Citation: YE Lin, ZHANG Shaofeng, MIN Jiakang, MA Li, TANG Tao. Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide[J]. Chinese Journal of Applied Chemistry, ;2019, 36(4): 451-458. doi: 10.11944/j.issn.1000-0518.2019.04.180300 shu

Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide

YE Lin ^a,b ,
ZHANG Shaofeng ^a,b ,
MIN Jiakang ^a,b ,
MA Li ^a,, ,
TANG Tao ^a,,

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Acdemy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: MA Li, mali@ciac.ac.cn TANG Tao, ttang@ciac.ac.cn
Received Date: 10 September 2018
Revised Date: 28 September 2018
Accepted Date: 29 September 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.51233005, No.51573179, No.21304089)the National Natural Science Foundation of China 51573179the National Natural Science Foundation of China 51233005the National Natural Science Foundation of China 21304089

Figures(9)

The compatibilization of immiscible poly(n-butyl methacrylate)(PBMA)/polystyrene(PS) blends was realized by the reaction of furan and maleimide groups. The furan-functionalized poly(n-butyl methacrylate)(P(BMA-co-FMA)) and maleimide-functionalized polystyrene(MPS) was synthesized by copolymerization and post-polymerization modification, respectively. The Diels-Alder reaction of the functionalized polymers and their blend were confirmed by nuclear magnetic resonance spectroscopy(NMR). The reaction of furan and maleimide dramatically promoted the compatibility of two components, confirmed by a homogeneous microstructure evidenced by transmission electron microscopy(TEM) observation and by the presence of a single glass transition temperature in the (P(BMA-co-FMA)/MPS blends. The properties of the blend materials could be controlled conveniently by adjusting the reaction time, and the blends transformed from tough material to brittle material gradually as the reaction processed, which was confirmed by the three point bending test.
- poly(butyl methacrylate,
- polystyrene,
- polymer blend,
- compatibilization,
- diels-Alder reaction,
- furan/maleimide
1. [1]
  Lipatov Y S. Polymer Blends and Interpenetrating Polymer Networks at the Interface with Solids[J]. Prog Polym Sci, 2002,27(9):1721-1801. doi: 10.1016/S0079-6700(02)00021-7
2. [2]
  Plate N, Litmanovich A, Kudryavtsev Y V. Reactions in Polymer Blends:Experiment and Theory(A Review)[J]. Polym Sci, Ser A, 2004,46(11):1834-1874.
3. [3]
  Ao Y H, Sun S L, Tan Z Y. Compatibilization of PP/EPDM Blends by Grafting Acrylic Acid to Polypropylene and Epoxidizing the Diene in EPDM[J]. J Appl Polym Sci, 2006,102(4):3949-3954. doi: 10.1002/(ISSN)1097-4628
4. [4]
  Tang T, Huang B T. Interfacial Behaviour of Compatibilizers in Polymer Blends[J]. Polymer, 1994,35(2):81-285.
5. [5]
  Jiang M, Li M, Xiang M L, et al. Interpolymer Complexation and Miscibility Enhancement by Hydrogen Bonding[M]. Berlin:Springer-Verlag Berlin Heidelberg, 1999:121-196.
6. [6]
  Liu N C, Huang H. Types of Reactive Polymers Used in Blending[M]. Cincinati:Hanser Gardner Publications, Inc, 2001:13-42.
7. [7]
  Park T, Zimmerman S C. Interplay of Fidelity, Binding Strength, and Structure in Supramolecular Polymers[J]. J Am Chem Soc, 2006,128(44):14236-14237. doi: 10.1021/ja065469u
8. [8]
  Dionisio M, Ricci L, Pecchini G. Polymer Blending through Host-Guest Interactions[J]. Macromolecules, 2014,47(2):632-638. doi: 10.1021/ma401506t
9. [9]
  Shen J, Piunova V A, Nutt S. Blends of Polystyrene and Poly(n-butyl methacrylate) Mediated by Perfluorocarbon End Groups[J]. Polymer, 2013,54(21):5790-5800. doi: 10.1016/j.polymer.2013.08.059
10. [10]
  Tawney P O, Snyder R H, Bryan C E. The Chemistry of Maleimide and Its Derivatives.I.N-Carbamylmaleimide[J]. J Org Chem, 1960,25(1):56-60.
11. [11]
  Tawney P O, Snyder R H, Conger R P. The Chemistry of Maleimide and Its Derivatives.Ⅱ.Maleimide and N-Methylolmaleimide[J]. J Org Chem, 1961,26(1):15-21.
12. [12]
  Stevens M P, Jenkins A D. Crosslinking of Polystyrene via Pendant Maleimide Groups[J]. J Polym Sci, Polym Chem Ed, 1979,17(11):3675-3685. doi: 10.1002/pol.1979.170171123
13. [13]
  Gandini A. The Furan/Maleimide Diels-Alder Reaction:A Versatile Click Unclick Tool in Macromolecular Synthesis[J]. Prog Polym Sci, 2013,38(1):1-29. doi: 10.1016/j.progpolymsci.2012.04.002
1. [1]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
2. [2]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
3. [3]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
4. [4]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
5. [5]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
6. [6]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
7. [7]
  Wenbing Hu , Jin Zhu . Flipped Classroom Approach in Teaching Professional English Reading and Writing to Polymer Graduates. University Chemistry, 2024, 39(6): 128-131. doi: 10.3866/PKU.DXHX202310015
8. [8]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
9. [9]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
10. [10]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
11. [11]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
12. [12]
  Yu-Hang Miao , Zheng-Xu Zhang , Xu-Yi Huang , Yuan-Zhao Hua , Shi-Kun Jia , Xiao Xiao , Min-Can Wang , Li-Ping Xu , Guang-Jian Mei . Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles. Chinese Chemical Letters, 2024, 35(4): 108830-. doi: 10.1016/j.cclet.2023.108830
13. [13]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
14. [14]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
15. [15]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
16. [16]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
17. [17]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
18. [18]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
19. [19]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
20. [20]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015

Get Citation

PDF

XML

Metrics

PDF Downloads(29)
Abstract views(2426)
HTML views(727)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142