Citation: GAO Siheng, YANG Yu, WU Jinling, QIN Lixia, KANG Shizhao, LI Xiangqing. Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite[J]. Chinese Journal of Applied Chemistry, ;2020, 37(8): 923-929. doi: 10.11944/j.issn.1000-0518.2020.08.200034 shu

Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite

School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: LI Xiangqing, E-mail:xqli@sit.edu.cn
Received Date: 4 February 2020
Revised Date: 23 March 2020
Accepted Date: 26 April 2020

Fund Project: the National Natural Science Foudation of China(No. 21771125), and the Shanghai Science and Technology Commission Local Capacity Building Project (No.19090503700)the Shanghai Science and Technology Commission Local Capacity Building Project No.19090503700the National Natural Science Foudation of China No. 21771125

Figures(7)

Ultrafine silver powder has shown wide applications in the fields of communication, electronics and front electrode of solar cells. Its size distribution, dispersion and surface state have close relationship with its performance. In this paper, in order to obtain ultrafine silver composite with narrow size distribution, good dispersibility and high conductivity, graphene oxide (GO) was introduced in the later period of silver particles synthesized by liquid phase reduction. The structure and morphology of the composite silver powder were characterized by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. The results show that the ultrafine silver powders obtained by this method possess good dispersion and narrow size distribution. Furthermore, the interaction between GO and silver particles was explored by UV-visible spectroscopy. It is also found that by fixing the concentration of silver nitrate solution, and increasing the content of GO, the conductivity of silver powder first increases, and then decreases. When the mass percentage of GO is 2.5%, due to more effective contact among silver particles, its interfacial resistance is lower and photocurrent is higher. It will provide important data and valuable reference for the application of ultrafine silver.
- ultrafine silver powder,
- graphene oxide,
- preparation method,
- conductivity,
- interfacial resistance
1. [1]
  Irizarry R, Burwell L, Leon M S. Preparation and Formation Mechanism of Silver Particles with Spherical Open Structures[J]. J Chem Educ, 2011,50(13):8023-8033.
2. [2]
  Liu Z, Qi X L, Wang H. Synthesis and Characterization of Spherical and Mono-Disperse Micro-Silver Powder Used for Silicon Solar Cell Electronic Paste[J]. Mater Lett, 2012,23(2):250-255.
3. [3]
  Henrika G, Juha L, Saima A. Control of the Size of Silver Nanoparticles and Release of Silver in Heat Treated SiO₂-Ag Composite Powders[J]. Mater, 2018,11(1):80-91. doi: 10.3390/ma11010080
4. [4]
  TIAN Qinghua, DENG Duo, LI Yu. Preparation of Ultrafine Silver Powders with Controllable Size and Morphology[J]. Trans Nonferrous Met Soc China, 2018,28(3):524-533.
5. [5]
  YAO Suwei, CAO Yan, ZHANG Weiguo. Preparation of Silver Nanoparticles with Different Morphology and Their Formation Mechanism by Photoreduction[J]. Chinese J Appl Chem, 2006,23(4):438-440. doi: 10.3969/j.issn.1000-0518.2006.04.022
6. [6]
  Kowalski K, Jurczyk M U, Wirstlein P K. Properties of Ultrafine-Grained Mg-Based composites Modified by Addition of Silver and Hydroxyapatite[J]. Mater Sci Technol, 2018,34:1096-1103. doi: 10.1080/02670836.2018.1424381
7. [7]
  Fu M, Li H Y, Wang Y. Study on the Synthesis and Performances of Ultrafine Silver Powder Used as Silicon Solar Cell Front Silver Contacts[J]. Mater Sci Forum, 2016,52:378-384.
8. [8]
  Meng S Y, Wu H B, Wu S P. Preparation of Ultrafine Silver Powder and Its Electrical Properties[J]. Mater, 2004,23(7):35-37.
9. [9]
  WEI Lili, XU Shengming, XU Gang. Effect of Surfactant on Dispersion of Ultrafine Silver Powder[J]. Trans Nonferrous Met Soc China, 2009,19(3):595-600. doi: 10.3321/j.issn:1004-0609.2009.03.031
10. [10]
  Guo G, Gan W, Luo J. Preparation and Dispersive Mechanism of Highly Dispersive Ultrafine Silver Powder[J]. Appl Surf Sci, 2010,256(22):6683-6687. doi: 10.1016/j.apsusc.2010.04.070
11. [11]
  Motlak M, Barakat N A M, Akhtar M S. Influence of GO Incorporation in TiO₂ Nanofibers on the Electrode Efficiency in Dye-Sensitized Solar Cells[J]. Ceram Int, 2015,41(1):1205-1212. doi: 10.1016/j.ceramint.2014.09.049
12. [12]
