Citation: JI Fance, LIU Xiangdong, SHENG Dekun, YANG Yuming. Photothermal-Induced Shape Memory Polymers Prepared by Reactive Blending[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 904-908. doi: 10.11944/j.issn.1000-0518.2019.08.190024 shu

Photothermal-Induced Shape Memory Polymers Prepared by Reactive Blending

a.
Chinese Academy of Sciences Key Laboratory of High-Performance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: YANG Yuming, ymyang@ciac.ac.cn
Received Date: 25 January 2019
Revised Date: 27 February 2019
Accepted Date: 18 March 2019

Figures(4)

Based on the high reactivity of carboxyl and epoxy groups, crosslinked polyolefins were successfully prepared by reactive blending of ethylene-glycidyl methacrylate copolymer(PE-GMA) and ethylene acrylic acid copolymer(EAA). The thermodynamic properties and shape memory effect of the obtained polymer were measured by differential scanning calorimeter(DSC) and dynamic mechanical thermal analyses(DMA). The dual-shape memory effect, multi-shape memory effect and two-way shape memory effect were achieved due to the broad distribution of crystallite sizes of the crosslinked polyolefins. By the aid of photothermal effect of graphene oxide(GO), photothermal-induced shape memory effect was also realized. The "temperature gradient" strategy was successfully applied to the photothermal-induced two-way shape memory effect of the crosslinked polyolefins.
- crosslinked polyolefins,
- shape memory effect,
- photothermal effect,
- temperature gradient
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沈阳化工大学材料科学与工程学院沈阳 110142