Citation: LIN Yongcen, DONG Xue, MA Yuqin, ZHAO Lang. Designed Formation of NiCo-Layered Double Hydroxide Derived from Zeolitic Imidazolate Framework-67 with Selective Dye Adsorption Property[J]. Chinese Journal of Applied Chemistry, ;2020, 37(6): 683-694. doi: 10.11944/j.issn.1000-0518.2020.06.190330 shu

Designed Formation of NiCo-Layered Double Hydroxide Derived from Zeolitic Imidazolate Framework-67 with Selective Dye Adsorption Property

LIN Yongcen ^1,2 ,
DONG Xue ^1,2 ,
MA Yuqin ^1,, ,
ZHAO Lang ^2,,

a.
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130012, China
b.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: MA Yuqin, myq3939@163.com ZHAO Lang, zhaolang@ciac.ac.cn
Received Date: 11 December 2019
Revised Date: 9 February 2020
Accepted Date: 12 March 2020

Fund Project: Supported by the National Natural Science Foundation of China(No.21201160), and the Jilin Province Science and Technology Development Program(No.20170204038GX, No.20170101180JC)the Jilin Province Science and Technology Development Program 20170204038GXthe Jilin Province Science and Technology Development Program 20170101180JCthe National Natural Science Foundation of China 21201160

Figures(7)

