Citation: CUI Huamin, ZHANG Xueqian, HU Pandeng, YAN Bing, HUANG Weiwei, GUO Wenfeng. Calix[4]quinone/N-Doped Amorphous Carbon Nanofibers Composites for Lithium-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2020, 37(2): 198-204. doi: 10.11944/j.issn.1000-0518.2020.02.190236 shu

Calix[4]quinone/N-Doped Amorphous Carbon Nanofibers Composites for Lithium-Ion Batteries

CUI Huamin ^a,‡ ,
ZHANG Xueqian ^b,‡ ,
HU Pandeng ^a ,
YAN Bing ^a ,
HUANG Weiwei ^a,, ,
GUO Wenfeng ^a,,

a.
School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China
b.
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei 066004, China

Corresponding author: HUANG Weiwei, huangweiwei@ysu.edu.cn GUO Wenfeng, wfguo@ysu.edu.cn

^‡

Received Date: 5 September 2019
Revised Date: 21 October 2019
Accepted Date: 19 November 2019

Fund Project: the National Natural Science Foundation of China 21403187the National Natural Science Foundation of China 21875206Supported by the National Natural Science Foundation of China(No.21875206, No.21403187), and the Natural Science Foundation of Hebei Province(No.B2019203487)the Natural Science Foundation of Hebei Province B2019203487

Figures(5)

