Citation: HUANG Jimei, MENG Ruijin, YANG Jinhu. Preparation and Lithium Ion Storage Performance of Sulfur-Doped Titanium Dioxide/Titanium Carbide Composite[J]. Chinese Journal of Applied Chemistry, ;2018, 35(8): 925-931. doi: 10.11944/j.issn.1000-0518.2018.08.180127 shu

Preparation and Lithium Ion Storage Performance of Sulfur-Doped Titanium Dioxide/Titanium Carbide Composite

School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: YANG Jinhu, yangjinhu@tongji.edu.cn
Received Date: 24 April 2018
Revised Date: 11 June 2018
Accepted Date: 13 June 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.21273161), Natural Science Foundation of Shanghai(No.17ZR1447800)Natural Science Foundation of Shanghai 17ZR1447800the National Natural Science Foundation of China 21273161

Figures(5)

Sulfur-doped titanium dioxide/titanium carbide(S-TiO₂/Ti₃C₂)composites were prepared via in-situ hydrothermal oxidation and chemical vapor phase sulfurization using two-dimensional layered Ti₃C₂ as the raw material. The results show that the TiO₂ nanoparticles in situ grew on the Ti₃C₂ nanosheets and sulphur was successfully doped into titanium dioxide. The S-TiO₂/Ti₃C₂ composite as anode material for lithium ion batteries exhibits superior electrochemical performance. A discharge specific capacity of 288 mA·h/g can be obtained after 100 cycles at a current density of 0.2 A/g, which is much higher than those of TiO₂/Ti₃C₂ and pure Ti₃C₂ electrodes. The outstanding cycle stability and discharge specific capacity of the S-TiO₂/Ti₃C₂ electrode are attributed to following reasons:TiO₂ nanoparticles electrically contacting Ti₃C₂ nanosheets can facilitate the interfacial electron transfer and effectively avoid the separation of the two components during the cycle. In addition, S-TiO₂ can improve the conductivity of the TiO₂ and produce some defects to enhance the reactivity. This work provides a new strategy for the preparation of two-dimensional composite materials through an in-situ transformation.
- sulfur doping,
- titanium dioxide,
- two-dimensional transition metal carbides,
- composite,
- lithium-ion batteries
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