Citation: GAO Shan, SUN Haijun, DU Mengmeng, GUO Fen, YE Xiaoli, QIAO Lei. Capacitive Performance Comparison of Carbon Fiber Cloth Supported Three-Dimensional Polyaniline Networks in RCl(R=H, Li, Na, K) Aqueous Solution[J]. Chinese Journal of Applied Chemistry, ;2019, 36(2): 236-244. doi: 10.11944/j.issn.1000-0518.2019.02.180144 shu

Capacitive Performance Comparison of Carbon Fiber Cloth Supported Three-Dimensional Polyaniline Networks in RCl(R=H, Li, Na, K) Aqueous Solution

GAO Shan ^a ,
SUN Haijun ^a ,
DU Mengmeng ^a,, ,
GUO Fen ^b ,
YE Xiaoli ^a ,
QIAO Lei ^a

a.
Wuhan Second Ship Design and Research Institute, Wuhan, 430064, China
b.
Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China

Corresponding author: DU Mengmeng, duchangmeng0704@126.com
Received Date: 2 May 2018
Revised Date: 30 May 2018
Accepted Date: 19 July 2018

Fund Project: Youth Science and Technology Backbone Training Program of Wuhan University of Science and Technology 2017xz011the Natural Science Foundation of Hubei Province 2018CFB214Supported by the Natural Science Foundation of Hubei Province(No.2018CFB214), Youth Science and Technology Backbone Training Program of Wuhan University of Science and Technology(No.2017xz011)

Figures(6)

