Citation: LI Fei, XIA Zhiguo. Rare Earth Doped Phosphors and Inorganic Quantum Dots for Solid State Lighting: Opportunity and Challenge[J]. Chinese Journal of Applied Chemistry, ;2018, 35(8): 859-870. doi: 10.11944/j.issn.1000-0518.2018.08.180152 shu

Rare Earth Doped Phosphors and Inorganic Quantum Dots for Solid State Lighting: Opportunity and Challenge

LI Fei ,
XIA Zhiguo ^,

The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: XIA Zhiguo, xiazg@ustb.edu.cn
Received Date: 4 May 2018
Revised Date: 26 June 2018
Accepted Date: 26 June 2018

Fund Project: the National Natural Science Foundation of China 51722202Supported by the National Natural Science Foundation of China(No.51722202)

Figures(6)

White light-emitting diode(w-LED) has the advantages of long service life, environmental protection, energy saving and high safety, which has basically replaced traditional incandescent and fluorescent lamp after development of more than ten years and is considered to be the new generation lighting source. As the core material of w-LED, fluorescence conversion material directly affects the performance of the device. Therefore, the development of high-performance fluorescent conversion materials is of great importance to further enhance the performance of w-LED devices. This review mainly describes the rare-earth phosphors and inorganic quantum dots which used in solid-state lighting device. We summarize the progress of the structural design, composition and photoluminescent tuning of rare-earth phosphors and typically introduce the design and photoluminescence tuning of chalcogenide quantum dots represented by ZnS, perovskite quantum dots and carbon dots used in w-LED. Finally, the future development including the opportunity and challenge of the fluorescent conversion materials for solid state lighting is prospected.
- white light-emitting diode,
- rare earth doped phosphors,
- quantum dots,
- photoluminescence tuning
1. [1]
  Nakamura S, Mukai T, Senoh M. High-Brightness InGaN/AlGaN Double-Heterostructure Blue-Green-Light-Emitting Diodes[J]. J Appl Phys, 1994,76(12):8189-8191. doi: 10.1063/1.357872
2. [2]
  Li G, Tian Y, Zhao Y. Recent Progress in Luminescence Tuning of Ce³⁺ and Eu²⁺-Activated Phosphors for pc-WLEDs[J]. Chem Soc Rev, 2015,44(23):8688-8713. doi: 10.1039/C4CS00446A
3. [3]
  Xia Z, Xu Z, Chen M. Recent Developments in the New Inorganic Solid-state LED Phosphors[J]. Dalton Trans, 2016,45(28):11214-11232. doi: 10.1039/C6DT01230B
4. [4]
  Dorenbos P. A Review on How Lanthanide Impurity Levels Change with Chemistry and Structure of Inorganic Compounds[J]. ECS J Solid State SC, 2013,2(2):R3001-R3011. doi: 10.1149/2.001302jss
5. [5]
  Xia Z, Liu Q. Progress in Discovery and Structural Design of Color Conversion Phosphors for LEDs[J]. Prog Mater Sci, 2016,84:59-117. doi: 10.1016/j.pmatsci.2016.09.007
6. [6]
  George N C, Denault K A, Seshadri R. Phosphors for Solid-State White Lighting[J]. Ann Rev Mater Res, 2013,43(1):481-501. doi: 10.1146/annurev-matsci-073012-125702
7. [7]
  Narendran N, Gu Y. Life of LED-Based White Light Sources[J]. J Disp Technol, 2005,1(1):167-171. doi: 10.1109/JDT.2005.852510
8. [8]
  Pimputkar S, Speck J S, DenBaars S P. Prospects for LED Lighting[J]. Nat Photonics, 2009,3(4):180-182. doi: 10.1038/nphoton.2009.32
9. [9]
  Rohwer L S, Srivastava A M. Development of Phosphors for LEDs[J]. Electrochem Soc Interface, 2003,12(2):36-39.
10. [10]
  Kim Y H, Viswanath N S M, Unithrattil S. Review-Phosphor Plates for High-Power LED Applications:Challenges and Opportunities Toward Perfect Lighting[J]. ECS J Solid State SC, 2017,7(1):R3134-R3147.
