Citation: CHE Tinghua, TAN Xiao, YAN Jiawei, SONG Fengdan, ZHANG Hongmei, QI Suitao. Synthesis of Copper Modified Porous Nickel Self-supported Electrode and Its Catalytic Oxidation of Glucose[J]. Chinese Journal of Applied Chemistry, ;2019, 36(9): 1091-1098. doi: 10.11944/j.issn.1000-0518.2019.09.190005 shu

Synthesis of Copper Modified Porous Nickel Self-supported Electrode and Its Catalytic Oxidation of Glucose

Shaanxi Key Laboratory of Energy and Chemical Process Intensification, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China

Corresponding author: QI Suitao, suitaoqi@mail.xjtu.edu.cn
Received Date: 7 January 2019
Revised Date: 13 March 2019
Accepted Date: 29 April 2019

Fund Project: Supported by the Fundamental Research Funds for the Central Universities(No.xjj2016045)the Fundamental Research Funds for the Central Universities xjj2016045

Figures(7)

Porous Ni(nickel foam, NF) self-supported electrodes modified by Cu₂O/Cu were fabricated by hydrothermal method. Their morphology and structure were characterized by X-ray diffraction(XRD) and field-emission scanning electron microscopy(FESEM). The resulted surface of porous Ni is completely covered with octahedral Cu₂O/Cu composites of different sizes. The maximum diameter of the octahedron is about 5 μm. The glucose catalytic oxidation activity of Cu₂O/Cu-NF was measured by cyclic voltammetry and constant potential amperometric method in alkaline medium with three-electrode system. The results show that the Cu₂O/Cu-NF fabricated at 150℃ has the strongest electrocatalytic activity. The linear relationship of response current and glucose concentration could be observed clearly in the range of 3.7×10^-3~1.1 mmol/L and 1.4~5.0 mmol/L, with sensitivity of 6929 μA/(mmol·L^-1·cm²) and 706.1 μA/(mmol·L^-1·cm²), respectively. Satisfyingly, the Cu₂O/Cu-NF electrode is successfully employed to eliminate the interferences from uric acid(UA), acid ascorbic(AA) and L-proline(L-P) during the catalytic oxidation of glucose. The response current of Cu₂O/Cu-NF electrode for glucose electrocatalytic oxidation could reach 91.6% of the original current after one month. The Cu₂O/Cu-NF electrode allows highly sensitive, excellently selective, stable, and fast amperometric sensing of glucose and thus is promising for the future development of nonenzymatic glucose sensors.
- electrocatalysis,
- glucose oxidation,
- porous Ni self-supported electrode
1. [1]
  Brouzgou A, Tsiakaras P. Electrocatalysts for Glucose Electrooxidation Reaction:A Review[J]. Top Catal, 2015,58(18):1-17.
2. [2]
  BAI Hongyan, WANG Xiuhua, DAI Zhihui. Research Development of Non-enzymatic Glucose Detection[J]. Chinese J Appl Chem, 2012,29(6):611-615.
3. [3]
  Wang G F, He X P, Wang L L. Non-enzymatic Electrochemical Sensing of Glucose[J]. Microchim Acta, 2013,180(3):161-186. doi: 10.1007/s00604-012-0923-1
4. [4]
  Su S, Lu Z W, Li J. MoS₂-Au@Pt Nanohybrid as a Sensing Platform for Electrochemical Nonenzymatic Glucose Detection[J]. New J Chem, 2018,42(9):6750-6755. doi: 10.1039/C8NJ00940F
5. [5]
  Ma L, Wang X Y, Zhang Q R. Pt Catalyzed Formation of a Ni@Pt/reduced Graphene Oxide Nanocomposite:Preparation and Electrochemical Sensing Application for Glucose Detection[J]. Anal Methods, 2018,10(31):3845-3850. doi: 10.1039/C8AY01275J
6. [6]
  Meg as-Sayago C, Bobadilla L F, Ivanova S. Gold Catalyst Recycling Study in Base-free Glucose Oxidation Reaction[J]. Catal Today, 2017,301:72-77.
7. [7]
  Derrien E, Mounguenguidiallo M, Perret N. Aerobic Oxidation of Glucose to Glucaric Acid under Alkaline-Free Conditions:Au-Based Bimetallic Catalysts and Effect of Residues in a Hemicellulose Hydrolysate[J]. Ind Eng Chem Res, 2017,56(45):13176-13190. doi: 10.1021/acs.iecr.7b01571
8. [8]
  Li F, Feng Y, Yang L M. A Selective Novel Non-enzyme Glucose Amperometric Biosensor Based on Lectin Sugar Binding on Thionine Modified Electrode[J]. Biosens Bioelectron, 2011,26(5):2489-2494. doi: 10.1016/j.bios.2010.10.040
9. [9]
  Gough D A, Anderson F L, Giner J. Effect of Coreactants on Electrochemical Glucose Oxidation[J]. Anal Chem, 1978,50(7):941-944. doi: 10.1021/ac50029a029
10. [10]
  Vassilyev Y B, Khazova O A, Nikolaeva N N J. Kinetics and Mechanism of Glucose Electrooxidation on Different Electrode-Catalysts:Part Ⅰ.Adsorption and Oxidation on Platinum[J]. Electroanal Chem, 1985,196(1):105-125. doi: 10.1016/0022-0728(85)85084-1
