Citation: LI Jiaqi, FU Dayou, WANG Zhuqing, TAN Wenyuan, CHEN Yuqin, JI Gangyang. Online Ozone Detection Method Based on Gas-Liquid Phase Chemiluminescence Technology[J]. Chinese Journal of Applied Chemistry, ;2020, 37(1): 96-102. doi: 10.11944/j.issn.1000-0518.2020.01.190136 shu

Online Ozone Detection Method Based on Gas-Liquid Phase Chemiluminescence Technology

LI Jiaqi ^a ,
FU Dayou ^a,, ,
WANG Zhuqing ^a ,
TAN Wenyuan ^a ,
CHEN Yuqin ^a ,
JI Gangyang ^b

a.
Sichuan University of Science and Engineering, College of Chemical Engineering, Zigong, Sichuan 643000, China
b.
Beijing Kechuang Haiguang Instrument Co., Ltd., Beijing 100020, China

Corresponding author: FU Dayou, 425105638@qq.com
Received Date: 13 May 2019
Revised Date: 8 July 2019
Accepted Date: 19 August 2019

Fund Project: Supported by the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering(No.y2018057), the Sichuan Institute of Technology Talent Introduction Project(No.2016RCL17), the Sichuan Zigong City Science and Technology Bureau Project(No.2018YYJC12), the Fine Chemical Additives and Surfactants Sichuan Higher Education Funded by the Key Laboratory Project(No.2018JXY06), the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering(No.y2018058), and the Zigong City Science and Technology Bureau Project(No.2017xc20)the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering y2018058the Sichuan Zigong City Science and Technology Bureau Project 2018YYJC12the Zigong City Science and Technology Bureau Project 2017xc20the Fine Chemical Additives and Surfactants Sichuan Higher Education Funded by the Key Laboratory Project 2018JXY06the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering y2018057the Sichuan Institute of Technology Talent Introduction Project 2016RCL17

Figures(7)

Based on luminol chemiluminescence system, a self-developed online ozone concentration detector was used to establish a real-time online method for detecting ozone concentration for the determination of ozone gas at trace level. The effects of luminol, potassium hydroxide, alcohols and surfactants on the chemiluminescence intensity were investigated. The results showed that ethylene glycol (volume fraction 1.5%), methanol (volume fraction 1.5%), ethanol (volume fraction 1.0%), and glycerol (volume fraction 3.0%) were added to luminol (0.005 mol/L) and potassium hydroxide (0.05 mol/L) can significantly enhance the luminescence signal of O₃ in the luminol system, and formaldehyde (volume fraction 3.0%) can effectively inhibit the interference of NO₂ signal. At the same time, the detection limit of ozone was 1.26 μg/m³, the relative standard deviation was 0.32%, and the relative error was 0.75%. This ozone determination system has the advantages of stable signal, good precision, high accuracy and low detection limit. It is suitable for online continuous detection of trace O₃ in the atmosphere.
- luminol,
- gas-liquid phase,
- chemiluminescence,
- detection,
- ozone
1. [1]
  Jia L, Ge M F, Xu Y F. Advances in Atmospheric Ozone Chemistry[J]. Prog Chem, 2006,18(11):1565-1574.
2. [2]
  Brune W H, Baier B C, Thomas J. Ozone Production Chemistry in the Presence of Urban Plumes[J]. Faraday Discuss, 2016,189:169-189.
3. [3]
  Finlayson-Pitts B J, PittsJr J N. Atmospheric Chemistry of Tropospheric Ozone Formation:Scientific and Regulatory Implications[J]. Air Repair, 1993,43(8):1091-1100.
4. [4]
  WANG Dan. Discussion on Standardization Measures for Prevention and Control of Atmospheric Ozone Pollution[J]. China Standard, 2017(6):247-248.
5. [5]
  LI Wangxia. Exploration on Monitoring and Prevention of Ozone in Ambient Air Pollutants[J]. Resour Econom Environ Prot, 2018(8):38-38.
6. [6]
  Birdsall C M, Jenkins A C, Spadinger E. Iodometric Determination of Ozone[J]. Anal Chem, 1952,24(4):662-664.
7. [7]
  Qi W J, Wu D, Zhao J M. Fluorescent Silica Nanoparticle-Based Probe for the Detection of Ozone via Fluorescence Resonance Energy Transfer[J]. Analyst, 2013,138(21):6305-6308.
8. [8]
  Qi W J, Liu Z Y, Lai J P. Detection of Ozone Based on Its Striking Inhibition of Tris(1, 10-phenanthroline)ruthenium(ii)/Glyoxal Electrochemiluminescence[J]. Chem Commun, 2014,50(60):8164-8166.
9. [9]
  Qin S H, Cheng L, Selorm A L. An Overview of Ozone Research[J]. J Avd Oxid Technol, 2018,21(1):297-302.
10. [10]
  XIE Jianrong. Summary of Eommon Methods for the Determination of Ozone[J]. Fujian Anal Test, 1999(2):1045-1053.
11. [11]
  QI Bin, WANG Zhuqing, YANG Hongyan. On-line Chemiluminescence Instrument for Measurement of Nitrogen Dioxide[J]. Chinese J Anal Chem, 2010,38(4):607-610.
12. [12]
  Regener V H. Measurement of Atmospheric Ozone with the Chemiluminescent Method[J]. J Geophys Res, 1964,69(18):3795-3800.
13. [13]
  WANG Zhuqing, ZHENG Yi, YANG Bing. A Real-Time Online Ozone Analyzer Based on the Gas-Liquid Surface Chemiluminescence[J]. Anal Instrum, 2016(3):6-10.
14. [14]
  Finlayson B J, Pitts J N, Atkinson Jr R. Low-Pressure Gas-Phase Ozone-Olefin Reactions. Chemiluminescence, Kinetics, and Mechanisms[J]. J Am Chem Soc, 1974,96(17):5356-5367.
15. [15]
  Saqib M, Qi L, Hui P. Development of Luminol-N-hydroxyphthalimide Chemiluminescence System for Highly Selective and Sensitive Detection of Superoxide Dismutase, Uric Acid And Co²⁺[J]. Biosens Bioelectron, 2017,99:519-524.
16. [16]
  Fontijn A, Sabadell A J, Ronco R J. Homogeneous Chemiluminescent Measurement of Nitric Oxide with Ozone. Implications for Continuous Selective Monitoring of Gaseous Air Pollutants[J]. Anal Chem, 1970,42(6):575-579.
17. [17]
  Mikuška P, Večeřa Z. Application of Gallic Acid and Xanthene Dyes for Determination of Ozone in Air with a Chemiluminescence Aerosol Detector[J]. Anal Chim Acta, 1998,374(2/3):297-302.
18. [18]
  Lu G, Oda T, Araki H. Transformation of Stored Energy into Light in the Chemiluminescence of 1, 2-Dioxetanes[J]. Chemphotochem, 2018,2(5):421-424.
19. [19]
  XUE Xiuyuan, CUI Haisheng. The Application of Chemiluminescence Analysis in Environmental Monitoring[J]. J Baoji Coll Arts Sci(Nat Sci), 2018,38(3):35-43.
20. [20]
  Mikuska P, Vecera Z. Effect of Complexones and Tensides on Selectivity of Nitrogen Dioxide Determination in Air with a Chemiluminescence Aerosol Detector[J]. Anal Chim Acta, 2000,410(1/2):159-165.
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