A novel hollow composite of NiCo-layered double hydroxide and zeolitic imidazolate framework-67 (NiCo-LDH@ZIF-67) adsorbent with high adsorption capacity for pollutants, high adsorption selectivity of methyl orange (MO) and great regenerability was synthesized using ZIF-67 as a template. The sample was characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrometer (FT-IR), N₂ adsorption desorption and X-ray photoelectron spectroscopy (XPS). The effect of solution pH, the initial MO concentration and the contact time with the mixture solution on the adsorption property of NiCo-LDH@ZIF-67 was studied. The results indicate that its adsorption kinetics for MO can be well simulated by a pseudo-second-order model and its adsorption isotherm for MO follows the Langmuir equation. The optimized adsorption condition is pH=4, contact time of 15 minutes, and adsorbent dosage of 2400 mg/L. Its maximum adsorption capacity for MO can reach as high as 1766 mg/g and is higher than those reported for all similar adsorbents in the literature. In addition, NiCo-LDH@ZIF-67 can selectively adsorb MO from a mixed solution of MO and methylene blue (MB).
- layered double hydroxide,
- adsorption,
- dye,
- metal organic frameworks,
- zeolitic imidazolate framework-67
1. [1]
  Akbarnejad S, Amooey A A, Ghasemi S. High Effective Adsorption of Acid Fuchsin Dye Using Magnetic Biodegradable Polymer-Based Nanocomposite from Aqueous Solutions[J]. Microchem J, 2019,149103966. doi: 10.1016/j.microc.2019.103966
2. [2]
  Sabarinathan C, Karuppasamy P, Vijayakumar C T. Development of Methylene Blue Removal Methodology by Adsorption Using Molecular Polyoxometalate:Kinetics, Thermodynamics and Mechanistic Study[J]. Microchem J, 2019,146:315-326. doi: 10.1016/j.microc.2019.01.015
3. [3]
  Miandad R, Kumar R, Barakat M A. Untapped Conversion of Plastic Waste Char into Carbon-Metal LDOs for the Adsorption of Congo Red[J]. J Colloid Interface Sci, 2018,511:402-410. doi: 10.1016/j.jcis.2017.10.029
4. [4]
  Wang L, Wang A. Adsorption Properties of Congo Red from Aqueous Solution onto Surfactant-Modified Montmorillonite[J]. J Hazard Mater, 2008,160(1):173-180. doi: 10.1016/j.jhazmat.2008.02.104
5. [5]
  Lin H Y, Zhao J, Song G. High Quality and High Performance Adsorption of Congo Red Using As-Grown MWCNTs Synthesized over a Co-MOF as a Catalyst Precursor via the CVD Method[J]. Dalton Trans, 2017,46(48):17067-17073. doi: 10.1039/C7DT03627B
6. [6]
  Wang J H, Zhang Y, An L C. Sulfonated Hollow Covalent Organic Polymer:Highly-Selective Adsorption Toward Cationic Organic Dyes over Anionic Ones in Aqueous Solution[J]. Chinese J Chem, 2018,36(9):826-830. doi: 10.1002/cjoc.201800142
7. [7]
  Zhao S, Chen D, Wei F. Removal of Congo Red Dye from Aqueous Solution with Nickel-Based Metal-Organic Framework/Graphene Oxide Composites Prepared by Ultrasonic Wave-Assisted Ball Milling[J]. Ultrason Sonochem, 2017,39:845-852. doi: 10.1016/j.ultsonch.2017.06.013
8. [8]
  Yang Q, Wang Y, Wang J. High Effective Adsorption/Removal of Illegal Food Dyes from Contaminated Aqueous Solution by Zr-MOFs(UiO-67)[J]. Food Chem, 2018,254:241-248. doi: 10.1016/j.foodchem.2018.02.011
9. [9]
  Guan T, Fang L, Lu Y. A Facile Approach to Synthesize 3D Flower-Like Hierarchical NiCo Layered Double Hydroxide Microspheres and Their Enhanced Adsorption Capability[J]. Colloids Surf A, 2017,529:907-915. doi: 10.1016/j.colsurfa.2017.06.049
10. [10]
  Chakraborty A, Acharya H. Facile Synthesis of MgAl-Layered Double Hydroxide Supported Metal Organic Framework Nanocomposite for Adsorptive Removal of Methyl Orange Dye[J]. J Colloid Interface Sci, 2018,24:35-39. doi: 10.1016/j.colcom.2018.03.005
11. [11]
  Hu H, Guan B, Xia B. Designed Formation of Co₃O₄/NiCo₂O₄ Double-Shelled Nanocages with Enhanced Pseudocapacitive and Electrocatalytic Properties[J]. J Am Chem Soc, 2015,137(16):5590-5595. doi: 10.1021/jacs.5b02465
12. [12]
  Wang H, Fan G L, Zheng C. Facile Sodium Alginate Assisted Assembly of Ni-Al Layered Double Hydroxide Nanostructures[J]. Ind Eng Chem Res, 2010,49(6):2759-2767. doi: 10.1021/ie901519h
13. [13]
  Li C, Wei M, Evans D G. Layered Double Hydroxide-Based Nanomaterials as Highly Efficient Catalysts and Adsorbents[J]. Small, 2014,10(22):4469-4486. doi: 10.1002/smll.201401464