11. [11]
  Guo C Y, Huo H H, Han X. Ni/CdS Bifunctional Ti@TiO₂ Core Shell Nanowire Electrode for High-Performance Nonenzymatic Glucose Sensing[J]. Anal Chem, 2014,86(1):876-883. doi: 10.1021/ac4034467
12. [12]
  Darvishi S, Souissi M, Kharaziha M. Gelatin Methacryloyl Hydrogel for Glucose Biosensing Using Ni Nanoparticles-Reduced Graphene Oxide:An Experimental and Modeling Study[J]. Electrochim Acta, 2018,261:275-283. doi: 10.1016/j.electacta.2017.12.126
13. [13]
  Zhang Q, Luo Q, Qin Z B. Self-assembly of Graphene-Encapsulated Cu Composites for Nonenzymatic Glucose Sensing[J]. ACS Omega, 2018,3(3):3420-3428. doi: 10.1021/acsomega.7b01197
14. [14]
  Zhang Y, Zhao D Y, Zhu W X. Engineering Multi-stage Nickel Oxide Rod-On-Sheet Nanoarrays on Ni Foam:A Superior Catalytic Electrode for Ultrahigh-Performance Electrochemical Sensing of Glucos[J]. Sens Actuators B, 2018,255:416-423. doi: 10.1016/j.snb.2017.08.078
15. [15]
  El-Refaei S M, Saleh M M, Awad M I. Enhanced Glucose Electrooxidation at a Binary Catalyst of Manganese and Nickel Oxides Modified Glassy Carbon Electrode[J]. J Power Sources, 2013,223:125-128. doi: 10.1016/j.jpowsour.2012.08.098
16. [16]
  Amaniampong P N, Trinh Q T, Li K X. Porous Structured CuO-CeO₂ Nanospheres for the Direct Oxidation of Cellobiose and Glucose to Gluconic Acid[J]. Catal Today, 2018,306:172-182. doi: 10.1016/j.cattod.2017.01.009
17. [17]
  Xu D, Zhu C L, Meng X. Design and Fabrication of Ag-CuO Nanoparticles on Reduced Grapheme Oxide for Nonenzymatic Detection of Glucose[J]. Sens Actuators B, 2018,265:435-442. doi: 10.1016/j.snb.2018.03.086
18. [18]
  Li Y C, Zhong Y M, Zhang Y Y. Carbon Quantum Dots/octahedral Cu₂O Nanocomposites for Non-enzymatic Glucose and Hydrogen Peroxide Amperometric Sensor[J]. Sens Actuators B, 2015,206:735-743. doi: 10.1016/j.snb.2014.09.016
19. [19]
  Khan R, Ahmad R, Rai P. Glucose-Assisted Synthesis of Cu₂O Shuriken-Like Nanostructures and Their Application as Nonenzymatic Glucose Biosensors[J]. Sens Actuators B, 2014,203:471-476. doi: 10.1016/j.snb.2014.06.128
20. [20]
  Hou C T, Xu Q, Yin L N. Metal-organic Framework Templated Synthesis of Co₃O₄ Nanoparticles for Direct Glucose and H₂O₂ Detection[J]. Analyst, 2012,137(24):5803-5808. doi: 10.1039/c2an35954e
21. [21]
  Liu M M, Liu R, Chen W. Graphene wrapped Cu₂O Nanocubes:Non-enzymatic Electrochemical Sensors for the Detection of Glucose and Hydrogen Peroxide with Enhanced Stability[J]. Biosens Bioelectron, 2013,45:206-212. doi: 10.1016/j.bios.2013.02.010
22. [22]
  Kung C W, Cheng Y H, Ho K C. Single Layer of Nickel Hydroxide Nanoparticles Covered on a Porous Ni Foam and Its Application for Highly Sensitive Non-enzymatic Glucose Sensor[J]. Sens Actuators B, 2014,204:159-166. doi: 10.1016/j.snb.2014.07.102
23. [23]
  Wang L, Xie Y Z, Wei C T. Hierarchical NiO Superstructures/Foam Ni Electrode Derived from Ni Metal-Organic Framework Flakes on Foam Ni for Glucose Sensing[J]. Electrochim Acta, 2015,174:846-852. doi: 10.1016/j.electacta.2015.06.086
24. [24]
  Jafarian M, Forouzandeh F, Danaee I. Electrocatalytic Oxidation of Glucose on Ni and NiCu Alloy Modified Glassy Carbon Electrode[J]. J Solid State Electrochem, 2009,13(8):1171-1179. doi: 10.1007/s10008-008-0632-1
25. [25]
  HAO Miaoqing. Performance and Mechanism of the Direct Biomass Alkaline Fuel Cell[D]. Tianjin: Tianjin University, 2013(in Chinese).
26. [26]
  Dong C J, Tao Y, Chang Q. Direct Growth of MnCO₃ on Ni Foil for a Highly Sensitive Nonenzymatic Glucose Sensor[J]. J Alloys Compd, 2018,762(25):216-221.
27. [27]
  Zhang H Y, Liu S. Nanoparticles-Assembled NiO Nanosheets Templated by Graphene Oxide Film for Highly Sensitive Non-enzymatic Glucose Sensing[J]. Sens Actuators B, 2017,238:788-794. doi: 10.1016/j.snb.2016.07.126
28. [28]
  Fang B, Gu A X, Wang G F. Silver Oxide Nanowalls Grown on Cu Substrate as an Enzymeless Glucose Sensor[J]. ACS Appl Mater Interfaces, 2009,1(12):2829-2834. doi: 10.1021/am900576z
29. [29]
  Wang M, Ma Z Z, Li J P. Well-dispersed Palladium Nanoparticles on Nickel-Phosphorus Nanosheets as Efficient Three-Dimensional Platform for Superior Catalytic Glucose Electro-oxidation and Non-enzymatic Sensing[J]. J Colloid Interface Sci, 2018,511(4):355-364.
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