Citation: LI Jiaqi, FU Dayou, WANG Zhuqing, TAN Wenyuan, CHEN Yuqin, JI Gangyang. Online Ozone Detection Method Based on Gas-Liquid Phase Chemiluminescence Technology[J]. Chinese Journal of Applied Chemistry, ;2020, 37(1): 96-102. doi: 10.11944/j.issn.1000-0518.2020.01.190136 shu

Online Ozone Detection Method Based on Gas-Liquid Phase Chemiluminescence Technology

LI Jiaqi ^a ,
FU Dayou ^a,, ,
WANG Zhuqing ^a ,
TAN Wenyuan ^a ,
CHEN Yuqin ^a ,
JI Gangyang ^b

a.
Sichuan University of Science and Engineering, College of Chemical Engineering, Zigong, Sichuan 643000, China
b.
Beijing Kechuang Haiguang Instrument Co., Ltd., Beijing 100020, China

Corresponding author: FU Dayou, 425105638@qq.com
Received Date: 13 May 2019
Revised Date: 8 July 2019
Accepted Date: 19 August 2019

Fund Project: Supported by the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering(No.y2018057), the Sichuan Institute of Technology Talent Introduction Project(No.2016RCL17), the Sichuan Zigong City Science and Technology Bureau Project(No.2018YYJC12), the Fine Chemical Additives and Surfactants Sichuan Higher Education Funded by the Key Laboratory Project(No.2018JXY06), the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering(No.y2018058), and the Zigong City Science and Technology Bureau Project(No.2017xc20)the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering y2018058the Sichuan Zigong City Science and Technology Bureau Project 2018YYJC12the Zigong City Science and Technology Bureau Project 2017xc20the Fine Chemical Additives and Surfactants Sichuan Higher Education Funded by the Key Laboratory Project 2018JXY06the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering y2018057the Sichuan Institute of Technology Talent Introduction Project 2016RCL17

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Based on luminol chemiluminescence system, a self-developed online ozone concentration detector was used to establish a real-time online method for detecting ozone concentration for the determination of ozone gas at trace level. The effects of luminol, potassium hydroxide, alcohols and surfactants on the chemiluminescence intensity were investigated. The results showed that ethylene glycol (volume fraction 1.5%), methanol (volume fraction 1.5%), ethanol (volume fraction 1.0%), and glycerol (volume fraction 3.0%) were added to luminol (0.005 mol/L) and potassium hydroxide (0.05 mol/L) can significantly enhance the luminescence signal of O₃ in the luminol system, and formaldehyde (volume fraction 3.0%) can effectively inhibit the interference of NO₂ signal. At the same time, the detection limit of ozone was 1.26 μg/m³, the relative standard deviation was 0.32%, and the relative error was 0.75%. This ozone determination system has the advantages of stable signal, good precision, high accuracy and low detection limit. It is suitable for online continuous detection of trace O₃ in the atmosphere.
- luminol,
- gas-liquid phase,
- chemiluminescence,
- detection,
- ozone
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