Citation: YAN Bing, XIONG Wenxu, ZHENG Shibing, ZHANG Xueqian, HUANG Weiwei. Single-Walled Carbon Nanotubes Enhanced Electrochemical Performance of High-Capacity Organic Cathode Composites Calix[4]quinone/Mesporous Carbon CMK-3 for Li-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2019, 36(5): 554-563. doi: 10.11944/j.issn.1000-0518.2019.05.180231 shu

Single-Walled Carbon Nanotubes Enhanced Electrochemical Performance of High-Capacity Organic Cathode Composites Calix[4]quinone/Mesporous Carbon CMK-3 for Li-Ion Batteries

College of Environmental and Chemical Engineering, Yan Shan University, Qinhuangdao, Hebei 066004, China

Corresponding author: HUANG Weiwei, huangweiwei@ysu.edu.cn
Received Date: 2 July 2018
Revised Date: 13 September 2018
Accepted Date: 9 October 2018

Fund Project: the Natural Science Foundation of Hebei Province of China B2015203124the National Natural Science Foundation of China 21403187Supported by the National Natural Science Foundation of China(No.21403187), the Natural Science Foundation of Hebei Province of China(No.B2015203124)

Figures(5)

The dissolution of calix[4]quinone(C4Q) in electrolytes can be inhibited by the C4Q/CMK-3(mesoporous carbon) nanocomposites prepared through perfusion method, but the electrochemical performance of the nanocomposites needs to be further improved. We prepared a serious of C4Q/CMK-3/SWCNTs(single-walled carbon nanotubes) composites with different ratio by deaerating-stirring method. In these composites, SWCNTs substituted conductive carbon blacks Super-P of the original C4Q/CMK-3 composites, which also reduced the content of CMK-3. SEM and electrochemical tests are conducted to investigate the relation of the morphology and electrochemical performance that cased by SWCNTs. The results show that the optimum mass ratio was m(C4Q):m(CMK-3):m(SWCNTs)=(1:1:1), which shows a capacity retention of 55% after 100 cycles at 0.1 C. Even at 1 C, the discharge capacity is still 260 mA·h/g. The significant improvement in the electrochemical performance could be ascribed to the formation of three-dimensional conductive network by SWCNTs.
- single-walled carbon nanotubes,
- calix[4]quinone,
- C4Q/CMK-3,
- lithium-ion batteries
1. [1]
  Sripad S, Viswanathan V. Evaluation of Current, Future, and Beyond Li-Ion Batteries for the Electrification of Light Commercial Vehicles:Challenges and Opportunities[J]. J Electrochem Soc, 2017,164(11):E3635-E3646. doi: 10.1149/2.0671711jes
2. [2]
  Zhang K, Han X P, Hu Z. Nanostructured Mn-Based Oxides for Electrochemical Energy Storage and Conversion[J]. Chem Soc Rev, 2015,44(3):699-728. doi: 10.1039/C4CS00218K
3. [3]
  Larcher D, Tarascon J. Towards Greener and More Sustainable Batteries for Electrical Energy Storage[J]. Nat Chem, 2015,7(1):19-29.
4. [4]
  Al Sadat W I, Archer L A. The O₂-assisted Al/CO₂ Electrochemical Cell:A System for CO₂ Capture/Conversion and Electric Power Generation[J]. Sci Adv, 2016,2(7)e1600968. doi: 10.1126/sciadv.1600968
5. [5]
  Amine K, Kanno R, Tzeng Y. Rechargeable Lithium Batteries and Beyond:Progress, Challenges, and Future Directions[J]. MRS Bull, 2014,39(5):395-401. doi: 10.1557/mrs.2014.62
6. [6]
  Armand M, Tarascon J M. Building Better Batteries[J]. Nature, 2008,451(7179):652-657. doi: 10.1038/451652a
7. [7]
  Fergus J W. Recent Developments in Cathode Materials for Lithium Ion Batteries[J]. J Power Sources, 2010,195(4):939-954. doi: 10.1016/j.jpowsour.2009.08.089
8. [8]
  Goodenough J B, Kim Y. Challenges for Rechargeable Li-Ion Batteries[J]. Chem Mater, 2010,229(3):587-603.
9. [9]
  Zhang K, Hu Z, Tao Z L. Inorganic & Organic Materials for Rechargeable Li Batteries with Multi-electron Reaction[J]. China Mater, 2014,57(1):42-58.
10. [10]
  Shi Y, Peng L L, Ding Y. Nanostructured Conductive Polymers for Advanced Energy Storage[J]. Chem Soc Rev, 2015,44(19):6684-6696. doi: 10.1039/C5CS00362H
11. [11]
  HUANG Weiei, YAN Bing, SUN Huimin. Organic Cathode Materials for Sodiumion Batteries[J]. J Yanshan Univ, 2018,42(3):189-198. doi: 10.3969/j.issn.1007-791X.2018.03.001
12. [12]
