Citation: LIU Ning, LIU Shuilin, WU Suyun, TANG Xinde, WU Zhi, LI Aiyang. CTAB-P123-Assisted Synthesis of Orderly Mesoporous KF/Al-Ce-SBA-15 Solid Base and Its Catalytic Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1294-1300. doi: 10.11944/j.issn.1000-0518.2019.11.190081 shu

CTAB-P123-Assisted Synthesis of Orderly Mesoporous KF/Al-Ce-SBA-15 Solid Base and Its Catalytic Application

Department of Materials and Chemical Engineering, New Building Materials Academy, Hunan Institute of Technology, Hengyang, Hunan 421002, China

Corresponding author: LIU Ning, liuning0731@163.com LI Aiyang, 229469276@qq.com
Received Date: 1 April 2019
Revised Date: 10 June 2019
Accepted Date: 9 July 2019

Fund Project: Supported by the National Natural Science Foundation of China(No. 51802093), the Hunan Provincial Natural Science Foundation of China(No.2019JJ60026, No.2019JJ50107), the Foundation of Hunan Educational Committee(No.18B465), the Key Laboratory of Functional Organometallic Materials of Hengyang Normal University(No.GN18K01), and the Characteristic Application Discipline of Material Science and Engineering in Hunan(No.Xiang-Jiao-Tong[2018]369)the Characteristic Application Discipline of Material Science and Engineering in Hunan Xiang-Jiao-Tong[2018]369the Hunan Provincial Natural Science Foundation of China 2019JJ50107the Foundation of Hunan Educational Committee 18B465the National Natural Science Foundation of China 51802093the Key Laboratory of Functional Organometallic Materials of Hengyang Normal University GN18K01the Hunan Provincial Natural Science Foundation of China 2019JJ60026

Figures(5)

