Citation: QIN Sinan, TANG Luhua, GAO Wenhui. Cyhalothrin Molecularly Imprinted Electrochemical Sensor: Preparation, Performance and Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 958-967. doi: 10.11944/j.issn.1000-0518.2019.08.180414 shu

Cyhalothrin Molecularly Imprinted Electrochemical Sensor: Preparation, Performance and Application

Research Center for Fermentation Engineering of Hebei, College of Biological Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050000, China

Corresponding author: GAO Wenhui, wenhuigao@126.com
Received Date: 28 December 2018
Revised Date: 4 March 2019
Accepted Date: 3 April 2019

Fund Project: Supported by Science and Technology Planning Project of Hebei Province(No.16275503D), Scientific and Technological Research and Development Project of Shijiazhuang City(No.181490372A)Scientific and Technological Research and Development Project of Shijiazhuang City 181490372AScience and Technology Planning Project of Hebei Province 16275503D

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A novel molecularly imprinted electrochemical sensor with specific recognition ability to template molecules and its structural analogs were prepared by electro-polymerization. Cyhalothrin was used as the template molecule and o-phenylenediamine and o-aminophenol as composite functional monomers. The imprinting effect and analytical performance of the sensor were characterized by cyclic voltammetry and square wave voltammetry. A rapid analysis method was established for determination of cyhalothrin residues in agricultural products. Under the optimal conditions, the linear relationship of cyhalothrin was good within the concentration range of 1.0×10^-7~1.0×10^-5 mol/L, and the detection limit(S/N=3) was 3.0×10^-8 mol/L, the average recoveries of spiked sample were between 84.8% and 94.7%, and the relative standard deviations(RSDs) were 1.1%~4.8%(n=5). This sensor has advantages of simple operation, detection speediness, high sensitivity, low cost, good selectivity, stability and reproducibility, which provides it a good application prospect.
- cyhalothrin,
- molecular imprinting polymer,
- electrochemical sensor,
- rapid analysis
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