Citation: ZHOU Fengzhen, LI Wenqiu, WANG Wenjing, GUO Huiling. Influencing Factors of Lanthanum Adsorption by Ca-Montmorillonite and Its Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(12): 1413-1421. doi: 10.11944/j.issn.1000-0518.2019.12.190077 shu

Influencing Factors of Lanthanum Adsorption by Ca-Montmorillonite and Its Application

Hubei University of Technology, School of Bioengineering and Food, Wuhan 430068, China

Corresponding author: GUO Huiling, 405530371@qq.com
Received Date: 22 March 2019
Revised Date: 3 June 2019
Accepted Date: 3 July 2019

Fund Project: the National Natural Science Foundation of China 21401051Supported by the National Natural Science Foundation of China (No. 21401051) and the Natural Science Foundation of Hubei Province (No. 2014CFB595)the Natural Science Foundation of Hubei Province 2014CFB595

Figures(6)

The adsorption of lanthanum on Ca-montmorillonite was studied. The crystal structure, surface morphology, specific surface area and chemical structure of Ca-montmorillonite were characterized by XRD, SEM, BET, Fourier transform infrared spectrum (FT-IR) and X-Ray fluorescence (XRF). The effects of initial lanthanum concentration, pH and adsorption temperature on the adsorption of La onto Ca-montmorillonite were examined when the mass concentration of Ca-montmorillonite was 10 g/L. The phosphorus removal effect of Ca-MMT@La was studied. The results showed that the adsorption of La onto Ca-montmorillonite increases with initial lanthanum concentration increasing, and the maximum adsorption capacity is 49.62 mg/g. With the increase of the pH of lanthanum-containing solution, the adsorption capacity increases and the optimum adsorption is obtained at initial pH 6 with the adsorption capacity of 38.36 mg/g. With the increase of temperature, the adsorption capacity increases firstly and then decreases. The maximum adsorption capacity of lanthanum is 41.23 mg/g at 20℃. The adsorption equilibrium was best described by the Langmuir isotherm model. The result indicated that La is adsorbed onto Ca-montmorillonite through the monolayer adsorption. Ca-montmorillonite can not adsorb phosphorus. However, Ca-MMT@La has a strong adsorption capacity for phosphate with the adsorption capacity of 7.24 mg/g and the phosphorus removal rate of 72.41%. The adsorption of phosphorus onto Ca-MMT@La increases with the increase of loaded lanthanum content.
- Ca-montmorillonite,
- adsorbent,
- lanthanum,
- wastewater treatment,
- adsorption effect
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