Citation: LIU Xue, MA Hua, XU Heng, JI Haicong, WANG Dong. Lithium Storage Properties of Non-woven Fabric Based Polypyrrole Flexible Electrodes[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 555-561. doi: 10.11944/j.issn.1000-0518.2020.05.190304 shu

Lithium Storage Properties of Non-woven Fabric Based Polypyrrole Flexible Electrodes

LIU Xue ^a ,
MA Hua ^a ,
XU Heng ^a ,
JI Haicong ^a ,
WANG Dong ^a,b,,

a.
Hubei Key Laboratory of Advanced Textile Materials & Application, College of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, China
b.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China

Corresponding author: WANG Dong, wangdon08@126.com
Received Date: 14 November 2019
Revised Date: 3 January 2020
Accepted Date: 20 February 2020

Fund Project: the National Natural Science Foundation of China 51873166Supported by the National Natural Science Foundation of China(No.51873166)

Figures(6)

Flexible lithium-ion batteries with high-performance play a significant role in the development of wearable electronics. Pyrrole was polymerized in situ on polyethylene terephthalate (PET) non-woven fabric substrate through chemical oxidation method. By controlling the reaction conditions, PET-based polypyrrole(PPy) flexible electrode (PPy/PET) with different morphologies can be obtained. When the shearing force is low, the morphology of resulting PPy was nanowires (NW), vice versa, nanoparticles (NP). The mean diameter of PPy-NW is 460 nm. PET is covered with the interconnected PPy-NW, forming three-dimensional netlike conducting pathways. The as-prepared samples are directly used as binder-free flexible electrodes. The results of electrochemical tests demonstrate that PPy-NW/PET is favorable for enhancing lithium storage performance. It delivers an initial discharge and charge capacity of 124 and 98 mA·h/g with superior flexibility and stability. This paper offers a strategy for the fabrication of flexible and lightweight electrode materials and their application in energy storage.
- polypyrrole,
- non-woven fabric,
- flexibility,
- lithium ion battery
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