The orderly mesoporous KF/Al-Ce-SBA-15(KF/ACS) solid bases were successfully prepared with cetyltrimethylammonium bromide(CATB)-poly(ethylene oxide)/poly(propylene oxide)/poly(ethylene oxide) triblock copolymer (P123) as the dual-template and KF as the modifier in two steps. The structure and property of the obtained catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and CO₂-temperature programmed desorption (TPD). The results illustrated that the KF/ACS catalysts possess both an ordered mesostructure and superbasicity when the introduced Al/Ce atomic ratio is 0.12 and the loading amounts(mass fraction) of KF is 10%. The catalytic activity of the prepared materials was evaluated in the ring-opening reaction of propylene oxide (PO) with methanol. It shows excellent catalytic performance exhibiting 92.0% yield of propylene glycol monomethyl ether (PM) and 96.1% selectivity to 1-methoxy-2-propanol (PPM) and the by-products of dipropylene glycol methyl ether was effectively inhibited.
- cetyltrimethylammonium bromide,
- triblock copolymer P123,
- mesoporous solid bases,
- SBA-15,
- Al-Ce mixed oxides
1. [1]
  CHEN Zhengli, HAN Na, SU Wei. Preparation of Fe-Co-β-SBA-15 and Its Catalytic Performance[J]. Mod Chem Ind, 2019,39(01):171-175.
2. [2]
  Sun L B, Liu X Q, Zhou H C. Design and Fabrication of Mesoporous Heterogeneous Basic Catalysts[J]. Chem Soc Rev, 2015,44(15):5092-5147. doi: 10.1039/C5CS00090D
3. [3]
  Liu X Y, Sun L B, Lu F. Constructing Mesoporous Solid Superbases by a Dualcoating Strategy[J]. J Mater Chem A, 2013,1(5):1623-1631. doi: 10.1039/C2TA00690A
4. [4]
  Sun L B, Sun Y H, Liu X D. Preparation of Mesoporous Solid Superbases by Using Metal Oxide Interlayers[J]. Curr Org Chem, 2014,18(10):1296-1304. doi: 10.2174/1385272819666140424204512
5. [5]
  Malhotra R, Ali A. Lithium-Doped Ceria Supported SBA-15 as Mesoporous Solid Reusable and Heterogeneous Catalyst for Biodiesel Production via Simultaneous Esterification and Transesterification of Waste Cottonseed Oil[J]. Renew Energy, 2018,119:32-44. doi: 10.1016/j.renene.2017.12.001
6. [6]
  Wu Z Y, Jiang Q, Wang Y M. Generating Superbasic Sites on Mesoporous Silica SBA-15[J]. Chem Mater, 2006,18(19):4600-4608. doi: 10.1021/cm0608138
7. [7]
  Yang L, Yang X, Tian E. Mechanistic Insights into the Production of Methyl Lactate by Catalytic Conversion of Carbohydrates on Mesoporous Zr-SBA-15[J]. J Catal, 2016,333:207-216. doi: 10.1016/j.jcat.2015.10.013
8. [8]
  Wei Y, Li Y, Tan Y. Short-Channeled Mesoporous Zr-Al-SBA-15 as a Highly Efficient Catalyst for Hydroxyalkylation of Phenol with Formaldehyde to Bisphenol F[J]. Chem Eng J, 2016,298:271-280. doi: 10.1016/j.cej.2016.04.038
9. [9]
  Wang F, Li J, Yuan J. Short Channeled Zr-Ce-SBA-15 Supported Palladium Catalysts for Toluene Catalytic Oxidation[J]. Catal Commun, 2011,12(15):1415-1419. doi: 10.1016/j.catcom.2011.05.021
10. [10]
  Sun H, Han J, Ding Y. One-Pot Synthesized Mesoporous Ca/SBA-15 Solid Base for Transesterification of Sunflower Oil with Methanol[J]. Appl Catal A:Gen, 2010,390(1/2):26-34.
11. [11]
  Liu N, Wu Z, Li M. Low-Temperature Preparation of a Mesoporous Silica Superbase by Employing the Multifunctionality of a La₂O₃ Interlayer[J]. ChemCatChem, 2017,9(9):1641-1647. doi: 10.1002/cctc.201601246
12. [12]
  Liu N, Wu Z, Li M. A Novel Strategy for Constructing Mesoporous Solid Superbase Catalysts:Bimetallic Al-La Oxides Supported on SBA-15 Modified with KF[J]. Catal Sci Technol, 2017,7(3):725-733. doi: 10.1039/C6CY02334G
13. [13]
  Zhang J, Ju X, Wu Z Y. Structural Characteristics of Cerium Oxide Nanocrystals Prepared by the Microemulsion Method[J]. Chem Mater, 2001,13(11):4192-4197. doi: 10.1021/cm010235p
14. [14]
  Sreedhala S, Vinod C P. Surfactant Assisted Formation of Ruthenium Nanochains under Mild Conditions and Their Catalytic CO Oxidation Activity[J]. Chem Comm, 2015,51(50):10178-10181. doi: 10.1039/C4CC09430A
15. [15]
  Badamali S K, Luque R, Clark J H. Microwave Assisted Oxidation of a Lignin Model Phenolic Monomer Using Co(salen)/SBA-15[J]. Catal Commun, 2009,10(6):1010-1013. doi: 10.1016/j.catcom.2008.12.051
16. [16]
  Wang N, Chu W, Zhang T. Synthesis, Characterization and Catalytic Performances of Ce-SBA-15 Supported Nickel Catalysts for Methane Dry Reforming to Hydrogen and Syngas[J]. Int J Hydrogen Energy, 2012,37(1):19-30. doi: 10.1016/j.ijhydene.2011.03.138
17. [17]
  Liu X Y, Sun L B, Lu F. Constructing Mesoporous Solid Superbases by a Dualcoating Strategy[J]. J Mater Chem A, 2013,1(5):1623-1631. doi: 10.1039/C2TA00690A
18. [18]
  Li T T, Sun L B, Liu X Y. Isolated Lithium Sites Supported on Mesoporous Silica:A Novel Solid Strong Base with High Catalytic Activity[J]. Chem Commun, 2012,48(51):6423-6425. doi: 10.1039/c2cc32264a
19. [19]
  He T, Qu Y, Wang J. Experimental and Theoretical Study for Vapor Phase Aldol Condensation of Methyl Acetate and Formaldehyde over Alkali Metal Oxides Supported on SBA-15[J]. Ind Eng Chem Res, 2018,57(8):2773-2786. doi: 10.1021/acs.iecr.7b02841
20. [20]
  Jiraroj D, Tongtooltush T, Panpranot J. Catalytic Cracking of Biodiesel Waste Using Metal Supported SBA-15 Mesoporous Catalysts[J]. Catalysts, 2019,9(3)291. doi: 10.3390/catal9030291
21. [21]
  Ranucci C R, Colpini L M S, Monteiro M R. Preparation, Characterization and Stability of KF/Si-MCM-41 Basic Catalysts for Application in Soybean Oil Transesterification with Methanol[J]. J Environ Chem Eng, 2015,3(2):703-707. doi: 10.1016/j.jece.2015.02.023
22. [22]
  Tang Y, Ren H, Chang F. Nano KF/Al₂O₃ Particles as an Efficient Catalyst for no-Glycerol Biodiesel Production by Coupling Transesterification[J]. RSC Adv, 2017,7(10):5694-5700. doi: 10.1039/C6RA25782H
23. [23]
  Kalita P, Gupta N M, Kumar R. Synergistic Role of Acid Sites in the Ce-Enhanced Activity of Mesoporous Ce-Al-MCM-41 Catalysts in Alkylation Reactions:FTIR and TPD-Ammonia Studies[J]. J Catal, 2007,245(2):338-347. doi: 10.1016/j.jcat.2006.10.022
24. [24]
  Cheng W, Wang W, Zhao Y. Influence of Acid-Base Properties of ZnMgAl-Mixed Oxides for the Synthesis of 1-Methoxy-2-propanol[J]. Appl Clay Sci, 2008,42(1/2):111-115.
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