Citation: LIU Yongjun, ZHOU Liyun, SHENG Shouri, SONG Cheng, HOU Haoqing, SONG Caisheng. Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides[J]. Chinese Journal of Applied Chemistry, ;2019, 36(6): 658-663. doi: 10.11944/j.issn.1000-0518.2019.06.180352 shu

Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: SONG Cheng, sonyia416@gmail.com
Received Date: 6 November 2018
Revised Date: 13 January 2019
Accepted Date: 14 January 2019

Fund Project: the National Natural Science Foundation of China 51663011Science and Technology Research Project of Jiangxi Provincial Department of Education GJJ170177Supported by the National Natural Science Foundation of China(No.51663011), Science and Technology Research Project of Jiangxi Provincial Department of Education(No.GJJ170177)

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A novel diketone anhydride polyimide was synthesized by introducing p-phenylenediamine(PPD) to 4, 4'-terephthaloyldiphthalic anhydride through the traditional two-step method in dimethylacetamide(DMAc). The properties of the polyimide were characterized by Fourier transform infrared spectrometer(FT-IR), wide-angle X-ray diffraction(WAXD), differential scanning calorimetric(DSC), dynamic thermomechanical analyzer(DMA), thermal gravimetric analysis(TGA), tensile test and ultraviolet-visible spectrophotometry(UV-Vis). The relationship between different thermal imidization temperature and the properties of the diketone polyimide was studied. The results showed that PAA formed the imide ring structure completely at 320℃. The polyimide had good film-forming performance and partially ordered aggregate structure. The polyimide had excellent thermal properties:the glass transition temperature(T_g) was 298℃ and the thermal decomposition temperature(T_5%) was 523℃. The film had a tensile strength of 130 MPa and tensile modulus of 5.77 GPa at 320℃. The cutoff wavelength of the film was 375 nm and the film had good transmittance in visible region.
- diketone anhydride polyimide,
- thermal properties,
- transmittance
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