Citation: GUO Hongchen, QIN Yusheng, WANG Xianhong, WANG Fosong. Copolymerization of Carbon Dioxide and Propylene Oxide under Aluminum Porphyrin Catalyst[J]. Chinese Journal of Applied Chemistry, ;2019, 36(10): 1118-1127. doi: 10.11944/j.issn.1000-0518.2019.10.190031 shu

Copolymerization of Carbon Dioxide and Propylene Oxide under Aluminum Porphyrin Catalyst

GUO Hongchen ^a,b ,
QIN Yusheng ^a ,
WANG Xianhong ^a,b,, ,
WANG Fosong ^a,b

a.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Xianhong, xhwang@ciac.ac.cn
Received Date: 29 January 2019
Revised Date: 5 March 2019
Accepted Date: 2 April 2019

Fund Project: the Key Research Projects in Frontier Science of the Chinese Academy of Sciences QYZDJ-SSW-JSC017Supported by the Key Research Projects in Frontier Science of the Chinese Academy of Sciences(No.QYZDJ-SSW-JSC017)

Figures(3)

Aluminum porphyrin is a soil-tolerant metal porphyrin complex. Although its catalytic activity on the copolymerization of CO₂ and propylene oxide has been disclosed by Inoue in 1978, the catalytic activity is still very low, and the synthesized poly(propylene carbonate) has low relative molecular mass. It is a big challenge to make progress on the catalytic performance of aluminum porphyrin. In this work, the electronic environment of central aluminum was adjusted by delicate design of porphyrin ligand using meso-tetrasubstituted porphyrin derivatives that were employed to catalyze the copolymerization of CO₂ and propylene oxide with bis-(triphenyl phosphine) iminium chloride(PPNCl) as the co-catalyst. It was found that the electronic environment of the central aluminum ion had great effect on the catalytic performance of aluminum porphyrin catalysts, the turnover frequency(TOF) value of Cl substituted aluminum porphyrin catalyst 6a reached 2672 h^-1 at 90℃ and 3 MPa, while poly(propylene carbonate) with relative molecular mass of 1.84×10⁴ was afforded using catalyst 4b bearing toluene sulfonic group(OTs^-) as axial group of good leaving ability. Our work indicates that delicate designed aluminum porphyrin can become a possible candidate as high performance catalyst in the copolymerization of CO₂ and propylene oxide, under optimized copolymerization conditions.
- aluminum porphyrin,
- carbon dioxide,
- propylene oxide,
- poly(propylene carbonate)
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