Citation: TIAN Dan, LIU Qiang, CHEN Fang, MA Xiaoyan. Preparation and Certification of n-Octylferrocene Certified Reference Material[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 849-856. doi: 10.11944/j.issn.1000-0518.2018.07.170239 shu

Preparation and Certification of n-Octylferrocene Certified Reference Material

The Key Laboratory of Polymer Science and Technology, School of Science, Northwestern Polytechnical University, Xi'an 710129, China

Corresponding author: MA Xiaoyan, m_xiao_yana@nwpu.edu.cn
Received Date: 7 August 2017
Revised Date: 17 August 2017
Accepted Date: 30 October 2017

Fund Project: the Explosive Technology Basic Research Project of Technology and Industry for National Defense [2014]1481Supported by the Explosive Technology Basic Research Project of Technology and Industry for National Defense(No.[2014]1481)

Octylferrocene is often used as a burning rate catalyst for solid rocket propellants because of its excellent catalytic performance and good compatibility. However, so far, there is no its reference material, which makes it difficult to trace and unify the magnitude of the weapons and equipment quality monitoring process, and the quality of related products can not be guaranteed. The reference material of n-octylferrocence in relative purity greater than 99.5% was prepared from industrial product as primary substance by re-crystalization from mixed solvent at low temperature, and its uniformity and stability was investigated by gas chromatography. The purity of n-octylferrocence reference material was certified by the method of mass balance. Other homologues were controlled by self-contrast method. The result shows that the certified result is 99.6% and the expanded uncertainty is 0.2%(k=2).
- n-octylferrocene,
- certified reference material,
- mass balance method,
- uncertainty
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