Citation: QU Haonan, BAO Chong, MA Wenjing, MA Yiming, ZHAO Peng, WANG Xinhai, ZHOU Yanmei. Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 58-64. doi: 10.11944/j.issn.1000-0518.2019.01.180049 shu

Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

He'nan Joint International Research Laboratory of Environmental Pollution Control Materials, College of Chemistry and Chemical Engineering, He'nan University, Kaifeng, He'nan 475004, China

Corresponding author: WANG Xinhai, xinhaiwang@126.com ZHOU Yanmei, zhouyanmei@henu.edu.cn
Received Date: 19 February 2018
Revised Date: 16 April 2018
Accepted Date: 7 June 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.21576071, No.21776061)the National Natural Science Foundation of China 21776061the National Natural Science Foundation of China 21576071

Figures(5)

Cellulose is a renewable resource. Compounds obtained by the hydrolysis of cellulose are of great significance to ease the energy pressure. Herein, the hydrolysis of cellulose catalyzed by solid carbon sulfonic acid supported 1-butyl-3-methylimidazolium chloride is reported. The solid carbon sulfonic acid obtained from bamboo biomass by pre-carbonization at 700℃ and sulfonation at 150℃ was used as the matrix. Ionic liquid functionalized solid carbon sulfonic acid catalyst was obtained by loading 1-butyl-3-methylimidazolium chloride. The results show that the total reducing sugar yield under optimal conditions is increased by 15.2% relative to the total reducing sugar yield by exploiting solid carbon sulfonic acid. The catalyst still exhibits good performance after recycling.
- solid carbon sulfonic acid,
- ionic liquids,
- hydrolysis of cellulose
1. [1]
  Liu Y, West A R. Semiconductor-Insulator Transition in Undoped Rutile, TiO₂, Ceramics[J]. J Am Ceram Soc, 2013,96(1):218-222. doi: 10.1111/jace.12025
2. [2]
  Ogaki Y, Yu S, Hara T. Hemicellulose Decomposition and Saccharides Production from Various Plant Biomass by Sulfonated Allophane Catalyst[J]. Catal Today, 2011,164(1):415-418. doi: 10.1016/j.cattod.2010.11.002
3. [3]
  Xu A, Wang J, Wang H. Effects of Anionic Structure and Lithium Salts Addition on the Dissolution of Cellulose in 1-Butyl-3-methylimidazolium-based Ionic Liquid Solvent Systems[J]. Green Chem, 2010,12(2):268-275. doi: 10.1039/B916882F
4. [4]
  Alonso D M, Gallo J M R, Mellmer M A. Direct Conversion of Cellulose to Levulinic Acid and Gamma-Valerolactone Using Solid Acid Catalysts[J]. Catal Sci Technol, 2013,3(4):927-931. doi: 10.1039/C2CY20689G
5. [5]
  Goswami M, Meena S, Navatha S. Hydrolysis of Biomass Using a Reusable Solid Carbon Acid Catalyst and Fermentation of the Catalytic Hydrolysate to Ethanol[J]. Bioresour Technol, 2015,188:99-102. doi: 10.1016/j.biortech.2015.03.012
6. [6]
  OUYANG Siyu, XU Qiong, FU Zaihui. New Progress in Acid Catalysis of Biomass Conversion to 5-Hydroxymethylfurfural[J]. Chem Ind Eng Prog, 2014,33(5):1077-1085.
7. [7]
  Li C Z, Qian W, Zhao Z K. Acid in Ionic Liquid:An Efficient System for Hydrolysis of Lignocellulose[J]. Green Chem, 2008,10(2):177-182. doi: 10.1039/B711512A
8. [8]
  LUO Yingling, XU Zhiquan, YI Weilin. Ionic Liquid Pretreatment of Biomass Improves Saccharification Yield[J]. Chinese J Appl Chem, 2014,31(1):54-60.
9. [9]
  LIU Zhen, DAI Hui, WANG Jianji. Ionic Liquid Pretreatment of Enzymatic Hydrolysis of Cellulose[J]. Chinese J Appl Chem, 2009,26(9):1111-1113.
10. [10]
  Zhuo K, Du Q, Bai G. Hydrolysis of Cellulose Catalyzed by Novel Acidic Ionic Liquids[J]. Carbohydr Polym, 2015,115:49-53. doi: 10.1016/j.carbpol.2014.08.078
11. [11]
  Liu X, Xu Q, Liu J. Hydrolysis of Cellulose into Reducing Sugars in Ionic Liquids[J]. Fuel, 2016,164:46-50. doi: 10.1016/j.fuel.2015.09.086
