Citation: LIU Bing, GONG Huili, LIU Rui, HU Changwen. Synthesis of TiO₂ Coated Gold Nanorod with Core-Shell Structure and Its Photocatalytic Hydrogen Evolution[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 939-948. doi: 10.11944/j.issn.1000-0518.2019.08.190004 shu

Synthesis of TiO₂ Coated Gold Nanorod with Core-Shell Structure and Its Photocatalytic Hydrogen Evolution

LIU Bing ^a,, ,
GONG Huili ^a ,
LIU Rui ^a ,
HU Changwen ^b

a.
College of Resources Environment and Tourism, Capital Normal University, Beijing 100048, China
b.
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: LIU Bing, liubing7100@126.com
Received Date: 7 January 2019
Revised Date: 25 February 2019
Accepted Date: 9 April 2019

Figures(13)

TiO₂ coated gold nanorods with core-shell structure(GNR@TiO₂) about 200 nm were synthesized by sol-gel process and hydrothermal method. After hydrothermal crystallization, the particle size of the material expands to 300 nm, while the morphology and the local surface plasmon resonance(LSPR) of GNR have no change. The structure and properties of the samples were characterized by X-ray diffraction(XRD), high resolution transmission electron microscope(HRTEM), X-ray photoelectron spectroscopy(XPS), ultraviolet-visible absorption spectroscopy and photocatalytic hydrogen production. The results show that the hydrogen production rate of crystallized GNR@TiO₂ is 31.0 μmol/(g·h) in the visible light range, which is much higher than that of 7.3 μmol/(g·h) before crystallization. Based on experimental result and finite difference time domain(FDTD) analysis, we proposed a photocatalytic mechanism for efficient hydrogen generation. LSPR promotes the visible light absorption. Anatase TiO₂ enhances the electric field and promotes the photogenerated electron-hole separation. The crystallized TiO₂ shell is porous and multi-mesoporous, which increases the active sites and is conducive to material transfer.
- photocatalysis,
- TiO₂,
- gold nanorods,
- visible light,
- water splitting
1. [1]
  Tong H, Ouyang S, Bi Y. Nano-Photocatalytic Materials:Possibilities and Challenges[J]. Adv Mater, 2012,24(2):229-251. doi: 10.1002/adma.201102752
2. [2]
  Zhou H, Qu Y, Zeid T. Towards Highly Efficient Photocatalysts Using Semiconductor Nanoarchitectures[J]. Energy Environ Sci, 2012,5:6732-6743. doi: 10.1039/c2ee03447f
3. [3]
  Ma Y, Wang X, Jia Y. Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations[J]. Chem Rev, 2014,114(19):9987-11043. doi: 10.1021/cr500008u
4. [4]
  Linsebigler A L, Lu G Q, Yates J T. Photocatalysis on TiO₂ Surfaces:Principles, Mechanisms, and Selected Results[J]. Chem Rev, 1995,95:735-758. doi: 10.1021/cr00035a013
5. [5]
  Chen X, Mao S S. Titanium Dioxide Nanomaterials:Synthesis, Properties, Modifications, and Applications[J]. Chem Rev, 2007,107(7):2891-2959. doi: 10.1021/cr0500535
6. [6]
  Silva C G, Juarez R, Marino T. Influence of Excitation Wavelength(UV or Visible Light) on the Photocatalytic Activity of Titania Containing Gold Nanoparticles for the Generation of Hydrogen or Oxygen[J]. J Am Chem Soc, 2011,133(3):595-602. doi: 10.1021/ja1086358
7. [7]
  Tachikawa T, Yonezawa T, Majima T. Super-Resolution Mapping of Reactive Sites on Titania-Based Nanoparticles with Water-Soluble Fluorogenic Probes[J]. ACS Nano, 2013,7(1):263-275. doi: 10.1021/nn303964v
8. [8]
  Bian Z F, Tachikawa T, Zhang P. Au/TiO₂ Superstructure-Based Plasmonic Photocatalysts Exhibiting Efficient Charge Separation and Unprecedented Activity[J]. J Am Chem Soc, 2014,136(1):458-465. doi: 10.1021/ja410994f
9. [9]
  Knight M W, Sobhani H, Nordlander P. Photodetection with Active Optical Antennas[J]. Science, 2011,332(6030):702-704. doi: 10.1126/science.1203056
