Citation: YU Yancun, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Polypyrrole Modified Carbon-Supported Pd Catalyst for Formic Acid Electrooxidation[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1317-1322. doi: 10.11944/j.issn.1000-0518.2019.11.190065 shu

Polypyrrole Modified Carbon-Supported Pd Catalyst for Formic Acid Electrooxidation

YU Yancun ^a,b ,
WANG Xian ^a,c ,
GE Junjie ^a,d ,
LIU Changpeng ^a,d ,
XING Wei ^a,d,,

a.
Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
University of Science and Technology of China(USTC), Hefei 230026, China
d.
Jilin Province Key Laboratory of Advanced Low Carbon Power Sources, Changchun 130022, China

Corresponding author: XING Wei, xingwei@ciac.ac.cn
Received Date: 13 March 2019
Revised Date: 27 March 2019
Accepted Date: 24 April 2019

Fund Project: Jilin Province Science and Technology Development Program 20180101030JCSupported by the National Natural Science Foundation of China(No.21633008, No.21733004, No.21603216), Jilin Province Science and Technology Development Program(No.20180101030JC), and the Hundred Talents Program of Chinese Academy of Sciencesthe National Natural Science Foundation of China 21603216the National Natural Science Foundation of China 21733004the National Natural Science Foundation of China 21633008

Figures(5)

