Citation: WANG Youhao, LI Fashe, WANG Wenchao, CHEN Yu. Effects of Light Wavelengths on Oxidative Stability of Biodiesel[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1301-1307. doi: 10.11944/j.issn.1000-0518.2019.11.190041 shu

Effects of Light Wavelengths on Oxidative Stability of Biodiesel

WANG Youhao ^a ,
LI Fashe ^a,b,, ,
WANG Wenchao ^a,b ,
CHEN Yu ^a,b

a.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction, Kunming University of Science and Technology, Kunming 650093, China

Corresponding author: LI Fashe, asan97@qq.com
Received Date: 18 February 2019
Revised Date: 25 April 2019
Accepted Date: 29 May 2019

Fund Project: the National Natural Science Foundation of China 51766007the Natural Science Foundation of Yunnan Province 2018FB092Supported by the National Natural Science Foundation of China(No.51766007), and the Natural Science Foundation of Yunnan Province(No.2018FB092)

Figures(5)

In order to study the effect of light on the oxidation stability of biodiesel, the jatropha biodiesel was treated with light in different wavelengths at 20℃ for 48 hours. The treated samples were then analyzed for oxidative stability. The results showed that light promoted the oxidation of biodiesel. The short-wavelength light represented by violet light had the strongest promoting effect on the oxidation of jatropha oil biodiesel. The induction period decreased from 5.12 h to 2.65 h in 48%; the red light with longer wavelength has the weakest promoting effect on the oxidation of biodiesel, and the induction period is reduced to 4.61 h, which is reduced in 10%. The acid value titration, composition analysis and UV characterization of light-treated biodiesel with different wavelengths showed that the acid value of biodiesel increased from 0.2577 mg/g to 0.3438 mg/g as the wavelength of light decreased. The relative content of methyl linoleate in the carbon-carbon double bond decreases; the absorption peak of the conjugated double bond increases. This shows that the shorter the wavelength of light, the stronger the promotion toward biodiesel oxidation.
- biodiesel,
- oxidation stability,
- photooxidation
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