Citation: XU Xiaolong, WANG Suijun, JIN Yi, WANG Hao. Mesoporous Carbon Matrix Suppressing Dendritic Growth of Lithium Battery Anode[J]. Chinese Journal of Applied Chemistry, ;2020, 37(6): 703-708. doi: 10.11944/j.issn.1000-0518.2020.06.190285 shu

Mesoporous Carbon Matrix Suppressing Dendritic Growth of Lithium Battery Anode

XU Xiaolong ¹ ,
WANG Suijun ² ,
JIN Yi ² ,
WANG Hao ^1,,

a.
The College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
b.
State Key Laboratory of Operation and Control of Renewable Energy & Storage Systems, China Electric Power Research Institute, Beijing 100192, China

Corresponding author: WANG Hao, haowang@bjut.edu.cn
Received Date: 25 October 2019
Revised Date: 19 December 2019
Accepted Date: 8 February 2020

Fund Project: Supported by the State Grid Technology Project(No.DG71-17-010)the State Grid Technology Project DG71-17-010

Figures(5)

To avoid the performance fading and safety problem of lithium batteries caused by dendrite growth on the surface of lithium anode, the mesoporous carbon matrix (MCM) was prepared using the zeolitic imidazolate framework-8 (ZIF-8) as the template and precursor. X-ray powder diffraction (XRD) and Raman spectroscopy indicate that the MCM has a certain degree of graphitization, and the N₂ adsorption-desorption test (BET) proves that MCM has typical mesoporous characteristics. The XRD, Raman and BET test results suggest that the optimum annealing temperature is 900 ℃. The optimized MCM is used to study the surface modification of lithium anode. After the charge and discharge cycle test, the XRD and scanning electron microscopy (SEM) tests show that the orientation deposition of lithium metal is avoided and the growth of lithium dendrites is suppressed because MCM can balance the charge distribution on the lithium anode surface. This work reveals a facile but efficient synthesis approach of the surface modification agent to extend the cycle life and enhance the safety for high performance lithium batteries.
- lithium battery,
- lithium dendrite,
- surface modification agent,
- mesoporous carbon matrix,
- suppressing dendrite growth
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