The active component of active carbon-supported Pd of the anode catalyst in direct formic acid fuel cell(DFAFC) is easy to aggregate and has electrocorrosive effect on the carbon carrier, resulting in low catalytic activity and stability. In this paper, regulating the carbon catalyst carrier effectively improved the catalytic activity and stability for formic acid electrooxidation. The polypyrrole(PPy) doped carbon was synthesized by low temperature chemical oxidation and activated carbon was added during the polymerization process. Pd catalyst supported on the carbon composites was prepared. The surface morphology of the pyropolypyrrole doped catalyst was characterized. It is found that the Pd nanoparticles could be stabilized at 2.25 nm. The surface nitrogen element of the catalyst exists in the form of pyrrole nitrogen. The carbon-based pyrolytic polypyrrole supported Pd has excellent performance for the formic acid electrocatalytic oxidation. Compared with the Pd/C catalyst, the specific activity per Pd unit mass is increased by 2.5 times.
- fuel cell,
- formic acid,
- electrooxidation,
- polypyrrole,
- Pd catalyst
1. [1]
  Yu X W, Pickup P G. Recent Advances in Direct Formic Acid Fuel Cells(DFAFC)[J]. J Power Sources, 2008,182(1):124-132. doi: 10.1016/j.jpowsour.2008.03.075
2. [2]
  YUAN Qingyun, TANG Yawen, ZHOU Yiming. Formic Acid as Methanol-alternative Fuel in Direct Methanol Fuel Cell[J]. Chinese J Appl Chem, 2005,22(9):7-10.
3. [3]
  Lu Y X, Du S F, Steinberger-wilckens R. One-Dimensional Nanostructured Electrocatalysts for Polymer Electrolyte Membrane Fuel Cells-A Review[J]. Appl Catal B-Environ, 2016,199:292-314. doi: 10.1016/j.apcatb.2016.06.022
4. [4]
  Shao Y Y, Yin G P, Gao Y Z. Understanding and Approaches for the Durability Issues of Pt-Based Catalysts for Pem Fuel Cell[J]. J Power Sources, 2007,171(2):558-566. doi: 10.1016/j.jpowsour.2007.07.004
5. [5]
  Ji X L, Lee K T, Holden R. Nanocrystalline Intermetallics on Mesoporous Carbon for Direct Formic Acid Fuel Cell Anodes[J]. Nat Chem, 2010,2(4):286-293. doi: 10.1038/nchem.553
6. [6]
  Zhang S, Shao Y Y, Liao H G. Graphene Decorated with Ptau Alloy Nanoparticles: Facile Synthesis and Promising Application for Formic Acid Oxidation[J]. Chem Mat, 2011,23(5):1079-1081. doi: 10.1021/cm101568z
7. [7]
  Tian N, Zhou Z Y, Sun S G. Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity[J]. Science, 2007,316(5825):732-735. doi: 10.1126/science.1140484
8. [8]
  Mota-Lima A, Silva D R, Gasparotto L H S. Stationary and Damped Oscillations in a Direct Formic Acid Fuel Cell(DFAFC) Using Pt/C[J]. Electrochim Acta, 2017,235:135-142. doi: 10.1016/j.electacta.2017.03.056
9. [9]
  Antolini E. Palladium in Fuel Cell Catalysis[J]. Energy Environ Sci, 2009,2(9):915-931. doi: 10.1039/b820837a
10. [10]
  Yan H J, Jiao Y Q, Wu A P. Synergism of Molybdenum Nitride and Palladium for High-Efficiency Formic Acid Electrooxidation[J]. J Mater Chem A, 2018,6(17):7623-7630. doi: 10.1039/C8TA02488J
11. [11]
  LI Huanzhi, SHEN Juanzhang, YANG Gaixiu. Anodic Pd Catalyst in Direct Formic Acid Fuel Cell and Its Electrocatalytic Stability[J]. Chem J Chinese Univ, 2011,32(7):1445-1450.
12. [12]
  El-Nagar G A, Dawood K M, El-Deab M S. Efficient Direct Formic Acid Fuel Cell(DFAFC) Anode of Nano-sized Palladium Complex:High Durability and Activity Origin[J]. Appl Catal B-Environ, 2017,213:118-126. doi: 10.1016/j.apcatb.2017.05.006
13. [13]
  Wang A L, Xu H, Feng J X. Design of Pd/PANI/Pd Sandwich-Structured Nanotube Array Catalysts with Special Shape Effects and Synergistic Effects for Ethanol Electrooxidation[J]. J Am Chem Soc, 2013,135(29):10703-10709. doi: 10.1021/ja403101r
14. [14]
  Han H, Noh Y, Kim Y. Electrocatalytic Oxidations of Formic Acid and Ethanol over Pd Catalysts Supported on a Doped Polypyrrole-Carbon Composite[J]. Chem Select, 2017,2(22):6260-6268.
15. [15]
  Wang W N, Gao Y C, Jia X D. A Novel Au-Pt@Ppy(Polypyrrole) Coral-Like Structure: Facile Synthesis, High SERS Effect, and Good Electro Catalytic Activity[J]. J Colloid Interface Sci, 2013,396:23-28. doi: 10.1016/j.jcis.2012.12.059
16. [16]
  Aydin R, Dogan H O, Koleli F. Electrochemical Reduction of Carbondioxide on Polypyrrole Coated Copper Electro-Catalyst under Ambient and High Pressure in Methanol[J]. Appl Catal B-Environ, 2013,140:478-482.
17. [17]
  Zheng L, Dong Y Y, Chi B. UIO-66-NH₂-Derived Mesoporous Carbon Catalyst Co-Doped with Fe/N/S as Highly Efficient Cathode Catalyst for PEMFCs[J]. Small, 2019,15(4)1803520. doi: 10.1002/smll.201803520
18. [18]
  Bi Q Y, Lin J D, Liu Y M. Dehydrogenation of Formic Acid at Room Temperature:Boosting Palladium Nanoparticle Efficiency by Coupling with Pyridinic-Nitrogen-Doped Carbon[J]. Angew Chem Int Ed, 2016,55(39):11849-11853. doi: 10.1002/anie.201605961
19. [19]
  LIU Jiajia, WU Bing, GAO Ying. Preparation of Polypyrrole-Carbon Black Supported Pd Catalyst for Formic Acid Electrooxidation[J]. Acta Chim Sin, 2012,70(16):1743-1747.
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