4437.
23. [23]
  Koskan L P. Polyaspartic Acid as Calcium Sulfate and a Barium Sulfate Inbibitor[P]. US5116513.1992.
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Cosmetic-Grade Sodium Polyaspartate

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com