11. [11]
  Katelnikovas A, Plewa J, Dutczak D. Synthesis and Optical Properties of Green Emitting Garnet Phosphors for Phosphor-Converted Light Emitting Diodes[J]. Opt Mater, 2012,34(7):1195-1201. doi: 10.1016/j.optmat.2012.01.034
12. [12]
  Akai T, Shigeiwa M, Okamoto K, et al XAFS Analysis of Local Structure Around Ce in Ca₃Sc₂Si₃O₁₂: Ce Phosphor for White LEDs[C]//AIP Conference Proceedings, AIP: 2007: 389-391.
13. [13]
  Elliott J. Recent Progress in the Chemistry, Crystal Chemistry and Structure of the Apatites[J]. Calcif Tissue Int, 1969,3(1):293-307. doi: 10.1007/BF02058672
14. [14]
  White T J, Dong Z. Structural Derivation and Crystal Chemistry of Apatites[J]. Acta Crystallogr B, 2003,59(1):1-16. doi: 10.1107/S0108768102019894
15. [15]
  Kusaka K, Hagiya K, Ohmasa M. Determination of Structures of Ca₂CoSi₂O₇, Ca₂MgSi₂O₇, and Ca₂(Mg_0.55Fe_0.45)Si₂O₇ in Incommensurate and Normal Phases and Observation of Diffuse Streaks at High Temperature[J]. Phys Chem Miner, 2001,28(3):150-166. doi: 10.1007/s002690000147
16. [16]
  Zhang M, Wang J, Ding W. Luminescence Properties of M₂MgSi₂O₇:Eu²⁺(M=Ca, Sr) Phosphors and Their Effects on Yellow and Blue LEDs for Solid-State Lighting[J]. Opt Mater, 2007,30(4):571-578. doi: 10.1016/j.optmat.2007.01.008
17. [17]
  Zhang Q, Wang J, Zhang M. Tunable Bluish Green to Yellowish Green Ca_2(1-x)Sr_2xAl₂SiO₇:Eu²⁺ Phosphors for Potential LED Application[J]. Appl Phys B, 2008,92(2):195-198. doi: 10.1007/s00340-008-3089-0
18. [18]
  Singh S, Khatkar S, Boora P. Structural and Luminescent Properties of Eu³⁺-Doped GdSrAl₃O₇ Nanophosphor[J]. J Mater Sci, 2014,49(14):4773-4779. doi: 10.1007/s10853-014-8176-5
19. [19]
  Zhang X, Zhang J, Xu J. Luminescent Properties of Eu²⁺-Activated SrLaGa₃S₆O Phosphor[J]. J Alloy Compd, 2005,389(1):247-251.
20. [20]
  Aleksovska S, Petruševski V M, Pejov L. Crystal Structures of Members in Isostructural Series:Prediction of the Crystal Structure of Cs₂MnO₄-K₂SO₄ Type Isomorph[J]. Croat Chem Acta, 1997,70(4):1009-1019.
21. [21]
  Müller-Buschbaum H. The Crystal Chemistry of AM₂O₄ Oxometallates[J]. J Alloy Compd, 2003,349(1):49-104.
22. [22]
  Denault K A, Brgoch J, Gaultois M W. Consequences of Optimal Bond Valence on Structural Rigidity and Improved Luminescence Properties in Sr_xBa_2xSiO₄:Eu²⁺ Orthosilicate Phosphors[J]. Chem Mater, 2014,26(7):2275-2282. doi: 10.1021/cm500116u
23. [23]
  Marchuk A, Schultz P, Hoch C. M₂PO₃N(M=Ca, Sr):Ortho-Oxonitridophosphates with β-K₂SO₄ Structure Type[J]. Inorg Chem, 2015,55(2):974-982.