Although calix[4]quinone (C4Q) has a theoretical specific capacity up to 447 mA·h/g, its high solubility in liquid electrolytes and low conductivity make it impractical in lithium-ion batteries (LIBs). In order to solve these problems, N-doped amorphous carbon nanofibers (NACF) were obtained by high-temperature carbonization with chitin as raw material, and were used to adsorb C4Q to prepare C4Q/NACF (mass ratio is 1:1) composite material. The as-assembled LIBs delivered an initial discharge capacity of 426 mA·h/g, and maintained 213 mA·h/g after 100 cycles at 0.1 C. Even at a high rate of 1 C, the capacity could still reach 188 mA·h/g. These experimental results show that the performance of LIBs is effectively improved by using NACF biomass carbon to immobilize C4Q.
- chitin,
- N-doped amorphous carbon nanofibers,
- calix[4]quinone,
- immobilization,
- lithium-ion batteries
1. [1]
  Armand M, Tarascon J M. Building Better Batteries[J]. Nature, 2008,451(7179):652-657. doi: 10.1038/451652a
2. [2]
  Goodenough J B, Kim Y. Challenges for Rechargeable Li Batteries[J]. Chem Mater, 2010,22(3):587-603. doi: 10.1021/cm901452z
3. [3]
  Xin S, Guo Y G, Wan L J. Nanocarbon Networks for Advanced Rechargeable Lithium Batteries[J]. Acc Chem Res, 2012,45(10):1759-1769. doi: 10.1021/ar300094m
4. [4]
  CHEN Lihui, WU Qiuhan, PAN Pei. Spinel Lithium Manganese Oxide Octahedral Nanoparticles with Excellent Electrochemical Performance as Cathode Materials for Lithium-Ion Batteries[J]. Chinese J Appl Chem, 2018,35(11):1384-1390. doi: 10.11944/j.issn.1000-0518.2018.11.170407
5. [5]
  Zhou M, Qian J F, Ai X P. Redox-Active Fe(CN)₆^4--Doped Conducting Polymers with Greatly Enhanced Capacity as Cathode Materials for Li-Ion Batteries[J]. Adv Mater, 2011,23(42):4913-4917. doi: 10.1002/adma.201102867
6. [6]
  Han X Y, Chang C X, Yuan L J. Aromatic Carbonyl Derivative Polymers as High-Performance Li-Ion Storage Materials[J]. Adv Mater, 2007,19(12):1616-1621. doi: 10.1002/adma.200602584
7. [7]
  Song Z P, Zhou H S. Towards Sustainable and Versatile Energy Storage Devices:An Overview of Organic Electrode Materials[J]. Energy Environ Sci, 2013,6(8):2280-2301. doi: 10.1039/c3ee40709h
8. [8]
  Nokami T, Matsuo T, Inatomi Y. Polymer-Bound Pyrene-4, 5, 9, 10-Tetraone for Fast-Charge and -Discharge Lithium-Ion Batteries with High Capacity[J]. J Am Chem Soc, 2012,134(48):19694-19700. doi: 10.1021/ja306663g
9. [9]
  Song Z P, Qian Y M, Gordin M L. Polyanthraquinone as a Reliable Organic Electrode for Stable and Fast Lithium Storage[J]. Angew Chem Int Ed, 2015,54(47):13947-13951. doi: 10.1002/anie.201506673
10. [10]
  Xie J, Wang Z L, Gu P Y. A Novel Quinone-Based Polymer Electrode for High Performance Lithium-Ion Batteries[J]. Sci China Mater, 2016,59(1):6-11. doi: 10.1007/s40843-016-0112-3
11. [11]
  Larcher D, Tarascon J M. Towards Greener and More Sustainable Batteries for Electrical Energy Storage[J]. Nat Chem, 2014,7(1):19-29.
12. [12]
  Ma J, Zhou E, Fan C. Endowing CuTCNQ with a New Role:A High-Capacity Cathode for K-Ion Batteries[J]. Chem Commun, 2018,54(44):5578-5581. doi: 10.1039/C8CC00802G
13. [13]
  Wang L P, Zhang H Q, Mou C X. Dicarboxylate CaC₈H₄O₄ as a High-Performance Anode for Li-Ion Batteries[J]. Nano Res, 2015,8(2):523-532. doi: 10.1007/s12274-014-0666-x
14. [14]
  Zhang H Q, Deng Q J, Hou A J. Porous Li₂C₈H₄O₄ Coated with N-Doped Carbon by Using CVD as an Anode Material for Li-Ion Batteries[J]. J Mater Chem A, 2014,2(16):5696-5702. doi: 10.1039/C3TA14720G
15. [15]
  Yang A K, Wang X C, Lu Y. Core-Shell Structured 1, 4-Benzoquinone@TiO₂ Cathode for Lithium Batteries[J]. J Energy Chem, 2018,27(6):1644-1650. doi: 10.1016/j.jechem.2018.06.003
16. [16]
  Visco S J, DeJonghe L C. Ionic Conductivity of Organosulfur Melts for Advanced Storage Electrodes[J]. J Electrochem Soc, 1988,135(12):2905-2909. doi: 10.1149/1.2095460
17. [17]
  Liu K, Zheng J M, Zhong G M. Poly(2, 5-dihydroxy-1, 4-benzoquinonyl sulfide)(PDBS) as a Cathode Material for Lithium Ion Batteries[J]. J Mater Chem, 2011,21(12):4125-4131. doi: 10.1039/c0jm03127e
18. [18]
  Huang W W, Zhu Z Q, Wang L J. Quasi-Solid-State Rechargeable Lithium-Ion Batteries with a Calix[4] quinone Cathode and Gel Polymer Electrolyte[J]. Angew Chem Int Ed, 2013,52(35):9162-9166. doi: 10.1002/anie.201302586
19. [19]
