Citation: XIE Yaqiao, ZHAO Jiaxin, LI Jielan, XU Zidi, QU Jiangying, TIAN Yunqi, GAO Feng. Synthesis of Sodium Chloride Induced Lignin-Based Porous Carbon and Their Supercapacitor Performances[J]. Chinese Journal of Applied Chemistry, ;2019, 36(4): 482-488. doi: 10.11944/j.issn.1000-0518.2019.04.180294 shu

Synthesis of Sodium Chloride Induced Lignin-Based Porous Carbon and Their Supercapacitor Performances

XIE Yaqiao ^a ,
ZHAO Jiaxin ^a ,
LI Jielan ^a ,
XU Zidi ^a ,
QU Jiangying ^a,b ,
TIAN Yunqi ^a ,
GAO Feng ^a,b,,

a.
Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China
b.
School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, China

Corresponding author: GAO Feng, fenggao2003@163.com
Received Date: 6 July 2018
Revised Date: 22 October 2018
Accepted Date: 29 November 2018

Fund Project: the National Natural Science Foundation of China U1610114Supported by the National Natural Science Foundation of China(No.U1610114), Natural Science Fund of Liaoning Province(No.201602458), Doctoral Scientific Research Foundation of Liaoning Province(No.201601240)Natural Science Fund of Liaoning Province 201602458Doctoral Scientific Research Foundation of Liaoning Province 201601240

Figures(4)

A novel class of lignin-based porous carbon(PC) for supercapacitor electrode was successfully fabricated using lignin as the carbon precursor and NaCl as the template by reflux at low temperature and calcination at high temperature. The results indicate that the porous structures of the obtained samples can be regulated by varying the calcination temperature, where the surface area and pore volume of samples firstly increases then decreases with the increase of the temperature. As a result, the specific surface area of the obtained sample can be tailored in the range of 548~600 m²/g. PC calcinated at 700℃ has the largest surface area and exhibits the highest specific capacitance of 252 F/g and an effective areal capacitance of 31.2 μF/cm² in 6 mol/L KOH solution. NaCl template can be cycled by washing from the products. This paper proposes a green method for synthesis of high value-added porous carbon from waste materials.
- porous carbon,
- lignin,
- salt template,
- supercapacitor
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