Citation: LIN Xiaoyi, ZHU Yongchao, MENG Xiangru. Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate[J]. Chinese Journal of Applied Chemistry, ;2018, 35(1): 82-88. doi: 10.11944/j.issn.1000-0518.2018.01.170336 shu

Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate

a.
No.1 Middle School of Nanyang, Nanyang, He'nan 473009, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: MENG Xiangru, mengxiangru200008@163.com
Received Date: 14 September 2017
Revised Date: 12 December 2017
Accepted Date: 12 December 2017

Fund Project: He′nan Science and Technology Project 172102210128Supported by the National Natural Science Foundation of China(No.J1210060), the He′nan Science and Technology Project(No.172102210128)National Natural Science Foundation of China J1210060

Figures(6)

By solvothermal reaction of Eu(NO₃)₃ 6H₂O with 2-(2-bromophenyl)-1H-imidazole-4, 5-dicarboxylic acid (o-BrPhH₃IDC) in the presence of terephthalic acid, a three-dimensional supramolecular complex (H₃O)[Eu(o-BrPhH₂IDC)₄](1) was prepared. The crystal structure of complex 1 was determined by single crystal X-ray diffraction. The results show that complex 1 crystallizes in the cubic system, Ⅰ-43d space group, and the central europium ion is in a eight-coordinate system. The solid-state fluorescence of complex 1 reveals that complex 1 exhibits a characteristic europium emission spectra at the excitation wavelength of 395 nm which implies that the organic ligand has a good antenna effect and a good sensitization effect on europium ion.
- Eu-complex,
- imidazole dicarboxylate,
- crystal structure,
- fluorescence properties
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沈阳化工大学材料科学与工程学院沈阳 110142