Citation: LIN Hongyan, TIAN Yuan, WANG Qinglin, ZENG Ling, LIU Guocheng, ZHAO Yanyu. Synthesis and Fluorescence Properties of a Zinc Complex Based on the One-Dimensional Double-Helical Chains[J]. Chinese Journal of Applied Chemistry, ;2018, 35(11): 1372-1377. doi: 10.11944/j.issn.1000-0518.2018.11.170464 shu

Synthesis and Fluorescence Properties of a Zinc Complex Based on the One-Dimensional Double-Helical Chains

College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: LIN Hongyan, linhongyan_2015@126.com
Received Date: 25 December 2017
Revised Date: 29 January 2018
Accepted Date: 9 March 2018

Fund Project: the National Natural Science Foundation of China 21501013the National Natural Science Foundation of China 21401010Supported by the National Natural Science Foundation of China(No.21501013, No.21401010)

Figures(4)

A zinc complex based on the one-dimensional (1D) double-helical chains was hydrothermally self-assembled by selecting the organic ligand N, N'-bis (3-pyridyl)malonamide (3-bpma), 1, 4-phenylenediacetic acid (H₂ pda) and zinc nitrate, [Zn (3-bpma) (pda)]_n (1), then structurally characterized by infrared spectroscopy (IR), element analysis, thermogravimetry (TG) and X-ray single-crystal diffraction. The single-crystal structural analysis reveals that this zinc complex is an orthorhombic system with space group Pna21, its cell parameters are:a=1.62512 (11) nm, b=1.15947 (8) nm, c=1.19282 (8) nm, α=90°, β=90°, γ=90°, V=2.2476 (3) nm³, M_r=513.80, D_c=1.518 g/cm³, Z=4, F (000)=1056, R₁=0.0381, wR₂=0.0669. The zinc ions are bridged by two kinds of ligands 3-bpma and pda to form a 1D double-helical chain, then the adjacent chains are extended into the 3D supramolecular network through the hydrogen bonding interactions. The title zinc complex shows a strong fluorescence emission characteristic. Moreover, this complex possesses remarkable fluorescent sensing behaviors for organic solvent molecules and metal ions, which may be a potential fluorescent sensing material for detecting nitrobenzene.
- hydrothermal synthesis,
- zinc complex,
- helical structure,
- fluorescent property,
- fluorescent sensing
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