  MENG Xianwen, SONG Xiao, LIU Suqin. Preparation of Ag₃VO₄/GO Composite and Its Visible Light Catalytic Performance[J]. Chinese J Appl Chem, 2016,33(12):1441-1447. doi: 10.11944/j.issn.1000-0518.2016.12.160088
13. [13]
  LAN Feng, MA Shenghua, WANG Hui. Applications of Graphene in Solar Cells[J]. Knowl Mod Phys, 2018,1(4):6-9.
14. [14]
  WANG Lihui,SHI Haixin,YIN Yanzhen. Ag-Doped Graphene-Coated Solar Cell Front Electrode Silver Paste and Preparation Method:CN,201711206932[P]. 2018-04-20(in Chinese).
15. [15]
  Bakhshizadeh N, Sivoththaman S. Graphene-Decorated Nanocomposites for Printable Electrodes in Thin Wafer Devices[J]. Electron Mater, 2017,46(12):6922-6929. doi: 10.1007/s11664-017-5734-z
16. [16]
  Ge R Y, Wang X Y, Zhang C. The Influence of Combination Mode on the Structure and Properties of Porphyrin-Graphene Oxide Composites[J]. Colloids Surf A, 2015,483:45-52. doi: 10.1016/j.colsurfa.2015.05.056
17. [17]
  Li G, Feng W, Zhang X. Facile Preparation of Nanoporous Ag Decorated with CeO₂ Nanoparticles for Surface-Enhanced Raman Scattering[J]. J Mater Res, 2019,34(12):1-11.
18. [18]
  Xia X H, Zeng J, Li Q G. Silver Nanocrystals with Concave Surfaces and Their Optical and Surface-Enhanced Raman Scattering Properties[J]. Angew Chem, 2011,123(52):12750-12754. doi: 10.1002/ange.201105200
19. [19]
  Jiang J, Zhu L, Zou J. Micro/nano-Structured Graphitic Carbon Nitride-Ag Nanoparticle Hybrids as Surface-Enhanced Raman Scattering Substrates with Much Improved Long-Term Stability[J]. Carbon, 2015,87:193-205. doi: 10.1016/j.carbon.2015.02.025
20. [20]
  Chao Y X, Yang H W, Li Y X. Rapid Synthesis of Irregular Sub-Micron Flaky Silver with High Flake-Particle Ratio:Application to Silver Paste[J]. Chem Phys Lett, 2018,708:183-187. doi: 10.1016/j.cplett.2018.08.021
21. [21]
  Florent P, Clement A R, Miriam C. Plasmonic Nanocomposites Based on Silver Nanocube-Polymer Blends Displaying Nearly Perfect Absorption in the UV Region[J]. Langmuir, 2019,35(6):2179-2187. doi: 10.1021/acs.langmuir.8b03003
22. [22]
  Novoselov K S, Geim A K, Morozov S V. Electric Field Effect in Atomically Thin Carbon Films[J]. Science, 2004,306(5696):666-669. doi: 10.1126/science.1102896
23. [23]
  Cittadini M, Bersani M, Perrozzi F. Graphene Oxide Coupled with Gold Nanoparticles for Localized Surface Plasmon Resonance Based Gas Sensor[J]. Carbon, 2014,69:452-459. doi: 10.1016/j.carbon.2013.12.048
24. [24]
  Ma Y F, Yang L L, Yang Y. Multifunctional Ag-Decorated g-C₃N₄ Nanosheets as Recyclable SERS Substrates for CV and RhB Detection[J]. RSC Adv, 2018,8(39):22095-22102. doi: 10.1039/C8RA02657B
25. [25]
  Akbari E, Akbari I, Ebrahimi M R. sp²/sp³ Bonding Ratio Dependence of the Band-Gap in Graphene Oxide[J]. Eur Phys J B, 2019,92(4):22095-22102.
26. [26]
  Romano V, Torrisi L, Cutroneo M. Raman Investigation of Laser-Induced Structural Defects of Graphite Oxide Films[J]. EPJ Web Confer, 2018,167:1-4.
27. [27]
  Zhuang B, Li X Q, Ge R Y. Assembly and Electron Transfer Mechanisms on Visible Light Responsive 5,10,15,20-Meso-Tetra(4-Carboxyphenyl) Porphyrin/Cuprous Oxide Composite for Photocatalytic Hydrogen Production[J]. Appl Catal A, 2017,533:81-89. doi: 10.1016/j.apcata.2017.01.008
28. [28]
  Tu W, Lei J, Wang P. Photoelectrochemistry of Free-Base-Porphyrin-Functionalized Zinc Oxide Nanoparticles and Their Applications in Biosensing[J]. Chemistry, 2011,17(34):9440-9447. doi: 10.1002/chem.201100577
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
5. [5]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
6. [6]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
9. [9]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
10. [10]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
11. [11]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
12. [12]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
13. [13]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
14. [14]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
15. [15]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
16. [16]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
17. [17]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
18. [18]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
19. [19]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
20. [20]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1094)
HTML views(297)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142