14. [14]
  Yang Y, Yan X, Hu X. In-situ Growth of ZIF-8 on Layered Double Hydroxide:Effect of Zn/Al Molar Ratios on Their Structural, Morphological and Adsorption Properties[J]. J Colloid Interface Sci, 2017,505:206-212. doi: 10.1016/j.jcis.2017.05.100
15. [15]
  Yao W, Yu S J, Wang J. Enhanced Removal of Methyl Orange on Calcined Glycerol-Modified Nanocrystallined Mg/Al Layered Double Hydroxides[J]. Chem Eng J, 2017,307:476-486. doi: 10.1016/j.cej.2016.08.117
16. [16]
  Tao X, Liu D, Cong W. Controllable Synthesis of Starch-Modified ZnMgAl-LDHs for Adsorption Property Improvement[J]. Appl Surf Sci, 2018,457:572-579. doi: 10.1016/j.apsusc.2018.06.264
17. [17]
  Robati D, Mirza B, Rajabi M. Removal of Hazardous Dyes-BR 12 and Methyl Orange Using Graphene Oxide as an Adsorbent from Aqueous Phase[J]. Chem Eng J, 2016,284:687-697. doi: 10.1016/j.cej.2015.08.131
18. [18]
  Habiba U, Siddique T A, Joo T C. Synthesis of Chitosan/Polyvinyl Alcohol/Zeolite Composite for Removal of Methyl Orange, Congo Red and Chromium(VI) by Flocculation/Adsorption[J]. Carbohydr Polym, 2017,157:1568-1576. doi: 10.1016/j.carbpol.2016.11.037
19. [19]
  Huang R H, Liu Q, Huo J. Adsorption of Methyl Orange onto Protonated Cross-Linked Chitosan[J]. Arab J Chem, 2017,10(1):24-32. doi: 10.1016/j.arabjc.2013.05.017
20. [20]
  Ni Z M, Xia S J, Wang L G. Treatment of Methyl Orange by Calcined Layered Double Hydroxides in Aqueous Solution:Adsorption Property and Kinetic Studies[J]. J Colloid Interface Sci, 2007,316(2):284-291. doi: 10.1016/j.jcis.2007.07.045
21. [21]
  Ling F L, Fang L, Lu Y. A novel CoFe Layered Double Hydroxides Adsorbent:High Adsorption Amount for Methyl Orange Dye and Fast Removal of Cr(VI)[J]. Micropor Mesopor Mater, 2016,234:230-238. doi: 10.1016/j.micromeso.2016.07.015
22. [22]
  Haque E, Lee J E, Jang I T. Adsorptive Removal of Methyl Orange from Aqueous Solution with Metal-Organic Frameworks, Porous Chromium-Benzenedicarboxylates[J]. J Hazard Mater, 2010,181:535-542. doi: 10.1016/j.jhazmat.2010.05.047
23. [23]
  Liu P F, Tao K, Li G C. In situ Growth of ZIF-8 Nanocrystals on Layered Double Hydroxide Nanosheets for Enhanced CO₂ Capture[J]. Dalton Trans, 2016,45(32):12632-12635. doi: 10.1039/C6DT02083F
24. [24]
  Hao L, Qiu Q, Li H. Directional Functionalization of MOF-74 Analogs via Ligand Pre-installation[J]. Chinese J Chem, 2016,34(2):220-224. doi: 10.1002/cjoc.201500597
25. [25]
  Thanh N T, Thien T V, Du P D. Adsorptive Removal of Congo Red from Aqueous Solution Using Zeolitic Imidazolate Framework-67[J]. J Environ Eng, 2018,6(2):2269-2280.
26. [26]
  Tian T, Wharmby M T, Parra J B. Role of Crystal Size on Swing-Effect and Adsorption Induced Structure Transition of ZIF-8[J]. Dalton Trans, 2016,45(16):6893-6900. doi: 10.1039/C6DT00565A
27. [27]
  Gao B, Zhou J, Wang H. Zeolitic Imidazolate Framework 8-Derived Au@ZnO for Efficient and Robust Photocatalytic Degradation of Tetracycline[J]. Chinese J Chem, 2019,37(2):148-154. doi: 10.1002/cjoc.201800440
28. [28]
  Zhang J J, Yan X L, Hu X Y. Direct Carbonization of Zn/Co Zeolitic Imidazolate Frameworks for Efficient Adsorption of Rhodamine B[J]. Chem Eng J, 2018,347:640-647. doi: 10.1016/j.cej.2018.04.132
29. [29]
  Yang Q X, Ren S S, Zhao Q Q. Selective Separation of Methyl Orange from Water Using Magnetic ZIF-67 Composites[J]. Chem Eng J, 2018,333:49-57. doi: 10.1016/j.cej.2017.09.099
30. [30]
  Yu D, Wu B, Ge L. Decorating Nanoporous ZIF-67-derived NiCo₂O₄ Shells on a Co₃O₄ Nanowire Array Core for Battery-Type Electrodes with Enhanced Energy Storage Performance[J]. J Mater Chem, 2016,4(28):10878-10884. doi: 10.1039/C6TA04286D
31. [31]
  Wang Q, Wang X F, Shi C L. LDH Nanoflower Lantern Derived from ZIF-67 and Its Application for Adsorptive Removal of Organics from Water[J]. Ind Eng Chem Res, 2018,57(37):12478-12484. doi: 10.1021/acs.iecr.8b01324
32. [32]
  Chen N N, Chen D, Wei F H. Effect of Structures on the Adsorption Performance of Cobalt Metal Organic Framework Obtained by Microwave-Assisted Ball Milling[J]. Chem Phys Lett, 2018,705:23-30. doi: 10.1016/j.cplett.2018.05.051
33. [33]
  Wang L, Wang A. Adsorption Characteristics of Congo Red onto the Chitosan/Montmorillonite Nanocomposite[J]. J Hazard Mater, 2007,147(3):979-985. doi: 10.1016/j.jhazmat.2007.01.145