  Zheng S B, Sun H M, Yan B. High-Capacity Organic Electrode Material Calix[4] quinone/CMK-3 Nanocomposite for Lithium Batteries[J]. Sci China Mater, 2018,61(10):1285-1290. doi: 10.1007/s40843-018-9259-4
20. [20]
  YAN Bing, XIONG Wenxu, ZHENG Shibing. Single-Walled Carbon Nanotubes Enhanced Electrochemical Performance of High-Capacity Organic Cathode Composites Calix[4] quinone/Mesporous Carbon CMK-3 for Li-Ion Batteries[J]. Chinese J Appl Chem, 2019,36(42):554-563.
21. [21]
  Ma Q L, Yu Y F, Sindoro M. Carbon-Based Functional Materials Derived from Waste for Water Remediation and Energy Storage[J]. Adv Mater, 2017,29(13)1605361. doi: 10.1002/adma.201605361
22. [22]
  Xu J T, Wang M, Wickramaratne N P. High-Performance Sodium Ion Batteries Based on a 3D Anode from Nitrogen-Doped Graphene Foams[J]. Adv Mater, 2015,27(12):2042-2048. doi: 10.1002/adma.201405370
23. [23]
  YU Junfeng, CHEN Peirong, YU Zhimin. Preparation and Characterization of Activated Carbon from Sawdust Bio-char by Chemical Activation with KOH[J]. Chinese J Appl Chem, 2013,30(9):1017-1022.
24. [24]
  Luo L B, Chen J J, Wang M Z. Near-infrared Light Photovoltaic Detector Based on GaAs Nanocone Array/Monolayer Graphene Schottky Junction[J]. Adv Funct Mater, 2014,24(19):2794-2800. doi: 10.1002/adfm.201303368
25. [25]
  Gaddam R R, Yang D F, Narayan R. Biomass Derived Carbon Nanoparticle as Anodes for High Performance Sodium and Lithium Ion Batteries[J]. Nano Energy, 2016,26:346-352. doi: 10.1016/j.nanoen.2016.05.047
26. [26]
  Cao Y L, Xiao L F, Sushko M L. Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications[J]. Nano Lett, 2012,12(7):3783-3787. doi: 10.1021/nl3016957
27. [27]
  Yang T Z, Qian T, Wang M F. A Sustainable Route from Biomass Byproduct Okara to High Content Nitrogen-Doped Carbon Sheets for Efficient Sodium Ion Batteries[J]. Adv Mater, 2015,28(3):539-545.
28. [28]
  LI Juntao, WU Jiaohong, ZHANG Tao. Preparation of Biochar from Different Biomasses and Their Application in the Li-S Battery[J]. Acta Phys-Chim Sin, 2017,33(5):968-975.
29. [29]
  Komaba S, Murata W, Ishikawa T. Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries[J]. Adv Funct Mater, 2011,21(20):3859-3867. doi: 10.1002/adfm.201100854
30. [30]
  Luo W, Schardt J, Bommier C. Carbon Nanofibers Derived from Cellulose Nanofibers as a Long-Life Anode Material for Rechargeable Sodium-Ion Batteries[J]. J Mater Chem A, 2013,1(36):10662-10666. doi: 10.1039/c3ta12389h
31. [31]
  Wang Y X, Chou S L, Liu H K. Reduced Graphene Oxide with Superior Cycling Stability and Rate Capability for Sodium Storage[J]. Carbon, 2013,57(1):202-208.
32. [32]
  Xiao L F, Cao Y L, Henderson W A. Hard Carbon Nanoparticles as High-Capacity, High-Stability Anodic Materials for Na-Ion Batteries[J]. Nano Energy, 2015,19:279-288.
33. [33]
  Yan N, Chen X. Sustainability:Don't Waste Seafood Waste[J]. Nature, 2015,524(7564):155-157. doi: 10.1038/524155a
34. [34]
  Ifuku S, Saimoto H. Chitin Nanofibers:Preparations, Modifications, and Applications[J]. Nanoscale, 2012,4(11):3308-3318. doi: 10.1039/C2NR30383C
35. [35]
  Duan B, Zheng X, Xia Z X. Highly Biocompatible Nanofibrous Microspheres Self-assembled from Chitin in NaOH/Urea Aqueous Solution as Cell Carriers[J]. Angew Chem Int Ed, 2015,54(17):5152-5156. doi: 10.1002/anie.201412129
36. [36]
  Hao R, Yang Y, Wang H. Direct Chitin Conversion to N-Doped Amorphous Carbon Nanofibers for High-Performing Full Sodium-Ion Batteries[J]. Nano Energy, 2017,45:220-228.
37. [37]
  Gutowska A, Li L Y, Shin Y. Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane[J]. Angew Chem Int Ed, 2005,44(23):3578-3582. doi: 10.1002/anie.200462602
38. [38]
  Xiong W X, Huang W W, Zhang M. Pillar[5] quinone-Carbon Nanocomposites as High-Capacity Cathodes for Sodium-Ion Batteries[J]. Chem Mater, 2019,31(19):8069-8075. doi: 10.1021/acs.chemmater.9b02601
39. [39]
  Huang W W, Zhang X Q, Zheng S B, et al. Calix[6]quinone as High-Performance Cathode for Lithium-Ion Battery[J]. Sci China Mater, 2019-09-11[2019-09-16]. http://engine.scichina.com/publisher/scp/journal/SCMs/doi/10.1007/s40843-019-1185-2?slug=abstract.[published online ahead of print].
40. [40]
  Morita Y, Agawa T, Nomura E. Syntheses and NMR Behavior of Calix[4] quinone and Calix[4] hydroquinone[J]. J Org Chem, 1992,57(13):3658-3662. doi: 10.1021/jo00039a027
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