Citation: DONG Zhiyun, ZHANG Xiaoyu, ZENG Zhengquan, XI Fugui. Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-[J]. Chinese Journal of Applied Chemistry, ;2020, 37(1): 80-87. doi: 10.11944/j.issn.1000-0518.2020.01.190165 shu

Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-

Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: XI Fugui, xifuguig@163.com; xifuguig@163.com
Received Date: 5 June 2019
Revised Date: 5 July 2019
Accepted Date: 5 September 2019

Fund Project: the Shanxi "1331 Project" Key Subjects Construction 2019Supported by the Shanxi "1331 Project" Key Subjects Construction(2019)

Figures(6)

Two novel anthracene-benzimidazolium based receptors 1 and 2 were synthesized. The anion (F^-, Cl^-, Br^-, I^-, AcO^-, HSO₄^-, H₂PO₄^-, ClO₄^-, NO₃^-) binding properties of receptors 1 and 2 were evaluated in acetonitrile by fluorescence spectroscopy. The receptors 1 and 2 display fluorescent quenching effect with H₂PO₄^-, the quench percentage for receptor 1 is 13%, and for receptor 2 is as much as 94%. The results indicate that receptor 2 is more closely matched to H₂PO₄^- in configuration, and receptor 2 can behave as a "turn-off" fluorescence sensor for H₂PO₄^-. Job-plot shows that receptor 2 and H₂PO₄^- form a 1:1 complex, the binding constant is (3.70±0.16)×10⁴ L/mol, and the detection limit is 3.77×10^-6 mol/L.
- anthracene,
- benzimidazolium,
- dihydrogen phosphate,
- fluorescent chemosensor
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沈阳化工大学材料科学与工程学院沈阳 110142

Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H2PO4-

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通讯作者: 陈斌, bchen63@163.com

Anthracene-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-