Citation: LIU Shiwei, Liang LIANG, LI Chenyang, LIU Changpeng, XING Wei, DONG Xiandui. Multilayered Anode Catalytic Electrode in High-Temperature Proton Exchange Membrane Fuel Cell[J]. Chinese Journal of Applied Chemistry, ;2019, 36(9): 1085-1090. doi: 10.11944/j.issn.1000-0518.2019.09.190034 shu

Multilayered Anode Catalytic Electrode in High-Temperature Proton Exchange Membrane Fuel Cell

LIU Shiwei ^a,b ,
Liang LIANG ^a,b ,
LI Chenyang ^a ,
LIU Changpeng ^a ,
XING Wei ^a,, ,
DONG Xiandui ^a,,

a.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: XING Wei, xingwei@ciac.ac.cn DONG Xiandui, dxd@ciac.ac.cn
Received Date: 31 January 2019
Revised Date: 13 March 2019
Accepted Date: 23 April 2019

Fund Project: the Key Deployment Program of CAS KFZD-SW-412the National Natural Science Foundation of China U1601211the National Natural Science Foundation of China 21433003the National Natural Science Foundation of China 21673221the Jilin Province Science and Technology Development Plan Project 20170203003SFSupported by the National Natural Science Foundation of China(No.21673221, No.21433003, No.U1601211), the Jilin Province Science and Technology Development Plan Project(No.20170203003SF), and the Key Deployment Program of CAS(No.KFZD-SW-412)

Figures(5)

High temperature proton exchange membrane fuel cell is a promising energy conversion device with the advantages of toxicity resistance and good stability. In this report, the multilayered catalytic structure was designed to improve anode electrode catalytic activity of fuel cell. Poly vinylidene fluoride co-hexafluoropropylene(PVDF-HFP) and polybenzimidazoles(PBI) are used as electrode binders to adjust the wettability of the diffusion electrode interface. The surface morphology and wettability of the electrode catalyst have been characterized. It was found that the porosity and roughness of the electrode layer were improved. The wettability distinction between layers(contact angles:149° for PVDF-HFP and 19° for PBI) was conducive to produce more stable three-phase reaction interfaces. The catalytic performance of fuel cells shows that the peak power density is enhanced by about 22%, and it has retained 82.1% and 71.4% in H₂ fuel containing CO at the concentrations of 10000 mg/m³ and 30000 mg/m³, respectively. It is concluded that the catalytic layer with such structure could increase the catalyst utilization and still maintain good toxic resistance to CO impurity inside fuel gas.
- hydrogen electro-oxidation,
- phosphoric acid fuel cell,
- gas diffusion electrode,
- anti-poison,
- polybenzimidazoles membrane
1. [1]
  Wang S Y, Jiang S P. Prospects of Fuel Cell Technologies[J]. Nat Sci Rev, 2017,4(2):163-166.
2. [2]
  Krishnana N N, Lee S, Ghorpade R V. Polybenzimidazole(PBI-OO) Based Composite Membranes Using Sulfophenylated TiO₂ as Both Filler and Crosslinker, and Their Use in the HT-PEM Fuel Cell[J]. J Membr Sci, 2018,560:11-20. doi: 10.1016/j.memsci.2018.05.006
3. [3]
  Rosli R E, Sulong A B, Daud W R W. A Review of High-Temperature Proton Exchange Membrane Fuel Cell(HT-PEMFC) System[J]. Int J Hydrogen Energy, 2017,42(14):9293-9314. doi: 10.1016/j.ijhydene.2016.06.211
4. [4]
  Araya S S, Zhou F, Liso V. A Comprehensive Review of PBI-Based High Temperature PEM Fuel Cells[J]. Int J Hydrogen Energy, 2016,41(46):21310-21344. doi: 10.1016/j.ijhydene.2016.09.024
5. [5]
  Asensio J A, Sanchez E M, Gomez-Romero P. Proton-Conducting Membranes Based on Benzimidazole Polymers for High-Temperature PEM Fuel Cells. A Chemical Ques[J]. Chem Soc Rev, 2010,39(2):3210-3239. doi: 10.1039/B922650H
6. [6]
  Melchior J P, Majer G, Kreuer K D. Why do Proton Conducting Polybenzimidazole Phosphoric Acid Membranes Perform well in High-Temperature PEM Fuel Cells?[J]. Phys Chem Chem Phys, 2016,19(1):601-612. doi: 10.1039/C6CP05331A
7. [7]
  Xu W, Lu Z, Sun X. , Superwetting Electrodes for Gas-Involving Electrocatalysis[J]. Acc Chem Res, 2018,51(7):1590-1598. doi: 10.1021/acs.accounts.8b00070
8. [8]
  Ma Y L, Wainright J S, Litt M H. Conductivity of PBI Membranes for High-Temperature Polymer Electrolyte Fuel Cells[J]. J Electrochem Soc, 2004,151(1):A8-A16. doi: 10.1149/1.1630037
9. [9]
  Orogbemi O M, Ingham D B, Ismail M S. The Effects of the Composition of Microporous Layers on the Permeability of Gas Diffusion Layers Used in Polymer Electrolyte Fuel Cells[J]. Int J Hydrogen Energy, 2016,41(46):21345-21351. doi: 10.1016/j.ijhydene.2016.09.160
10. [10]
  Yuk S, Lee D H, Choi S. An Electrode-Supported Fabrication of Thin Polybenzimidazole Membrane-Based Polymer Electrolyte Membrane Fuel Cell[J]. Electrochim Acta, 2018,270:402-408. doi: 10.1016/j.electacta.2018.03.052
11. [11]
  Su H N, Xu Q, Chong J J. Eliminating Micro-Porous Layer from Gas Diffusion Electrode for Use in High Temperature Polymer Electrolyte Membrane Fuel Cell[J]. Power Sources, 2017,341:302-308. doi: 10.1016/j.jpowsour.2016.12.029
12. [12]
  Majlan E H, Rohendi D, Daud W R W. Electrode for Proton Exchange Membrane Fuel Cells:A review[J]. Renew Sust Energ Rev, 2018,89:117-134. doi: 10.1016/j.rser.2018.03.007
13. [13]
  Lv Q, Li K, Liu C. TiO₂ Inserted Carbon Materials with Fine-Tuned Pore Structure as Effective Model Supports for Electrocatalysts of fuel Cells[J]. Carbon, 2016,98:126-137. doi: 10.1016/j.carbon.2015.10.097
14. [14]
  YANG Juan, YUAN Ting, ZHANG Haifeng. Effect of Hydrophobicity of Anodic Backing Layer on Mass Transfer Characteristics of Passive DMFCs[J]. Chinese J Appl Chem, 2013,30(11):1348-1353.
1. [1]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
2. [2]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
3. [3]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
4. [4]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
5. [5]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
6. [6]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
7. [7]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
10. [10]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
11. [11]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
12. [12]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
13. [13]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
14. [14]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
15. [15]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
16. [16]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
17. [17]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
20. [20]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(469)
HTML views(75)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142