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Citation: CHEN Hongyun, YANG Fanghong, LI Yupeng, HE Jiayu, CHE Mengqin, WANG Meichen, CHENG Chuanjie. Synthesis and Application of Water-Soluble Fe3O4 Magnetic Nano-catalyst[J]. Chinese Journal of Applied Chemistry, ;2019, 36(2): 188-194. doi: 10.11944/j.issn.1000-0518.2019.02.180089 shu

Synthesis and Application of Water-Soluble Fe3O4 Magnetic Nano-catalyst

  • a.

    School of Chemistry and Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 330013, China

  • b.

    School of Information Engineering, Nanchang University, Nanchang 330031, China

  • Corresponding author: CHENG Chuanjie, chengcj530@163.com
  • Received Date: 29 March 2018
    Revised Date: 7 June 2018
    Accepted Date: 4 July 2018

    Fund Project: the National Natural Science Foundation of China 21264008Supported by the National Natural Science Foundation of China(No.21564004, No.21264008)the National Natural Science Foundation of China 21564004

Figures(5)

  • Fe3O4 magnetic nano particles(MNPs) with sulfonic acid groups on the surface were readily prepared via coupling reaction between 4-amino phenylsulfonic acid diazonium tetrafluoroborate and Fe3O4 nano particles. Transmission electron microscopy(TEM) images reveal that the average size of these acidic particles is about 20 nm. These acidic particles show good solubility in water, but they are insoluble in most of common organic solvents, allowing easy isolation and recycling of the particles by their magnetic property in catalytic reactions. In terms of application, when the acidic magnetic particles were used to catalyze esterification reactions between carboxylic acids and alcohols, moderate to high isolated yields(71%~86%) of ester products were obtained. The optimized catalyst loading is 1.5%(mass fraction). Furthermore, 5-hydroxymethyl furfural(HMF) was also synthesized in a 32% yield from fructose utilizing the acidic magnetic particles as a catalyst.
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  • 1. 

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