24. [24]
  Black A P, Denault K A, Oró-Solé J. Red Luminescence and Ferromagnetism in Europium Oxynitridosilicates with a β-K₂SO₄ Structure[J]. Chem Commun, 2015,51(11):2166-2169. doi: 10.1039/C4CC08548E
25. [25]
  Zhang S, Nakai Y, Tsuboi T. The Thermal Stabilities of Luminescence and Microstructures of Eu²⁺-doped KBaPO₄ and NaSrPO₄with β-K₂SO₄ Type Structure[J]. Inorg Chem, 2011,50(7):2897-2904. doi: 10.1021/ic102504x
26. [26]
  Lim M A, Park J K, Kim C H. Luminescence Characteristics of Green Light Emitting Ba₂SiO₄:Eu²⁺ Phosphor[J]. J Mater Sci Lett, 2003,22(19):1351-1353. doi: 10.1023/A:1025739412154
27. [27]
  Tang Y S, Hu S F, Lin C C. Thermally Stable Luminescence of KSrPO₄:Eu²⁺ Phosphor for White Light UV Light-Emitting Diodes[J]. Appl Phys Lett, 2007,90(15)151108. doi: 10.1063/1.2721846
28. [28]
  Zhang M, Wang J, Zhang Q. Optical Properties of Ba₂SiO₄:Eu²⁺ Phosphor for Green Light-Emitting Diode(LED)[J]. Mater Res Bull, 2007,42(1):33-39. doi: 10.1016/j.materresbull.2006.05.011
29. [29]
  Lin C C, Xiao Z R, Guo G Y. Versatile Phosphate Phosphors ABPO₄ in White Light-Emitting Diodes:Collocated Characteristic Analysis and Theoretical Calculations[J]. J Am Chem Soc, 2010,132(9):3020-3028. doi: 10.1021/ja9092456
30. [30]
  Ji H, Huang Z, Xia Z. Discovery of New Solid Solution Phosphors via Cation Substitution-Dependent Phase Transition in M₃(PO₄)₂:Eu²⁺(M=Ca/Sr/Ba) Quasi-Binary Sets[J]. J Phys Chem C, 2015,119(4):2038-2045. doi: 10.1021/jp509743r
31. [31]
  Ye N, Zeng W, Jiang J. New Nonlinear Optical Crystal K₂Al₂B₂O₇[J]. JOSA B, 2000,17(5):764-768. doi: 10.1364/JOSAB.17.000764
32. [32]
  Okatov S, Ivanovskii A. Chemical Bonding and Atomic Ordering Effects in β-SiAlON[J]. Int J Inorg Mater, 2001,3(7):923-930. doi: 10.1016/S1466-6049(01)00087-3
33. [33]
  Wang C, Xin S Y, Wang X C. Double Substitution Induced Tunable Photoluminescence in the Sr₂Si₅N₈:Eu Phosphor Lattice[J]. New J Chem, 2015,39(9):6958-6964. doi: 10.1039/C5NJ00997A
34. [34]
  Huang Y, Gan J, Zhu R. Structural Phase Formation and Tunable Luminescence of Eu²⁺-Activated Apatite-type (Ca, Sr, Ba)₅(PO₄)₂(SiO₄)[J]. J Electrochem Soc, 2011,158(11):J334-J340. doi: 10.1149/2.026111jes
35. [35]
  Wang T, Zheng P, Liu X. Effects of Replacement of AlO⁺ for SiN⁺ on the Structure and Optical Properties of Sr₂Si₅N₈:Eu²⁺ Phosphors[J]. J Lumin, 2014,147:173-178. doi: 10.1016/j.jlumin.2013.11.016
36. [36]
  Xia Z, Ma C, Molokeev M S. Chemical Unit Cosubstitution and Tuning of Photoluminescence in the Ca₂(Al_1-xMg_x)(Al_1-xSi_1+x)O₇:Eu²⁺ Phosphor[J]. J Am Chem Soc, 2015,137(39):12494-12497. doi: 10.1021/jacs.5b08315
37. [37]
  Xia Z, Molokeev M S, Im W B. Crystal Structure and Photoluminescence Evolution of La₅(Si_2+xB_1-x)(O_13-xN_x):Ce³⁺ Solid Solution Phosphors[J]. J Phys Chem C, 2015,119(17):9488-9495. doi: 10.1021/acs.jpcc.5b01211
38. [38]
  Zhou D, Liu D, Pan G. Cerium and Ytterbium Codoped Halide Perovskite Quantum Dots:A Novel and Efficient Downconverter for Improving the Performance of Silicon Solar Cells[J]. Adv Mater, 2017,29(42)1704149. doi: 10.1002/adma.201704149
39. [39]
  Tian G, Gu Z, Zhou L. Mn²⁺ Dopant-Controlled Synthesis of NaYF₄:Yb/Er Upconversion Nanoparticles for in Vivo Imaging and Drug Delivery[J]. Adv Mater, 2012,24(9):1226-1231. doi: 10.1002/adma.v24.9
40. [40]
  Wood V, Panzer M, Halpert J. Selection of Metal Oxide Charge Transport Layers for Colloidal Quantum Dot LEDs[J]. ACS Nano, 2009,3(11):3581-3586. doi: 10.1021/nn901074r
41. [41]
  Rafipoor M, Dupont D, Tornatzky H. Strain Engineering in InP/(Zn, Cd)Se Core/Shell Quantum Dots[J]. Chem Mater, 2018.