Carbon fiber cloth supported three-dimensional polyaniline networks were synthesized by electrochemical polymerization. Scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer were applied to characterize the morphology of the electrode and analyze the characteristic groups on the electrode surface. The capacitive performance of the as-prepared electrode in four RCl(R=H, Li, Na, K) aqueous solutions was systematically compared. The electrochemical tests show that KCl electrolyte gives a wider potential window(1.8 V) than the HCl or LiCl electrolyte, and also exhibits a superior specific capacitance(501 F/g@0.5 A/g) to the NaCl electrolyte. The energy density under the current density of 10 A/g in the KCl electrolyte is even larger than that in the HCl electrolyte under 2.0 A/g. As a result, KCl is the most suitable electrolyte for the polyaniline-based capacitor. The potential window is widened and the energy density of electrochemical capacitor is remarkably improved just simply by altering the electrolyte in the aqueous solution, which avoids the issues of poor physico-chemical stability and severe environment contamination originated from the organic solutions.
- potential window,
- energy density,
- capacitor,
- polyaniline,
- alkaline metal salt
1. [1]
  Caldona E B, Al Christopher C, Pajarito B B. Novel Anti-Corrosion Coatings from Rubber-Modified Polybenzoxazine-Based Polyaniline Composites[J]. Appl Surf Sci, 2017,422:162-171. doi: 10.1016/j.apsusc.2017.05.083
2. [2]
  Hong J, Han X, Shi H. Preparation of Conductive Silk Fibroin Yarns Coated with Polyaniline Using an Improved Method Based on in situ Polymerization[J]. Synth Met, 2018,235:89-96. doi: 10.1016/j.synthmet.2017.12.002
3. [3]
  Eising M, Cava C E, Salvatierra R V. Doping Effect on Self-Assembled Films of Polyaniline and Carbon Nanotube Applied as Ammonia Gas Sensor[J]. Sens Actuators B:Chem, 2017,245:25-33. doi: 10.1016/j.snb.2017.01.132
4. [4]
  Dimitriev O P. Doping of Polyaniline by Transition-Metal Salts[J]. Macromolecules, 2004,37(9):3388-3395. doi: 10.1021/ma035677w
5. [5]
  Ryu K S, Kim K M, Kang S G. Electrochemical and Physical Characterization of Lithium Ionic Salt Doped Polyaniline as a Polymer Electrode of Lithium Secondary Battery[J]. Synth Met, 2000,110(3):213-217.
6. [6]
  ZHANG Aiqin, WANG Lizhen, ZHANG Yong. Electrochemical Properties of Activated Carbon-Polyaniline Hybrid Capacitor[J]. Chinese Battery Ind, 2010,15(1):18-21. doi: 10.3969/j.issn.1008-7923.2010.01.005
7. [7]
  Gupta V, Miura N. Large-Area Network of Polyaniline Nanowires Prepared by Potentiostatic Deposition Process[J]. Electrochem Commun, 2005,7(10):995-999. doi: 10.1016/j.elecom.2005.07.008
8. [8]
  MA Li, FENG Lijun, GAN Mengyu. Synthesis and Properties of Conducting Polyaniline Doped with Multiple Sulfonic Acid[J]. Chinese J Appl Chem, 2008,25(2):142-146. doi: 10.3969/j.issn.1000-0518.2008.02.004
9. [9]
  Guo F, Ye K, Huang X. Palladium Dispersed in Three-Dimensional Polyaniline Networks as the Catalyst for Hydrogen Peroxide Electro-Reduction in an Acidic Medium[J]. RSC Adv, 2015,5(114):94008-94015. doi: 10.1039/C5RA19478D
10. [10]
  XU Hui, XU Yao, CHEN Yong. The Adsorption of Trace Cr(Ⅵ) in Aqueous Solution by Polyaniline/Attapulgite Nanofiber Composite[J]. Chinese J Appl Chem, 2011,28(5):549-554. doi: 10.3969/j.issn.1001-4160.2011.05.009
11. [11]
  Gao Z, Yang W, Wang J. Electrochemical Synthesis of Layer-by-Layer Reduced Graphene Oxide Sheets/Polyaniline Nanofibers Composite and Its Electrochemical Performance[J]. Electrochim Acta, 2013,91:185-194. doi: 10.1016/j.electacta.2012.12.119
12. [12]
  WANG Hongzhi, GAO Cuixia, ZHANG Peng. Synthesis and Electrochemical Performance of Graphene/Polyaniline[J]. Acta Phys-Chim Sin, 2013,29(1):117-122. doi: 10.3866/PKU.WHXB201210234
13. [13]
  Guo F, Li Y, Cao D. A Double-Chamber Energy Storage Device with Dual Ionic Electrolyte Enabling High Energy Density[J]. Electrochim Acta, 2018,274:31-39. doi: 10.1016/j.electacta.2018.04.085
14. [14]
  Saprigin A, Brenneman K, Lee W. Li⁺ Doping-Induced Localization in Polyaniline[J]. J Synth Met, 1999,100(1):55-59.
15. [15]
  LU Xiangjun, DOU Hui, YANG Sudong. Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys-Chim Sin, 2011,27(10):2333-2339. doi: 10.3866/PKU.WHXB20111022
16. [16]
  Mi H, Zhang X, Ye X. Preparation and Enhanced Capacitance of Core-Shell Polypyrrole/Polyaniline Composite Electrode for Supercapacitors[J]. J Power Sources, 2008,176(1):403-409.
17. [17]
  Prunǎ A, Branzoi V, Branzoi F. Ordered Arrays of Copper Nanowires Enveloped in Polyaniline Nanotubes[J]. J Appl Electrochem, 2011,41(1):77-81.
18. [18]
  Hong X, Zhang B, Murphy E. Three-Dimensional Reduced Graphene Oxide/Polyaniline Nanocomposite Film Prepared by Diffusion Driven Layer-by-Layer Assembly for High-Performance Supercapacitors[J]. J Power Sources, 2017,343:60-66. doi: 10.1016/j.jpowsour.2017.01.034
19. [19]
  ZHANG Yue, WANG Guangjin, PAN Mu. Fast Electropolymerization of Polyaniline Nanofibers on Carbon Paper[J]. Chem J Chinese Univ, 2014,35(10):2234-2238. doi: 10.7503/cjcu20140524
20. [20]
  REN Lijun, ZHANG Gaini, LEI Ji. Prepartion of Polyaniline Nanowire Electrode Material with High Rate Performance for Supercapacitor[J]. New Chem Mater, 2017,45(1):56-58.
21. [21]
  SHANG Xiuli, SUO Longning, FENG Wencheng. Preparation of Polyaniline/Polysulfone Composite Material and Their Super-capacitive Performance[J]. Chinese J Appl Chem, 2013,30(9):1060-1064.
22. [22]
  Zhang X, Ji L, Zhang S. Synthesis of a Novel Polyaniline-Intercalated Layered Manganese Oxide Nanocomposite as Electrode Material for Electrochemical Capacitor[J]. J Power Sources, 2007,173(2):1017-1023. doi: 10.1016/j.jpowsour.2007.08.083
23. [23]
  Fan W, Zhang C, Tjiu W. Graphene-Wrapped Polyaniline Hollow Spheres as Novel Hybrid Electrode Materials for Supercapacitor Applications[J]. ACS Appl Mater Interfaces, 2017,5(8):3382-3391.
24. [24]
  Bandyopadhyay P, Kuila T, Balamurugan J. Facile Synthesis of Novel Sulfonated Polyaniline Functionalized Graphene Using m-Aminobenzene Sulfonic Acid for Asymmetric Supercapacitor Application[J]. Chem Eng J, 2017,308:1174-1184. doi: 10.1016/j.cej.2016.10.015
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