12. [12]
  YUE Caibo, WEI Yuyang, LV Minjie. Synthesis of Acetates in Novel Acidic Ionic Liquids[Hmim]HSO₄[J]. Chinese J Appl Chem, 2006,23(11):1282-1285. doi: 10.3969/j.issn.1000-0518.2006.11.021
13. [13]
  WANG Fuyu, LIU Yanli, WANG Chong. Dehydration of Fructose in Acidic Ionic Liquid to Produce 5-Hydroxymethylfurfural[J]. Chinese J Appl Chem, 2014,31(4):424-430.
14. [14]
  Hara M, Yoshida T, Takagaki A. A Carbon Material as a Strong Protonic Acid[J]. Angew Chem Int Ed, 2004,43(22):2955-2958. doi: 10.1002/(ISSN)1521-3773
15. [15]
  Ba Y Y, Xiao L P, Sun R C. Microwave-Assisted Conversion of Biomass Derived Hemicelluloses into Xylo-Oligosaccharides by Novel Sulfonated Bamboo-Based Catalysts[J]. Biomass Bioenergy, 2015,75:245-253. doi: 10.1016/j.biombioe.2015.02.023
16. [16]
  Yan L, Liu N, Wang Y. Production of 5-Hydroxymethylfurfural from Corn Stalk Catalyzed by Corn Stalk-Derived Carbonaceous Solid Acid Catalyst[J]. Bioresour Technol, 2014,173:462-466. doi: 10.1016/j.biortech.2014.09.148
17. [17]
  Sun Z, Tao M, Zhao Q. A Highly Active Willow-Derived Sulfonated Carbon Material with Macroporous Structure for Production of Glucose[J]. Cellulose, 2015,22(1):675-682. doi: 10.1007/s10570-014-0540-8
18. [18]
  Hu L, Li Z, Wu Z. Catalytic Hydrolysis of Microcrystalline and Rice Straw-Derived Cellulose over a Chlorine-Doped Magnetic Carbonaceous Solid Acid[J]. Ind Crops Prod, 2016,84:408-417. doi: 10.1016/j.indcrop.2016.02.039
19. [19]
  MA Hao, LIAO Chunyan, FAN Meilin. Solubility of Cellulose Anion-Functionalized Ionic Liquids on Cellulose[J]. Chinese J Appl Chem, 2018,35(4):449-456.
20. [20]
  Zhang C, Fu Z H, Liu Y C. Ionic Liquid-Functionalized Biochar Sulfonic Acid as a Biomimetic Catalyst for Hydrolysis of Cellulose and Bamboo under Microwave Irradiation[J]. Green Chem, 2012,14(7):1928-1934. doi: 10.1039/c2gc35071h
21. [21]
  Fu Z, Wan H, Hu X. Preparation and Catalytic Performance of a Carbon-Based Solid Acid Catalyst with High Specific Surface Area[J]. React Kinet Mech Catal, 2012,107(1):203-213. doi: 10.1007/s11144-012-0466-9
22. [22]
  Li C Z, Zhao Z K. Efficient Acid-Catalyzed Hydrolysis of Cellulose in Ionic Liquid[J]. Adv Synth Catal, 2007,349(11/12):1847-1850.
23. [23]
  CAI Xinxing, WANG Zhusheng, LI Ying. Preparation of Biomass Carbon Sulfonic Acid and Its Catalytic Hydrolysis of Cellulose[J]. CIESC J, 2015,66(8):3106-3112.
1. [1]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
2. [2]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
3. [3]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
4. [4]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
5. [5]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
6. [6]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
7. [7]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103
8. [8]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
9. [9]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
10. [10]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
11. [11]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
12. [12]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
13. [13]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
14. [14]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
15. [15]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
16. [16]
  Yixuan Zhu , Qingtong Wang , Jin Li , Lin Chen , Junlong Zhao . Blog of Oxytocin. University Chemistry, 2024, 39(9): 134-140. doi: 10.12461/PKU.DXHX202310090
17. [17]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
18. [18]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(855)
HTML views(114)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142