42. [42]
  Tan R, Yuan Y, Nagaoka Y. Monodisperse Hexagonal Pyramidal and Bipyramidal Wurtzite CdSe-CdS Core-Shell Nanocrystals[J]. Chem Mater, 2017,29(9):4097-4108. doi: 10.1021/acs.chemmater.7b00968
43. [43]
  Zou H, Liu M, Zhou D. Employing CdSe_xTe_1-x Alloyed Quantum Dots to Avoid the Temperature-Dependent Emission Shift of Light-Emitting Diodes[J]. J Phys Chem C, 2017,121(9):5313-5323. doi: 10.1021/acs.jpcc.6b12129
44. [44]
  Zeng R, Zhang T, Dai G. Highly Emissive, Color-Tunable, Phosphine-Free Mn:ZnSe/ZnS Core/Shell and Mn:ZnSeS Shell-Alloyed Doped Nanocrystals[J]. J Phys Chem C, 2011,115(7):3005-3010. doi: 10.1021/jp111288h
45. [45]
  Akkerman Q A, D'Innocenzo V, Accornero S. Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions[J]. J Am Chem Soc, 2015,137(32):10276-10281. doi: 10.1021/jacs.5b05602
46. [46]
  Zhang F, Zhong H, Chen C. Brightly Luminescent and Color-Tunable Colloidal CH₃NH₃PbX₃(X=Br, I, Cl) Quantum Dots:Potential Alternatives for Display Technology[J]. ACS Nano, 2015,9(4):4533-4542. doi: 10.1021/acsnano.5b01154
47. [47]
  Zhang X, Zhang Y, Wang Y. Color-Switchable Electroluminescence of Carbon Dot Light-Emitting Diodes[J]. ACS Nano, 2013,7(12):11234-11241. doi: 10.1021/nn405017q
48. [48]
  Chen D, Gao H, Chen X. Excitation-Independent Dual-Color Carbon Dots:Surface-State Controlling and Solid-State Lighting[J]. ACS Photonics, 2017,4(9):2352-2358. doi: 10.1021/acsphotonics.7b00675
49. [49]
  Kershaw S V, Abdelazim N M, Zhao Y. Investigation of the Exchange Kinetics and Surface Recovery of Cd_xHg_1-xTe Quantum Dots During Cation Exchange Using a Microfluidic Flow Reactor[J]. Chem Mater, 2017,29(7):2756-2768. doi: 10.1021/acs.chemmater.6b04544
50. [50]
  Chen D, Chen X, Wan Z. Full-Spectral Fine-Tuning Visible Emissions from Cation Hybrid Cs_1-mFA_mPbX₃(X=Cl, Br, and I, 0 < m < 1) Quantum Dots[J]. ACS Appl Mater Interfaces, 2017,9(24):20671-20678. doi: 10.1021/acsami.7b05429
51. [51]
  Shen H, Wang H, Li X. Phosphine-Free Synthesis of High Quality ZnSe, ZnSe/ZnS, and Cu-, Mn-Doped ZnSe Nanocrystals[J]. Dalton T, 2009(47):10534-10540. doi: 10.1039/b917674h
52. [52]
  Cao L, Zhang J, Ren S. Luminescence Enhancement of Core-Shell ZnS:Mn/ZnS Nanoparticles[J]. Appl Phys Lett, 2002,80(23):4300-4302. doi: 10.1063/1.1483113
53. [53]
  Corrado C, Cooper J K, Hawker M. Synthesis and Characterization of Organically Soluble Cu-doped ZnS Nanocrystals with Br Co-Activator[J]. J Phys Chem C, 2011,115(30):14559-14570. doi: 10.1021/jp202734n
54. [54]
  Ma L, Chen W. ZnS:Cu, Co Water-Soluble Afterglow Nanoparticles:Synthesis, Luminescence and Potential Applications[J]. Nanotechnology, 2010,21(38)385604. doi: 10.1088/0957-4484/21/38/385604
55. [55]
  Li F, Xia Z, Liu Q. Controllable Synthesis and Optical Properties of ZnS:Mn²⁺/ZnS/ZnS:Cu²⁺/ZnS Core/Multishell Quantum Dots Toward Efficient White Light Emission[J]. ACS Appl Mater Interfaces, 2017,9(11):9833-9839. doi: 10.1021/acsami.6b15997
56. [56]
  Jana S, Srivastava B B, Pradhan N. Correlation of Dopant States and Host Bandgap in Dual-Doped Semiconductor Nanocrystals[J]. J Phys Chem Lett, 2011,2(14):1747-1752. doi: 10.1021/jz200673q