34. [34]
  He P, Yu X Y, Lou X W. Carbon-Incorporated Nickel-Cobalt Mixed Metal Phosphide Nanoboxes with Enhanced Electrocatalytic Activity for Oxygen Evolution[J]. Angew Chem Int Ed Engl, 2017,56(14):3897-3900. doi: 10.1002/anie.201612635
35. [35]
  Zhang J, Hu H, Li Z. Double-Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High-Efficiency Polysulfide Mediator for Lithium-Sulfur Batteries[J]. Angew Chem Int Ed Engl, 2016,55(12):3982-3986. doi: 10.1002/anie.201511632
36. [36]
  Gao J, Lu Y, Fang L. Efficient Removal of Methyl Orange and Heavy Metal Ion from Aqueous Solution by NiFe-Cl-Layered Double Hydroxide[J]. Environ Eng Sci, 2018,35(4):373-381. doi: 10.1089/ees.2017.0023
37. [37]
  Li Z, Shao M, Zhou L. Directed Growth of Metal-Organic Frameworks and Their Derived Carbon-Based Network for Efficient Electrocatalytic Oxygen Reduction[J]. Adv Mater, 2016,28(12):2337-2344. doi: 10.1002/adma.201505086
38. [38]
  Yang Y, Yan X, Hu X. Development of Zeolitic Imidazolate Framework-67 Functionalized Co-Al LDH for CO₂ Adsorption[J]. Colloids Surf A, 2018,552:16-23. doi: 10.1016/j.colsurfa.2018.05.014
39. [39]
  Li J, Lu S, Huang H. ZIF-67 as Continuous Self-Sacrifice Template Derived NiCo₂O₄/Co, N-CNTs Nanocages as Efficient Bifunctional Electrocatalysts for Rechargeable Zn-Air Batteries[J]. ACS Sustain Chem Eng, 2018,6(8):10021-10029. doi: 10.1021/acssuschemeng.8b01332
40. [40]
  Chen Y, Jing C, Zhang X. Acid-Aalt Treated CoAl Layered Double Hydroxide Nanosheets with Enhanced Adsorption Capacity of Methyl Orange Dye[J]. J Colloid Interface Sci, 2019,548:100-109. doi: 10.1016/j.jcis.2019.03.107
41. [41]
  Du X D, Wang C C, Liu J G. Extensive and Selective Adsorption of ZIF-67 Towards Organic Dyes:Performance and Mechanism[J]. J Colloid Interface Sci, 2017,506:437-441. doi: 10.1016/j.jcis.2017.07.073
42. [42]
  Jiang D B, Yuan S, Cai X. Magnetic Nickel Chrysotile Nanotubes Tethered with pH-Sensitive Poly(Methacrylic Acid) Brushes for Cu(Ⅱ) Adsorption[J]. J Mol Liq, 2019,276:611-623. doi: 10.1016/j.molliq.2018.12.048
43. [43]
  Zhang Z, Zhang J, Liu J. Selective and Competitive Adsorption of Azo Dyes on the Metal-Organic Framework ZIF-67[J]. Water Air Soil Pollut, 2016,227(12)471. doi: 10.1007/s11270-016-3166-7
1. [1]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
2. [2]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
3. [3]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
4. [4]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
5. [5]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
6. [6]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
7. [7]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
8. [8]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
9. [9]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
10. [10]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
11. [11]
  Congyan Liu , Xueyao Zhou , Fei Ye , Bin Jiang , Bo Liu . Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity. Chinese Chemical Letters, 2025, 36(2): 109969-. doi: 10.1016/j.cclet.2024.109969
12. [12]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661
13. [13]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
14. [14]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
15. [15]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
16. [16]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
17. [17]
  Xinghong Cai , Qiang Yang , Yao Tong , Lanyin Liu , Wutang Zhang , Sam Zhang , Min Wang . AlO₂: A novel two-dimensional material with a high negative Poisson's ratio for the adsorption of volatile organic compounds. Chinese Chemical Letters, 2025, 36(2): 109586-. doi: 10.1016/j.cclet.2024.109586
18. [18]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
19. [19]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
20. [20]
  Manoj Kumar Sarangi , L․D Patel , Goutam Rath , Sitansu Sekhar Nanda , Dong Kee Yi . Metal organic framework modulated nanozymes tailored with their biomedical approaches. Chinese Chemical Letters, 2024, 35(11): 109381-. doi: 10.1016/j.cclet.2023.109381

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(256)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142