Citation: ZHANG Huizhu, HOU Yurong, WANG Xinyuan, LIU Guiyan. Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts[J]. Chinese Journal of Applied Chemistry, ;2018, 35(12): 1457-1461. doi: 10.11944/j.issn.1000-0518.2018.12.180015 shu

Synthesis and Catalytic Performance of Zinc Porphyrin Modified Binuclear Carbene Olefin Metathesis Catalysts

a.
College of Pharmacy, Jiamusi University, Jiamusi, Heilongjiang 154007, China
b.
College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: LIU Guiyan, guiyanliu2013@163.com
Received Date: 18 January 2018
Revised Date: 11 April 2018
Accepted Date: 28 April 2018

Fund Project: Supported by the General Program of Jiamusi University(No.JMSUJCMS2016-018)the General Program of Jiamusi University JMSUJCMS2016-018

Figures(2)

A zinc-containing porphyrin-modified Grubbs-Hoveyda type binuclear ruthenium carbene olefin metathesis catalyst was synthesized. The structure of the product was confirmed by nuclear magnetic resonance(NMR). The yield of the ring-closing metathesis(RCM) reaction of several representative substrates could reach 95% by using 0.1% steriochemic catalyst. For a specific cross-olefin metathesis reaction(CM), a higher yield(93%) could be obtained with extended reaction time. This study provides a new method and a theoretical basis for the modification of Grubbs-Hoveyda catalyst.
- binuclear,
- olefin metathesis,
- ruthenium carbene,
- zinc porphyrin
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沈阳化工大学材料科学与工程学院沈阳 110142