57. [57]
  Li F, Xia Z, Pan C. High Br^- Content CsPb(Cl_yBr_1-y)₃ Perovskite Nanocrystals with Strong Mn²⁺ Emission through Diverse Cation/Anion Exchange Engineering[J]. ACS Appl Mater Interfaces, 2018,10(14):11739-11746. doi: 10.1021/acsami.7b18750
58. [58]
  Huang S, Li Z, Wang B. Morphology Evolution and Degradation of CsPbBr₃ Nanocrystals under Blue Light-Emitting Diode Illumination[J]. ACS Appl Mater Interfaces, 2017,9(8):7249-7258. doi: 10.1021/acsami.6b14423
59. [59]
  Dang Z, Shamsi J, Palazon F. In Situ Transmission Electron Microscopy Study of Electron Beam-Induced Transformations in Colloidal Cesium Lead Halide Perovskite Nanocrystals[J]. ACS Nano, 2017,11(2):2124-2132. doi: 10.1021/acsnano.6b08324
60. [60]
  Zhang F, Huang S, Wang P. Colloidal Synthesis of Air-Stable CH₃NH₃PbI₃ Quantum Dots by Gaining Chemical Insight into the Solvent Effects[J]. Chem Mater, 2017,29(8):3793-3799. doi: 10.1021/acs.chemmater.7b01100
61. [61]
  Zou S, Liu Y, Li J. Stabilizing Cesium Lead Halide Perovskite Lattice Through Mn(Ⅱ) Substitution for Air-Stable Light-Emitting Diodes[J]. J Am Chem Soc, 2017,139(33):11443-11450. doi: 10.1021/jacs.7b04000
62. [62]
  Huang S, Li Z, Kong L. Enhancing the Stability of CH₃NH₃PbBr₃ Quantum Dots by Embedding in Silica Spheres Derived from Tetramethyl Orthosilicate in "Waterless" Toluene[J]. J Am Chem Soc, 2016,138(18):5749-5752. doi: 10.1021/jacs.5b13101
63. [63]
  Loiudice A, Saris S, Oveisi E. CsPbBr₃ QD/AlO_x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat[J]. Angew Chem Int Ed, 2017,56(36):10696-10701. doi: 10.1002/anie.201703703
64. [64]
  Hu H, Wu L, Tan Y. Interfacial Synthesis of Highly Stable CsPbX₃/Oxide Janus Nanoparticles[J]. J Am Chem Soc, 2017,140(1):406-412.
65. [65]
  Woo J Y, Kim Y, Bae J. Highly Stable Cesium Lead Halide Perovskite Nanocrystals Through in Situ Lead Halide Inorganic Passivation[J]. Chem Mater, 2017,29(17):7088-7092. doi: 10.1021/acs.chemmater.7b02669
66. [66]
  Yuan B, Guan S, Sun X. Highly Efficient Carbon Dots with Reversibly Switchable Green-Red Emissions for Trichromatic White Light-Emitting Diodes[J]. ACS Appl Mater Interfaces, 2018,10(18):16005-16014. doi: 10.1021/acsami.8b02379
67. [67]
  Gao R, Zhao M, Guan Y. Ordered and Flexible Lanthanide Complex Thin Films Showing Up-Conversion and Color-Tunable Luminescence[J]. J Mater Chem C, 2014,2(45):9579-9586. doi: 10.1039/C4TC01213E
68. [68]
  Li Z, Zhou Y, Yan D. Electrochemiluminescence Resonance Energy Transfer(ERET) Towards Trinitrotoluene Sensor Based on Layer-by-Layer Assembly of Luminol-Layered Double Hydroxides and CdTe Quantum Dots[J]. J Mater Chem C, 2017,5(14):3473-3479. doi: 10.1039/C7TC00100B
69. [69]
  Zhou Y, Yan D, Wei M. A 2D Quantum Dot-Based Electrochemiluminescence Film Sensor Towards Reversible Temperature-Sensitive Response and Nitrite Detection[J]. J Mater Chem C, 2015,3(39):10099-10106. doi: 10.1039/C5TC02002F
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