Citation: YU Yancun, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Polypyrrole Modified Carbon-Supported Pd Catalyst for Formic Acid Electrooxidation[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1317-1322. doi: 10.11944/j.issn.1000-0518.2019.11.190065 shu

Polypyrrole Modified Carbon-Supported Pd Catalyst for Formic Acid Electrooxidation

YU Yancun ^a,b ,
WANG Xian ^a,c ,
GE Junjie ^a,d ,
LIU Changpeng ^a,d ,
XING Wei ^a,d,,

a.
Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
University of Science and Technology of China(USTC), Hefei 230026, China
d.
Jilin Province Key Laboratory of Advanced Low Carbon Power Sources, Changchun 130022, China

Corresponding author: XING Wei, xingwei@ciac.ac.cn
Received Date: 13 March 2019
Revised Date: 27 March 2019
Accepted Date: 24 April 2019

Fund Project: Jilin Province Science and Technology Development Program 20180101030JCSupported by the National Natural Science Foundation of China(No.21633008, No.21733004, No.21603216), Jilin Province Science and Technology Development Program(No.20180101030JC), and the Hundred Talents Program of Chinese Academy of Sciencesthe National Natural Science Foundation of China 21603216the National Natural Science Foundation of China 21733004the National Natural Science Foundation of China 21633008

Figures(5)

The active component of active carbon-supported Pd of the anode catalyst in direct formic acid fuel cell(DFAFC) is easy to aggregate and has electrocorrosive effect on the carbon carrier, resulting in low catalytic activity and stability. In this paper, regulating the carbon catalyst carrier effectively improved the catalytic activity and stability for formic acid electrooxidation. The polypyrrole(PPy) doped carbon was synthesized by low temperature chemical oxidation and activated carbon was added during the polymerization process. Pd catalyst supported on the carbon composites was prepared. The surface morphology of the pyropolypyrrole doped catalyst was characterized. It is found that the Pd nanoparticles could be stabilized at 2.25 nm. The surface nitrogen element of the catalyst exists in the form of pyrrole nitrogen. The carbon-based pyrolytic polypyrrole supported Pd has excellent performance for the formic acid electrocatalytic oxidation. Compared with the Pd/C catalyst, the specific activity per Pd unit mass is increased by 2.5 times.
- fuel cell,
- formic acid,
- electrooxidation,
- polypyrrole,
- Pd catalyst
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