  Yokoji T, Matsubara H, Satoh M. Rechargeable Organic Lithium-Ion Batteries Using Electron-Deficient Benzoquinones as Positive-Electrode Materials with High Discharge Voltages[J]. J Mater Chem A, 2014,2(45):19347-19354. doi: 10.1039/C4TA02812K
13. [13]
  Lv M X, Zhang F, Wu Y F. Heteroaromatic Organic Compound with Conjugated Multi-carbonyl as Cathode Material for Rechargeable Lithium Batteries[J]. Sci Rep, 2016,6(4):2045-2322.
14. [14]
  Emanuelsson R, Sterby M, Strømme M. An All-Organic Proton Battery[J]. J Am Chem Soc, 2017,139(13):4828-4834. doi: 10.1021/jacs.7b00159
15. [15]
  Luo Z Q, Liu L, Zhao Q. An Insoluble Benzoquinone-Based Organic Cathode for Use in Rechargeable Lithium-Ion Batteries[J]. J Am Chem Soc, 2017,129(41):12561-12565.
16. [16]
  Huang W W, Zhu Z Q, Wang L J. Quasi-Solid-State Rechargeable Lithium-Ion Batteries with a Calix[4] quinone Cathode and Gel Polymer Electrolyte[J]. Angew Chem Int Ed, 2013,125(35):9162-9166.
17. [17]
  Häupler B, Wild A, Schubert U S. Carbonyls:Powerful Organic Materials for Secondary Batteries[J]. Adv Energy Mater, 2015,5(11):32-41.
18. [18]
  Zheng S B, Sun H M, Yan B. High-Capacity Organic Electrode Material Calix[4] quinone/CMK-3 Nanocomposite for Lithium Batteries[J]. Sci China Mater, 2018:1-6.
19. [19]
  Zheng S B, Hu J Y, Huang W W. Inorganic-Organic Nanocomposites Calix[4] quinone (C4Q)/CMK-3 as Cathode Materials for High-Capacity Sodium Batteries[J]. Inorg Chem Front, 2017,4(11):1806-1812. doi: 10.1039/C7QI00453B
20. [20]
  Zhu Z Q, Chen J. Review-Advanced Carbon-Supported Organic Electrode Materials for Lithium(Sodium)-Ion Batteries[J]. J Electrochem Soc, 2015,162(14):A2393-A2405. doi: 10.1149/2.0031514jes
21. [21]
  Song Z P, Zhou H. Towards Sustainable and Versatile Energy Storage Devices:An Overview of Organic Electrode Materials[J]. Energ Environ Sci, 2013,6(8):2280-2301. doi: 10.1039/c3ee40709h
22. [22]
  Yabuuchi N, Kubota K, Dahbi M. Research Development on Sodium-Ion Batteries[J]. Chem Rev, 2014,114(23):11636-11682. doi: 10.1021/cr500192f
23. [23]
  Xiang X D, Zhang K, Chen J. Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries[J]. Adv Mater, 2015,27(36):5343-5348. doi: 10.1002/adma.201501527
24. [24]
  Yao Y, Wu F. Naturally Derived Nanostructured Materials from Biomass for Rechargeable Lithium/Sodium Batteries[J]. Nano Energy, 2015,17(17):91-103.
25. [25]
  Kim Y Z, Wu W, Chun S E. Biologically Derived Melanin Electrodes in Aqueous Sodium-Ion Energy Storage Devices[J]. Proc Natl Acad Sci USA, 2013,110(52):20912-20917. doi: 10.1073/pnas.1314345110
26. [26]
  Zhao Q, Huang W W, Luo Z Q. Forecasting and Monitoring Active Sites of Sustainable Quinone Electrodes for High-capacity and Safe Aqueous Zinc Batteries[J]. Sci Adv, 2018,4(3)eaao1761. doi: 10.1126/sciadv.aao1761
27. [27]
  Pan B, Zhou D, Huang J. 2, 5-Dimethoxy-1, 4-Benzoquinone(DMBQ) as Organic Cathode for Rechargeable Magnesium-Ion Batteries[J]. J Electrochem Soc, 2016,163(3):A580-A583. doi: 10.1149/2.0021605jes
28. [28]
  Ebbesen T W, Lezec H J, Hiura H. Electrical Conductivity of Individual Carbon Nanotubes[J]. Nature, 1996,382(6586):54-56. doi: 10.1038/382054a0
29. [29]
  Ishii Y, Tashiro K, Hosoe K. Electrochemical Lithium-Ion Storage Properties of Quinone Molecules Encapsulated in Single-Walled Carbon nanotubes[J]. Phys Chem Chem Phys, 2016,18(15):10411-10418. doi: 10.1039/C6CP01103A
30. [30]
  Wu H P, Wang K, Meng Y N. An Organic Cathode Material Based on a Polyimide/CNT Nanocomposite for Lithium Ion Batteries[J]. J Mater Chem A, 2013,1(21):6366-6372. doi: 10.1039/c3ta10473g
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
12. [12]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
13. [13]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
14. [14]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
15. [15]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
16. [16]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
17. [17]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
18. [18]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
19. [19]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
20. [20]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(846)
HTML views(132)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142