10. [10]
  Awazu K, Fujimaki M, Rockstuhl C. A Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide[J]. J Am Chem Soc, 2008,130(5):1676-1680. doi: 10.1021/ja076503n
11. [11]
  Zhang Q, Lima D Q, Lee I. A Highly Active Titanium Dioxide Based Visible-Light Photocatalyst with Nonmetal Doping and Plasmonic Metal Decoration[J]. Angew Chem Int Ed, 2011,50(31):7088-7092. doi: 10.1002/anie.201101969
12. [12]
  Tada H, Mitsui T, Kiyonaga T. All-Solid-State Z-Scheme in CdS-Au-TiO₂ Three-Component Nanojunction System[J]. Nat Mater, 2006,5:782-786. doi: 10.1038/nmat1734
13. [13]
  Mubeen S, Lee J, Singh N. An Autonomous Photosynthetic Device in Which All Charge Carriers Derive from Surface Plasmons[J]. Nat Nanotechnol, 2013,8:247-251. doi: 10.1038/nnano.2013.18
14. [14]
  Christopher P, Xin H L, Linic S. Visible-Light-Enhanced Catalytic Oxidation Reactions on Plasmonic Silver Nanostructures[J]. Nat Chem, 2011,3:467-472. doi: 10.1038/nchem.1032
15. [15]
  Li G, Cherqui C, Bigelow N W. Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS[J]. Nano Lett, 2015,15(5):3465-3471. doi: 10.1021/acs.nanolett.5b00802
16. [16]
  Long R, Mao K, Gong M. Tunable Oxygen Activation for Catalytic Organic Oxidation:Schottky Junction Versus Plasmonic Effects[J]. Angew Chem Int Ed, 2014,126(12):3269-3273. doi: 10.1002/ange.201309660
17. [17]
  Long R, Rao Z, Mao K. Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well-Designed Palladium Nanostructures[J]. Angew Chem Int Ed, 2015,54(8):2425-2430. doi: 10.1002/anie.201407785
18. [18]
  Jiang R, Li B, Fang C. Metal/Semiconductor Hybrid Nanostructures for Plasmon-Enhanced Applications[J]. Adv Mater, 2014,26(31):5274-5309. doi: 10.1002/adma.201400203
19. [19]
  Law M, Greene L E, Joh J C. Plasmon-Induced Hot-Electron Generation at Nanoparticle/Metal-Oxide Interfaces for Photovoltaic and Photocatalytic Devices[J]. Nat Photonics, 2014,8:95-103. doi: 10.1038/nphoton.2013.238
20. [20]
  Murray W A, Barnes W L. Plasmonic Materials[J]. Adv Mater, 2007,19(22):3771-3782. doi: 10.1002/adma.200700678
21. [21]
  Anker J N, Hall W P, Lyandres O. Biosensing with Plasmonic Nanosensors[J]. Nat Mater, 2008,7:442-453. doi: 10.1038/nmat2162
22. [22]
  Pu Y C, Wang G, Chang K D. Au Nanostructure Decorated TiO₂ Nanowires Exhibiting Photoactivity Across Entire UV-Visible Region for Photoelectrochemical Water Splitting[J]. Nano Lett, 2013,13(8):3817-3823. doi: 10.1021/nl4018385
23. [23]
  Liu L Q, Ouyang S X, Ye J. Gold-Nanorod-Photosensitized Titanium Dioxide with Wide-Range Visible-Light Harvesting Based on Localized Surface Plasmon Resonance[J]. Angew Chem Int Ed, 2013,125(26):6821-6825. doi: 10.1002/ange.201300239
24. [24]
  Liu R, Sen A. Controlled Synthesis of Heterogeneous Metal-Titania Nanostructures and Their Applications[J]. J Am Chem Soc, 2012,134(42):17505-17512. doi: 10.1021/ja211932b
25. [25]
  Fang C, Jia H, Chang S. (Gold Core)/(Titania Shell) Nanostructures for Plasmon-Enhanced Photon Harvesting and Generation of Reactive Oxygen Species[J]. Energy Environ Sci, 2014,7:3431-3438. doi: 10.1039/C4EE01787K
26. [26]
  Ma X Y, Chen Z G, Hartono S B. Fabrication of Uniform Anatase TiO₂ Particles Exposed by {001} Facets[J]. Chem Commun, 2010,46:6608-6610. doi: 10.1039/c0cc01473g
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Synthesis of TiO2 Coated Gold Nanorod with Core-Shell Structure and Its Photocatalytic Hydrogen Evolution

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通讯作者: 陈斌, bchen63@163.com

Synthesis of TiO₂ Coated Gold Nanorod with Core-Shell Structure and Its Photocatalytic Hydrogen Evolution