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Citation: HAN Wenjing, BAIYIN Menghe. Solvothermal Synthesis and Characterization of Cs8Mn4Sn4Se16 and[Ni(1, 2-dap)3]2Cd2Sn2S8(1, 2-dap: 1, 2-Propanediamine)Chains[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 700-707. doi: 10.11944/j.issn.1000-0518.2018.06.170234 shu

Solvothermal Synthesis and Characterization of Cs8Mn4Sn4Se16 and[Ni(1, 2-dap)3]2Cd2Sn2S8(1, 2-dap: 1, 2-Propanediamine)Chains

  • a.

    College of Chemistry & Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China

  • b.

    Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University, Hohhot 010022, China

  • Corresponding author: BAIYIN Menghe, baiymh@163.com
  • Received Date: 29 June 2017
    Revised Date: 8 August 2017
    Accepted Date: 29 August 2017

    Fund Project: the National Natural Science Foundation of China 21461019Supported by the National Natural Science Foundation of China(No.21461019), the Natural Science Foundation Project of Inner Mongolia(No.2016MS0225)the Natural Science Foundation Project of Inner Mongolia 2016MS0225

Figures(10)

  • The chalcogenidostannate compound Cs8Mn4Sn4Se16(1) and[Ni(1, 2-dap)3]2Cd2Sn2S8(2) were solvothermally synthesized by using the alkali metal in 1, 4-butanediamine, and 1, 2-propanediamine(1, 2-dap) coordinated transition metal as guest cations, respectively. Single-crystal X-ray, ultraviolet-visible(UV-Vis) diffuse reflectance spectroscopy and thermogravimetric analysis and differential scanning calorimetry(TG-DSC) indicate that the compounds 1 and 2 belong to orthorhombic system Fddd group and Cmcm group. Both 1 and 2 consist of one-dimensional straight anionic chains composed of edge sharing tetrahedron SnQ4(Q=S, Se) or TMQ4(TM=Mn, Cd). The UV-visble diffuse reflectance data show that the band gaps of compounds 1 and 2 are 1.70 eV and 2.21 eV, respectively, which implies that compounds 1 and 2 have semiconductor properties. The TG-DSC results indicate good thermal stability of compunds 1 and 2 in some temperature condition.
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