Citation: CHEN Shaopeng, TAN Yuhui, YANG Kang, LI Chao, ZHOU Haitiao, YANG Shaoping, LUO Ziyu, TANG Yunzhi. In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole[J]. Chinese Journal of Applied Chemistry, ;2019, 36(2): 223-229. doi: 10.11944/j.issn.1000-0518.2019.02.180190 shu

In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole

CHEN Shaopeng ^a ,
TAN Yuhui ^a,, ,
YANG Kang ^a ,
LI Chao ^a ,
ZHOU Haitiao ^a ,
YANG Shaoping ^b,, ,
LUO Ziyu ^a ,
TANG Yunzhi ^a

a.
School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
b.
School of Mechanical & Material Engineering, Wuzhou University, Wuzhou, Guangxi 543002, China

Corresponding author: TAN Yuhui, tyxcn@163.com YANG Shaoping, ysp1120@163.com
Received Date: 24 May 2018
Revised Date: 20 June 2018
Accepted Date: 14 August 2018

Fund Project: the National Natural Science Foundation of China 21471070Supported by the National Natural Science Foundation of China(No.21471070, No.21761013, No.21671086, No.21461010), the Program of Jiangxi Provincial Science and Technology Department(No.20153BCB22006)the National Natural Science Foundation of China 21461010the National Natural Science Foundation of China 21671086the Program of Jiangxi Provincial Science and Technology Department 20153BCB22006the National Natural Science Foundation of China 21761013

Figures(6)

Hydrothermal reaction of 5, 5'-dicyano-3, 3'-bipyridyl ligands and sodium azide in the presence of the Lewis acid CuSO₄ in water and ethanol provided a novel metal organic tetrazole complex. X-ray single crystal diffraction analysis shows that this complex belongs to a tetragonal system with P4/ncc space group. This complex displays an interesting infinite two-dimensional(2D) network structure bridge linked by the pyridyl N atoms. The highly disordered sulfate around the central metals are likely to become ordered at low temperatures, leading to structural phase changes. The packing diagram of the crystal structure shows a butterfly hairpin shape. The highly nitrogenated structure allows this complex to be a potential high-energy material.
- tetrazole complex,
- pyridyl,
- two-dimensional network structure
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